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姓名	詹瑞裕(Rudy-yu chen)  查詢紙本館藏	畢業系所	化學工程與材料工程學系
論文名稱	以蒸汽輔助溶解-再結晶技術合成MFI沸石膜之研究 (MFI zeolite film by steam assisted dissolution -recrystallization technique)
相關論文	★ MFI沸石奈米結晶製備研究 ★ 氧化鋅奈米粒子的表面改質與分散 ★ 濕法製備氧化鋅摻雜鋁之透明導電膜 ★ 強吸水性透明奈米沸石膜 ★ 奈米氧化鋅透明導電膜的製作 ★ 製作AZO透明導電膜的各種嘗試 ★ 奈米結晶氧化鋯合成與分散 ★ 接枝PDMS之奈米氧化鋯及其與矽膠複合膜之光學性質 ★ 奈米氧化鋯之表面接枝及其與壓克力樹酯複合膜之電泳沉積 ★ 沸石晶核的製備與排列 ★ 納米級氧化鋯結晶粒子之高濃度穩定懸浮液製備 ★ 聚芳香羧酸酯之合成及性質研究 ★ MFI沸石超微粒子之製作 ★ 四氯化鈦之控制水解研究 ★ 具環氧基矽烷包覆奈米粒子之研究 ★ 具再分散性之奈米級氧化鋯結晶粒子之合成研究
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摘要(中)	中文摘要 MFI沸石具有規則的孔道結構及良好的化學與機械穩定性,由於方向性沸石膜在科 學上具有潛在的應用價值,尤其b軸直孔道朝上可以控制通過分子大小的b方向性,廣泛 應用於石油化工的膜分離、觸媒催化及吸附。超薄連續沸石膜的發展對於新興領域的應 用極為重要,如半導體工業製程低介電絕緣材料、光學抗反射層塗覆及航太鋁合金材料 的抗腐蝕層,若能開發超薄b方向性MFI沸石膜有助於新興領域的應用擴展。 本研究提出一種基於局限空間溶解與再結晶(confined space dissolution and recrystallization)程序的蒸汽輔助平面成長法,將預塗覆b軸向的沸石微晶單層 (microcrystal monolayer),精確控制結構引導劑TPAOH的表面劑量,在飽和蒸汽條件下, 矽晶片表面溶出的矽源供微晶結晶相互成長而融合,得到超薄(100~500 nm) b方向的MFI 沸石連續膜。相較於其他合成方法,本方法能有效抑制沸石微晶非方向或雙晶成長,解 決膜厚增加喪失方向性的缺點,合成的沸石膜具有可靠度高與高再現性等優點。 本文首先比較三種微晶層組裝方法,將微米與次微米的MFI微晶組裝於不同材質與 類型的基板,以製備b軸向的晶種層,結果顯示直接塗覆法對於組裝晶種層覆蓋率最高, 為最有效率的組裝方法。基板的表面性質對於組裝晶種層空隙率有著重要的影響,濺鍍 Pt膜的微晶層組裝,可得到有次序排列與整齊堆積,覆蓋率高達90 %的晶種層。 i MFI微晶層組裝於矽晶片基板的蒸汽輔助成長特性研究,針對微晶層特性、蒸氣反 應溫度、蒸汽含水分及TPAOH表面劑量及有機鹼種類等影響MFI沸石膜成長的重要參數 進行探討。在蒸汽輔助平面成長條件下,以0.75×0.35×1.15μm3組裝於矽晶片的b方向 MFI微晶層,滴覆2 ug/cm2的TPAOH作為結構引導劑,在185°C飽和蒸汽反應8小時,得 到膜厚500 nm的b方向MFI連續膜。以TPAOH有機鹼合成MFI沸石膜的晶體為六角形外, 其他有機模板均為矩形形貌。文中提出蒸汽輔助平面成長的成長模式,說明預塗覆於矽 晶片b方性微晶層在飽和蒸汽條件下,高溫鹼性環境提供微晶間隙侷限空間進行溶解-再 結晶程序,微晶沿矽晶片平面成長,形成b方向MFI沸石膜,此一方法提供合成沸石膜膜 厚、方向性及沸石形貌等微結構可調控的成長模式。 MFI微晶層直接塗覆於不同材質(矽晶片、石英及玻璃)與類型基材蒸汽輔助成長特 性的研究,探討基材表面蒸汽輔助成長過程,溶出物質對於合成MFI沸石膜微結構的影 響,利用MFI沸石膜與石英基材結合強度的特性,提供MFI沸石膜轉移至其他基板的可 行性。在矽晶片基材濺鍍Pt膜與塗覆有機犧牲層,探討飽和蒸汽鹼性環境,矽晶片表面 溶出的矽源擴散至微晶層,完全為Pt膜阻隔與有機犧牲層減緩,對於沸石膜成長特性的 影響,最後,利用有機高分子犧牲層可溶於水的特性,應用於發展無支撐MFI沸石膜合 成方法。
摘要(英)	Zeolite films could find applications in wide range of fields such as selective membranes, catalysis and adsorption due to their well-defined unique pore structures as well as high thermal and chemical stability. In addition, MFI zeolite thin films exhibit excellent corrosion resistance, low framework density, and high mechanical strength. Recently, strong attention has been transferred to the synthesis of high quality coatings that may find application in many different industrial fields such ascorrosion-resistant coatings for aerospace alloys[1], low-k layers for computer chips [2] and anti-reflective coating in optical devices [3]. A number of novel applications of zeolites depend on the ability to create thin, adhesive films on various substrates. For such uses, the preparation of continuous MFI films with defined crystal morphology, film thickness, and preferential crystal orientation is highly desired. A simple method based on confined space dissolution and recrystallization has been developed to synthesize continuous b-oriented MFI zeolite films on flat substrates, through the steaming of pre-coated microcrystal monolayer. The b-oriented MFI monolayer dosed with alkyl ammonium hydroxide and was then subjected to steam under high temperature to initiate the dissolution of seed crystals and crystallization at the gaps between the iii microcrystals, which grow laterally and eventually form a continuous film.Comparison of two different synthesis methods, the advantages of CSDR method lie in the ease control of the thickness and crystal orientation while prohibit the incorporation of newly formed crystals. Several silicalite-1 microcrystals were used as seeds to fabricate a close-packed b-oriented MFI monolayer by three assembly techniques, including interfacial-aided, dynamic interfacial and manual assembly. Seed crystals could be successfully assembled into a compact and highly b-oriented MFI monolayer on various substrates by manual assembly method. Surface characteristics of substrates have important influence on the fabrication of close-packed b-oriented MFI monolayer. It was found that the monolayer coverage about 90% could be obtained on the Pt deposition on Si-wafer by manual assembly. The effects of synthesis parameters (i.e. the steaming temperature, the size of the seed crystals, the