微卡計在固液吸附機制的研究-嵌印高分子及離子交換樹脂在近等電點時的吸附機制

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陳慶松(Chin-Sung Chen) 查詢紙本館藏

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化學工程與材料工程學系

論文名稱

微卡計在固液吸附機制的研究-嵌印高分子及離子交換樹脂在近等電點時的吸附機制
(Microcalorimetric studies of adsorption mechanism between solid and liquid-adsorption mechanism studies of imprinting polymer and ion-exchange resin near isoelectric point)

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摘要(中)

本研究主要針對嵌印高分子及離子交換樹脂在近等電點時的吸附機制進行探討，實驗上主要是利用恆溫滴定微卡計(Isothermal Titration Calorimetry，ITC)量測吸附熱及配合等溫吸附線的建立，期望從熱力學的角度來研究分析。
在嵌印高分子及離子交換樹脂在近等電點時的吸附機制研究方面，我們分別提出了模板分子2,4-D與嵌印高分子及控制組高分子的可能鍵結程序，並說明各鍵結程序對於整個系統的焓△Hads與火商
△Sads 的影響及

摘要(英)

The aim of the research is to provide the insight of the binding mechanism of imprinting polymer and ion-exchange resin near isoelectric point by isotherm curve analysis and adsorption enthalpy measurement by microcalorimetry.
We suggested a possible binding processes of 2,4-dichlorophoxyacetic acid (2,4-D) adsorbing on imprinting and control polymers and divided the process into four subprocesses; (a) dehydration process of imprinting polymer; (b) dehydration process of 2,4-D; (c) binding process of 2,4-D adsorbing on imprinting polymer and (d) rearragement process of water molecules after 2,4-D adsorbing on imprinting polymer. The thermodynamic information accompany the suggested process were also discussed. The data measured using isothermal titration calorimetry (ITC) for both imprinting and control polymers reveals the values of adsorption enthalpy (

關鍵字(中)

★ 乳球蛋白
★ 嵌印高分子
★ 吸附機制

關鍵字(英)

★ bata-lactoglibulin
★ imprinting polymer
★ adsorpti

論文目次

英文摘要 I
中文摘要 III
目錄 VI
圖目錄 IX
表目錄 XI
第一章緒論 1
第二章文獻回顧 3
2.1 嵌印高分子 3
2.1.1嵌印高分子之簡介 3
2.1.2嵌印高分子之合成方法 3
2.1.2-1整體聚合法 4
2.1.2-2 懸浮聚合法 5
2.1.3 嵌印高分子之鍵結力分類 7
2.1.2-1 共價鍵結 8
2.1.2-2 非共價鍵結 8
2.1.2-3 金屬錯合物的配位鍵結 11
2.1.4 嵌印高分子之應用 12
2.1.4-1 層析 13
2.1.4-2 薄膜與感應器 14
2.1.5 嵌印高分子之機制探討 15
2.1.5-1 除草劑2,4-D簡介 16
2.1.5-2 競爭鍵結分析 16
2.1.5-3 交聯反應性研究 17
2.2 離子交換層析 22
2.2.1 蛋白質在近等電點的離子交換層析 27
第三章研究目的 29
第四章實驗藥品與儀器設備 31
4.1 實驗藥品 31
4.2 儀器設備 32
4.3 恆溫滴定微卡計 34
第五章實驗步驟與分析 38
5.1 等溫吸附線的量測 38
5.1.1 嵌印高分子之實驗步驟 38
5.1.2 離子交換樹脂在近等電點之實驗步驟 39
5.2 吸附焓變化的量測 40
5.2.1 實驗步驟 40
5.2.2 實驗數據分析 43
第六章結果與討論 46
6.1 嵌印高分子之吸附機制研究 46
6.1.1 從分子結構推測其可能的鍵結機制 46
6.1.2 吸附行為驅動力的探討 47
6.1.3 等溫吸附線之分析 50
6.1.4 以熱力學數據探討吸附機制 53
6.2 離子交換樹脂在近等電點的吸附機制分析 66
6.2.1 吸附行為驅動力的探討 66
6.2.2 等溫吸附線的分析 68
6.2.2-1 Salt effect 69
6.2.2-2 pH effect 70
6.2.2-3 Temperature effect71
6.2.3 以熱力學數據探討其吸附機制 72
6.2.3-1 Salt effect 73
6.2.3-2 pH effect 73
6.2.2-3 Temperature effect74
第七章結論與心得 88
參考文獻 89

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指導教授

陳文逸(Wen-yih Chen)

審核日期

2000-7-1

推文