water content in the steam and the surface dosage of TPAOH) on the microstructure of MFI zeolite film were investigated in detail.The type of TAAOH significantly influenced the crystal morphology; TPAOH produced elongated hexagonal prisms, whereas all other TAAOHs led to rectangular crystals. On the MFI microcrystal monolayer, continuous and b-oriented MFI films can be obtained after steam assisted in-plane growth for 8 h at 185°C, leading to the formation of 350 nm-thick MFI zeolite film. Based on the film formation of MFI microcrystal monolayer, a confined space dissolution and recrystallization procedure was proposed to explain oriented MFI zeolite films onsubstrates iv directlycould be favorable to the intergrowth of MFI zeolite crystals along thein-plane direction. For comparison purposes, the steaming growth of pre-coated microcrystal monolayers also carried out using glass and quartz plate as film support. The dissolution of the quartz substrate is very limited under the steam reaction. Thus, MFI zeolite film could be readily detached from the quartz substrate, transferred and bonded onto target substrates. For the deposited Pt film substrate, the diffusion of Si from the Si-wafer into seed monolayer was completely prohibited. Since, the seed crystal itself was used as the SiO2 source for seed crystals growth, result in the formation rate for the silicalite-1 films slower than that the bare substrate. Finally, we report an approach to the fabrication of free-standing MFI zeolite films involves the use of a sacrificial layer, which was composed of soluble polymer and leaved the freestanding thin film behind by dissolving the sacrificial layer in water
關鍵字(中)	★ MFI膜 ★ 蒸汽輔助平面成長 ★ b方向性 ★ 有機模板 ★ 沸石微晶	關鍵字(英)	★ MFI zeolite film ★ confined space dissolution and recrystallizationb-orientated ★ structure directing agent ★ microcrystal monolayer ★ direct rubbing
論文目次	目錄 頁次 中文摘要..............................................................................................................i 英文摘要..................................................................................................iii 致謝.........................................................................................................vi 目錄......................................................................................................vii 表目錄...................................................................................................xii 圖目錄..................................................................................................xiii 第一章緒論.........................................................................................1 1.1 研究背景..............................................................................1 1.2 研究目的..................................................................................2 1.3 研究內容..............................................................................3 第二章文獻回顧.........................................................................................8 2.1沸石簡介........................................................................8 2.1.1 沸石結構...........................................................................8 2.1.2 沸石命名..........................................................................11 2.1.3 MFI沸石特性.........................................................................13 2.1.4 MFI沸石薄膜.........................................................................14 2-2 MFI沸石膜合成.........................................................................15 vii 2.2.1 直接合成法...........................................................................16 2.2.2 晶種合成法..........................................................................17 2.2.3 其他合成方法.........................................................................18 2.3 沸石膜合成參數....................................................................20 2.3.1 結構導向劑...........................................................................20 2.3.2 礦化劑..........................................................................22 2.3.3 支撐基材.........................................................................23 2.4 沸石粒組裝....................................................................23 2.4.1 基材表面改質...........................................................................24 2.4.2 沸石晶粒組裝方法..........................................................................30 2.5 MFI沸石膜應用....................................................................34 2.5.1 低介電材料...........................................................................35 2.5.2 抗反射膜..........................................................................35 2.5.3 抗腐蝕塗層.........................................................................36 viii 第三章 b軸向MFI微晶層組裝.............................................................44 3.1引言...............................................................................................44 3.2 實驗部分..................................................................................................44 3.2.1 MFI沸石微晶製備...........................................................................45 3.2.2 基材前處理..........................................................................46 3.3 沸石微晶層組裝....................................................................46 3.3.1 介面輔助組裝...........................................................................47 3.3.2 動態介面組裝..........................................................................48 3.3.3 直接塗覆法..........................................................................49 3.4 樣品分析...................................................................................................49 3.4.1 XRD晶體結構分析...........................................................................49 3.4.2 SEM形貌分析..........................................................................49 3.5 結果與討論...............................................................................................50 3.5.1 合成MFI微晶...........................................................................51 3.5.2 介面輔助微晶層..........................................................................51 3.5.3 動介面組裝微晶層...........................................................................53 3.5.4 直接塗覆微晶層..........................................................................55 3.5.5 微晶層組裝方法..........................................................................62 3.5.6 不同基材組裝..........................................................................63 ix 第四章 沸石微晶層蒸汽輔助成長研究...............................................................66 4.1 引言簡介................................................................................................66 4.2 微晶層蒸氣反應實驗...............................................................................66 4.2.1 實驗藥品..........................................................................................67 4.2.2 蒸汽反應實驗..........................................................................68 4.2.3 樣品微結構分析..................................................................................71 4.3 結果與討論.............................................................................................71 4.3.1 蒸汽反應溫度.....................................................................................71 4.3.2 蒸汽含水量影響..................................................................................77 4.3.3 TPAOH表面劑量影響........................................................................80 4.3.4 其他添加劑之影響.............................................................................81 4.3.5 有機鹼種類影響..................................................................................85 4.3.6 蒸汽輔助平面成長模式.....................................................................87 4.3.7 文獻MFI沸石膜合成方法歸納.....................................................89 4.4 整理與歸納.............................................................................................92 第五章 MFI沸石膜於各種基材之合成研究.......................................................97 5.1 引言................................................................................................97 5.2 實驗部分.......................................................................................98 5.2.1 矽晶片濺鍍Pt膜...................................................................................98 x 5.2.2 有機犧牲層旋塗..........................................................................99 5.2.3 蒸氣輔助成長.................................................................................99 5.2.4 樣品分析.....................................................................................99 5.3 結果與討論.............................................................................................100 5.3.1 玻璃基材微晶層蒸氣成長.................................................................100 5.3.2 石英基材微晶層蒸氣成長.................................................................101 5.3.3 Pt膜/矽晶片之微晶蒸氣成長.............................................................105 5.3.4 犧牲層微晶層蒸氣成長...................................................................110 5.4 整理與歸納..........................................................................................116 第六章 結論與展望.........................................................................................120 6.1 結論...............................................................................................120 6.2 展望.......................................................................................122 6.3 建議.......................................................................................123
參考文獻	第一章 參考文獻 [1] J. Gascon, F. Kapteijn, B. Zornoza, Practical approach to zeolitic membranes and coatings: State of the art, opportunities, barriers, and future perspectives, Chemistry of Materials2012, 24(15), 2829-2844. [2]C. M.Lew, R.Cai, Y.Yan, S. Zeolite, Thin films: from computer chips to space stations. Acc. Chem. Res.2010,43 (2), 210-219. [3]H. K.Hunt, C. M.Lew, M.Sun, Y.Yan, M. E.Davis, Pure-silica LTA, CHA, STT, ITW, and -SVR thin films and powders for low-k applications. Micropor. Mesopor. Mater.2010,130 (1-3), 49-55. [4]H. K.Hunt, C. M.Lew, M.Sun, Y.Yan, M. E.Davis,Pure-silica zeolite thin films by vapor phase transport of fluoride for low-k applications. Micropor. Mesopor. Mater. 2010, 128[1-3], 12-18 [5] C. H. Chen, S.Y. Li, A. S. T Chiang, A. T. Wu, Y. S. Sun, Scratch-resistant zeolite anti-reflective coating on glass for solar applications,Sol. Energy Mater. Sol. Cells. 2011,95,1694-1700. [6]L. Y.Huang, Y. C.Hao, W.ChangJean, M. J.Wang, A. S. T.Chiang, T. C.Tsai, Growth of MFI zeolite film as corrosion protection layer of aluminum alloy. Microporous and Mesoporous Materials2015,217, 71-80. [7] Z.B. Wang, Y.S. Yan, Controlling crystal orientation in zeolite MFI thin films by direct in situ crystallization, Chemistry of Materials2001, 13(3), 1101-1107. [8] J. Di, C. Zhang, W. Yan, Direct in situ crystallization of highly oriented silicalite-1 thin films on a surface sol–gel process modified substrate, Microporous and Mesoporous Materials2011, 145(1),104-107. [9] A. Gouzinis, M. Tsapatsis, On the preferred orientation and microstructural manipulation of molecular sieve films prepared by secondary growth, Chem. Mater. 1998, 10, 5 2497-2504. [10] J. Choi, S. Ghosh, Z.P. Lai, et al., Uniformly a-oriented MFI zeolite films by secondary growth, AngewandteChemie, International Edition in English2006, 45(7),1154-1158. [11] Z. Lai, M. Tsapatsis, J.P. Nicolich, Siliceous ZSM-5 membranes by secondary growth of b-oriented seed layers, Advanced Functional Materials2004, 14(7),716-729. [12] C. S. Tsay, A. S. T. Chiang, R. W. Thomson, Supported zeolite membrane by vapor-phase regrowth, AIChE J2000, 616-625. [13] W. Chaikittisilp, M. E. Davis, T. Okubo, TPA+-mediated conversion of silicon wafer into preferentially-oriented MFI zeolite film under steaming, Chem. Mater. 2007, 19, 4120-4122. [14] M. Ji, G. Liu, C. Chen, Synthesis of highly b-oriented ZSM-5 membrane on a rough surface modified simply with TiO2 by in situ crystallization, Microporous and Mesoporous Materials 2012, 155(1),117-123. [15]F.Z. Zhang, M. Fuji, M. Takahashi, In situ growth of continuous b-oriented MFI zeolite membranes on porous α-alumina substrates precoated with a mesoporous silica sublayer, Chemistry of Materials2005, 17(5), 1167-1173. [16]X. Lin, X. Chen, H. Kita, et al., Synthesis of silicalite tubular membranes by in situ crystallization, AIChE Journal2003, 49(1),237-247. [17] S. Aguado, E. McLeary, A. Nijmeijer, b-Oriented MFI membranes prepared from porous silica coatings, Microporous and Mesoporous Materials2009, 120(1-2),165-169. [18] K. V. Agrawal, B. Topuz, T. C. T. Pham, T. H. Nguyen, N. Sauer, N. Rangnekar, H. Zhang, K. Narasimharao, S. N. Basahel, L. F. Francis , C. W. Macosko, S. Al-Thabaiti , M. Tsapatsis, K.B. Yoon,Oriented MFI membranes by gel-less secondary growthof sub-100 nm MFI-nanosheetseed layers, Adv. 6 Mater.2015,27,2243-2249. [19] T. C. T. Pham, T. H. Nguyen, K. B. Yoon,Gel-free secondary growth of uniformly oriented silica MFI zeolite films and application for xylene separation, Angew. Chem. Int. Ed.2013,52,8693-8698. 第二章 參考文獻 [1] http://www.iza-structure.org/ [2] Y. G. Yan, T. Bein, Zeolite thin films with tunable molecular sieve, J. Am. Chem. Soc.,1995, 117, 9990–9994. [3] Z.P. Lai, G. Bonilla, I. Diaz, et al., Microstructural optimization of a zeolite membrane for organic vapor separation, Science,2003, 300 456-460. [4] J. Di, C. Zhang, W. Yan, Direct in situ crystallization of highly oriented silicalite-1 thin films on a surface sol–gel process modified substrate, Micropor. Mesopor. Mater.2011, 145, 104-107. [5] Z.B. Wang, Y.S. Yan, Controlling crystal orientation in zeolite MFI thin films by direct in situ crystallization, Chem. Mater.2001, 13, 1101-1107. [6] A. Gouzinis, M. Tsapatsis, On the preferred orientation and microstructural manipulation of molecular sieve films prepared by secondary growth, Chem. Mater. 1998, 10, 2497-2504. [7] J. Choi, S. Ghosh, Z.P. Lai, UniformLy a-oriented MFI zeolite films by secondary growth, Angew. Chem. Int. Ed.2006, 45,1154-1158. [8] Z. Lai, M. Tsapatsis, J.P. Nicolich, Siliceous ZSM-5 membranes by secondary growth of b-oriented seed layers, Adv. Funct. Mater.2004, 14, 716-729. [9] C. S. Tsay, A. S. T. Chiang, R. W. Thomson, Supported zeolite membrane by vapor-phase regrowth, AIChEJ. 2000, 616-625. [10] W. Chaikittisilp, M. E. Davis, T. Okubo, TPA+-mediated conversion of silicon wafer into preferentially-oriented MFI zeolite film under steaming, Chem. Mater. 2007,19, 4120-4122. [11] Y.K. Hwang, U.H. Lee, J.S. Chang, Microwave-induced fabrication of MFI zeolite crystal films onto various metal oxide substrates, Chem. Lett.2005, 34, 1596-1597. 37 [12] W. Xiao, L. Zhou, J. Yang, A simple seeding method for MFI zeolite membrane synthesis on macroporous support by microwave heating, Micropor. Mesopor. Mater.2010, 142, 154-160. [13] Z. Tang, S.J. Kim, X.H. Gu, Microwave synthesis of MFI-type zeolite membranes by seeded secondary growth without the use of organic structure directing agents, Micropor. Mesopor. Mater.2009, 118(1-3), 224-231. [14] T. C. T. Pham, T. H. Nguyen, K. B. Yoon,Gel-free secondary growth of uniformLy oriented silica MFI zeolite films and application for xylene separation, Angew. Chem. Int. Ed.2013,52,8693-8698. [15]K. V. Agrawal, B. Topuz, T. C. T. Pham, T. H. Nguyen, N. Sauer, N. Rangnekar, H. Zhang, K. Narasimharao, S. N. Basahel, L. F. Francis, C. W. Macosko, S. Al-Thabaiti, M. Tsapatsis, K.B. Yoon,Oriented MFI membranes by gel-less secondary growthof sub-100 nm MFI-nanosheet seed layers, Adv. Mater.2015,27,2243-2249. [16]Y. Peng, X. F. Lu, Z. B. Wang, Y. S. Yan, Fabrication of b-Oriented MFI Zeolite Films under Neutral Conditions without the Use of Hydrogen Fluoride. Angew. Chem. Int. Ed.2015, 54, 5709-5712. [17] M. Zhou, D. Korelskiy, P. C. Ye, M. Grahn, J. Hedlund, A uniformlyoriented MFI membrane for improved CO2separation,Angew. Chem. Int. Ed.2014, 53, 3492-3495. [18]M. Ji, G. Liu, C. Chen, et al., Synthesis of highly b-oriented ZSM-5 membrane on a rough surface modified simply with TiO2 by in situ crystallization, Micropor. Mesopor. Mater.2012, 155,117-1237. [19]L. Lang, X. Liu, B. Zhang, Controlling the orientation and coverage of silica-MFI zeolite films by surface modification, Appl. Surf. Sci.2009, 255,4886-4890. [20]F. Z. Zhang, M. Fuji, M. Takahashi, In situ growth of continuous b-oriented MFI zeolite membranes on porous α-alumina substrates precoated with a mesoporous silica sublayer, 38 Chem. Mater. 2005, 171167-1173. [21] S. Aguado, E. McLeary, A. Nijmeijer, b-Oriented MFI membranes prepared from porous silica coatings, Micropor. Mesopor. Mater.2009, 120, 165-169. [22]S. Li, X. Wang, D. Beving, Molecular sieving in a nanoporous b-oriented pure-silica-zeolite MFI monocrystal film, J. Am. Chem. Soc.2004, 126, 4122-4123. [23] Y. Liu, Y. S. Li, W. S. Yang, Fabrication of highly b-Oriented MFI film with molecular sieving properties by controlled in-plane secondary growth, J. Am. Chem. Soc. 2010,132, 1768-1769. [24]M.C. Lovallo, A. Gouzinis, M. Tsapatsis, Synthesis and characterization of oriented MFI membranes prepared by secondary growth, AIChE J1998, 44(8), 1903-1913. [25] T.C.T. Pham, H.S. Kim, K.B. Yoon, Growth of uniformly oriented silica MFI and BEA zeolite films on substrates, Science, 2011, 334 1533-1538. [26]X. Li, Y. Peng, Z. Wang, et al., Synthesis of highly b-oriented zeolite MFI films by suppressing twin crystal growth during the secondary growth, Cryst. Eng. Comm.2011, 13, 3657-3660. [27] T.C.T. Pham, H.S. Kim, K.B. Yoon, Growth of uniformly oriented silica MFI and BEA zeolite films on substrates, Science,2011, 334, 1533-1538. [28] J. Weitkamp,M. Hunger, Preparation of zeolites via the dry-gel synthesis method, stud. surf. sci. catal. 2005, 334, 1-12. [29]T. Nishide, T. Hamatsu, Y. Kiyozumi, Synthesis of oriented zeolite MFI films by solid-state transformation,J. Mater. Chem.2002, 12, 1465-1468. [30]N. Kosinov, E.J. Hensen, Synthesis and separation properties of an α-alumina-supported high-silica MEL membrane, J. Membr. Sci.2013, 447, 12-18. [31]O. A. Fouad, R.M. Mohamed, M.S. Hassan, I.A. Ibrahim, Effect of template type and template/silica mole ratio onthe crystallinity of synthesized nanosized 39 ZSM-5,Catal. Today.2006, 11,682-687. [32]G. Bonilla, I. Dı ́az, M. Tsapatsis, H. K. Jeong,Y.J. Lee,D. G. Vlachos, Zeolite (MFI) crystal morphology control using organic structure-directing agents, Chem. Mater. 2004, 16, 5697-5705. [33]T. Ban, H. Mitaku, C. Suzuki, J. Matsuba,Y. Ohya, Y. Takahashi, Crystallization and crystal morphology of silicalite-1 preparedfrom silica gel using different amines as a base,JCryst. Growth.2005, 274, 594-602. [34]S. L. Burkett,M. E. Davis,Mechanisms of structure direction in the synthesis of pure-silica zeolites. 1. Synthesis of TPA/Si-ZSM-5, Chem. Mater. 1995, 7, 920-928. [35]S. L. Burkett,M. E. Davis,Mechanisms of structure direction in the synthesis of pure-silica zeolites. 2. Hydrophobic hydration and structural specificity, Chem. Mater. 1995, 7,1453-1463. [36]P. A. Jacobs, E.G. Derouane, J. Weitkamp,J. Chem. Soc., Chem. Comm. 1981, 591-593. [37]Q. Li, M.L. Amweg, C.K. Yee, et al., Photochemical template removal and spatial patterning of zeolite MFI thin films using UV/ozone treatment, Micropor. Mesopor. Mater.2005, 87, 45-51. [38] I. Melián-Cabrera, F. Kapteijn, J.A. Moulijn, Room temperature detemplation of zeolites through H2O2-mediated oxidation, Chem. Commun.2005, 21, 2744-2746. [39]E.M. Flanigen, B.M. Lok, R.L. Patton, S.T. Wilson, in:Y. Murakami, A. Ijima (Eds.), New Developments in ZeoliteScience and Technology, J.W. Ward Kodansha Press, Tokyo,1986, p. 103. [40]H. Kessler, J. Patarin, C. Schott-Darie,The opportunities of the fluoride route in the synthesis of microporous materials, Stud. Surf. Sci. Catal.1994, 85, 75. [41] P. Nian, M. H. Su, T. Yu, Z. Wang,B. X. Zhang, X. L. Shao, X. Y.Jin,N. Z. Jiang, S.Li, Q. Ma, Fabrication of a highly b-oriented MFI-type zeolite film-modified electrode with 40 molecular sieving properties by Langmuir-Blodgett method. J Mater. Sci. 2016, 51, 3257-3270. [42] X. L. Cheng, Z. B. Wang, Y.S. Yan, Synthesis and corrosion resistance of high-silica zeolite MTW, BEA, and MFI coatings on steel and aluminum, Electrochem. Solid-State Lett. 2001, 4,B23. [43]I. Lee, J. L. Buday, H. K. Jeong, μ-Tiles and mortar approach: A simple technique for the facile fabrication of continuous b-oriented MFI silicalite-1 thin films,Micropor. Mesopor. Mater.2009, 122, 288–293. [44]K.B. Yoon, Organization of zeolite microcrystals for production of functional materials, Acc. Chem. Res.2007, 40(1), 29-40. [45] A. Kulak, Y. J. Lee, K. B. Yoon, Orientation‐controlled monolayer assembly of zeolite crystals on glass and mica by covalent linkage of surface‐bound xpoxide and amine groups, Angew Chem Int Ed, 2000, 39, 950-953. [46] S. Y. Choi, Y. J. Lee, K. B. Yoon, Monolayer Assembly of Zeolite Crystals on Glass with Fullerene as the Covalent Linker, J. Am. Chem. Soc. 2000, 122, 5201-5209. [47] G. S. Lee, Y. J. Lee, K. B. Yoon, Orientation-controlled monolayer assembly of zeolite crystals on glass using Terephthaldicarboxaldehyde as a covalent Linker, Tetrahedron.2000, 56, 6965-6968. [48] H. K. Lee, Y. J. Lee, K. B. Yoon, Facile assembly of zeolite monolayers on glass, silica, alumina, and other zeolites using 3-halopropylsilyl reagents as covalent linkers,Adv. Mater.2000,12, 1114-1117. [49] J. S. Lee, Y. J. Lee, K. B. Yoon,Synthesis of zeolite As ordered multicrystal arrays, Science,2003, 301, 818-821. [50] G. S. Lee, Y. J. Lee,K. B. Yoon,Layer-by-layer assembly of zeolite crystals on glass with polyelectrolytes as ionic linkers, J. Am. Chem. Soc. 2001, 123,9769-9779. 41 [51]Y. S. Park, G. S. Lee, K. B. Yoon, Micropatterned monolayer assembly of zeolite microcrystals on glass by ionic linkages, Micropor. Mesopor. Mater.2006, 96, 1-8. [52] H. K. Park, J. S. Lee, K. B. Yoon, Aligned monolayer assembly of zeolite crystals on platinum, gold, and indium–tin oxide surfaces with molecular linkages, Micropor. Mesopor. Mater. 2004, 72, 91-98. [53] Y. S. Chun, K. Ha, K. B. Yoon, Diisocyanates as novel molecular binders for monolayer assembly of zeolite crystals on glass, Chem. Commun.2002, 17 1846-1847. [54]A. Kulak, Y. S. Park, K. B. Yoon, Polyamines as strong molecular linkers for monolayer assembly of zeolite crystals on flat andcurved Glass. J Am Chem. Soc. 2000, 122(38): 9308-9309. [55] [57] [58] [59] [60] [61] J. S. Park, G. S. Lee,K. B. Yoon,Organization of Microcrystals on Glass by Adenine−Thymine Hydrogen Bonding,J. Am. Chem. Soc. 2002, 124, 13366-13367. J. Hedlund, S. Mintova, J. Sterte, Controlling the preferred orientation in silicalite-1 films synthesized by seeding, Micropor Mesopor Mater,1999,28, 185-194. J. Hedlund, F. Jareman, A. J. Bons, A masking technique for high quality MFI membranes, J. Membr. Sci.2003,222, 163-179. Y. Liu, Y. Li, W. Yang, Fabrication of highly b-oriented MFI monolayers on various substrates,Chem. Commun.2009, 1520-1522. Y. Liu, Y. S. Li, W. S. Yang, Fabrication of highly b-oriented MFI film with molecularsieving properties by controlled in-plane secondary growth, J. Am. Chem. Soc. 2010, 132, 1768-1769. Y. Liu, Y. S. Li, W. S. Yang, Phase-segregation-induced self-assembly of anisotropic MFI microbuilding blocks into compact and highly b-oriented monolayers, Langmuir2011, 27,2327-2333. [62] M. Zhou, J. Hedlung, Oriented monolayers of submicron crystals by dynamic interfacial 42 assembly,J. Mater. Chem.2012,22, 3307-3310. [63] J. Li, S.; Ma, Q. J. X. L. Lv,B. Q. Zhang,Reliablefabricationofpreferentially b-orientedsilicalite-1monolayers on varioussubstratesusingtheLangmuir-Blodgetttechnique, Mater. Lett. 2014, 124, 299-301. [64] J. A. Lee, L. L. Meng, D. J. Norris, L. E. Scriven, M. Tsapatsis, Colloidal crystal layers of hexagonal nanoplates by convective assembly, Langmuir 2006,22, 5217-5219. [65] J. S. Lee, J. H. Kim, Y. J. Lee, N. C. Jeong, K. B. Yoon, Manual assembly of microcrystal monolayers on substrates, Angew. Chem. Int. Ed. 2007, 49, 3087-3090. [66] C. H. Chen, S.Y. Li, A. S. T Chiang, A. T. Wu, Y. S. Sun, Sol. Scratch-resistant zeolite anti-reflective coating on glass for solar applications,Energy Mater. Sol. Cells. 2011, 95, 1694-1700. [67] L. Y. Huang, Y. C. Hao, W. C. ChangJean, M. J. Wang, A. S. T. Chiang, T. C. Tsai, Growth of MFI zeolite film as corrosion protection layer of aluminum alloy, Micropor. Mesopor. Mater.2015, 217, 71-80. [68]Z. B. Wang, H.T. Wang, A. Mitra, L.M. Huang, Y.S. Yan, Pure-Silica Zeolite Low-k Dielectric Thin Films, Adv. Mater. 2001, 13, 746-749. [69] H. K. Hunt, C. M. Lew, M. Sun,Y. Yan, M. E. Davis, Pure-silica zeolite thin films by vapor phase transport of fluoride for low-k applications. Micropor. Mesopor. Mater.2010, 128, 12-18. [70] H. K. Hunt, C. M. Lew, M. Sun, Y. Yan, M. E. Davis, Pure-silica LTA, CHA, STT, ITW, and -SVR thin films and powders for low-k applications. Micropor. Mesopor. Mater. 2010, 130, 49-55. 第三章 參考文獻 [1] Y. Liu, Y. Li, W. Yang, Fabrication of highly b-oriented MFI monolayers on various substrates, Chem. Comm.2009, 1520-1522. [2] Y. Liu, Y. S. Li, W. S. Yang, Fabrication of highly b-oriented MFI film with molecular sieving properties by controlled in-plane secondary growth, J. Am. Chem. Soc. 2010,132, 1768-1769. [3] Y. Liu, Y. S. Li, W. S. Yang, Phase-segregation-induced self-assembly of anisotropic MFI microbuilding blocks into compact and highly b-oriented monolayers,Langmuir. 2011,27 , 2327-2333. [4] M. Zhou, J. Hedlung, Oriented monolayers of submicron crystals by dynamic interfacial assembly,J. Mater. Chem., 2012, 22, 3307-3310. [5] J.S. Lee, J.H. Kim, Y. Ju, N.C. Jeong, K.B. Yoon, Manual assembly of microcrystal monolayers on substrates, Angew. Chem. Int. Ed. 2007, 46, 3087-3090. [6] T.C.T. Pham, H.S. Kim, K.B. Yoon, Growth of uniformLy oriented silica MFI and BEA zeolite films on substrates, Science,2011, 334, 1533-1538. 第四章 參考文獻 [1] C. S. Tsay, A. S. T. Chiang, R. W. Thomson, Supported zeolite membrane by vapor-phase regrowth, AIChE J2000, 616-625. [2] W. Chaikittisilp, M. E. Davis, T. Okubo, TPA+-mediated conversion of silicon wafer into preferentially-oriented MFI zeolite film under steaming,Chem. Mater.2007, 19, 4120-4122. [3] A. Gouzinis, M. Tsapatsis, On the preferred orientation and microstructural manipulation of molecular sieve films prepared by secondary growth, Chem. Mater. 1998, 10, 2497-2504. [4] J. Choi, S. Ghosh, Z.P. Lai, et al., Uniformly a-oriented MFI zeolite films by secondary growth, Angew. Chem. Int. Ed.2006, 45, 1154-1158. [5]Z. Lai, M. Tsapatsis, J.P. Nicolich, Siliceous ZSM-5 membranes by secondary growth of b-oriented seed layers, Adv. Funct. Mater.2004, 14, 716-729. [6] W. C. Wong, Louisa T. Y. Au, C. T. Ariso, K. L. Yeung, Effects of synthesis parameters on the zeolite membrane growth, J. Membr. Sci. 2001,191, 143–163. [7] M. Ji, G. Liu, C. Chen, Synthesis of highly b-oriented ZSM-5 membrane on a rough surface modified simply with TiO2 by in situ crystallization, Micropor. Mesopor. Mater.2012, 155, 117-123. [8] F.Z. Zhang, M. Fuji, M. Takahashi, In situ growth of continuous b-oriented MFI zeolite membranes on porous α-alumina substrates precoated with a mesoporous silica sublayer, Chem. Mater.2005, 17, 1167-1173. [9] S. Aguado, E. McLeary, A. Nijmeijer, b-Oriented MFI membranes prepared from porous silica coatings, Micropor. Mesopor. Mater.2009, 120, 165-169. 94 [10]T.C.T. Pham, H.S. Kim, K.B. Yoon, Growth of uniformly oriented silica MFI and BEA zeolite films on substrates, Science,2011, 334 1533-1538. [11]X. Li, Y. Peng, Z. Wang, et al., Synthesis of highly b-oriented zeolite MFI films by suppressing twin crystal growth during the secondary growth, Cryst.Eng.Comm. 2011, 13, 3657-3660. [12] M. Zhou, D. Korelskiy, P. C. Ye, M. Grahn, J. Hedlund, A uniformly oriented MFI membrane for improved CO2 separation, Angew. Chem. Int. Ed.2014, 126, 3560-3563. [13]T. Ban, H. Mitaku, C. Suzuki, J. Matsuba,Y. Ohya, Y. Takahashi, Crystallization and crystal morphology of silicalite-1 prepared from silica gel using different amines as a base, J. Cryst. Growth.2005, 274, 594-602. [14]G. Shu, J. Liu, A. S. T. Chiang, R. W. Thomson, Transparent zeolite films with regular surface patterns, Adv. Mater. 2006,18, 185-189. [15]T. Nishide, T. Hamatsu, Y. Kiyozumi, et al., Synthesis of oriented zeolite MFI films by solid-state transformation,J. Mater. Chem.2002, 12, 1465-1468. [16] T. C. T. Pham, T. H. Nguyen, K. B. Yoon, Gel-free secondary growth of uniformLy oriented silica MFI zeolite films and application for xylene separation, Angew. Chem. Int. Ed.2013, 52, 8693-8698. [17] K. V. Agrawal, B. Topuz, T. C. T. Pham, T. H. Nguyen, N. Sauer, N. Rangnekar, H. Zhang, K. Narasimharao, S. N. Basahel, L. F. Francis , C. W. Macosko, S. Al-Thabaiti, M. Tsapatsis, K.B. Yoon, Oriented MFI membranes by gel-less secondary growth of sub-100 nm MFI-nanosheet seed layers, Adv. Mater.2015, 27, 2243-2249. [18] Y. Peng, X. F. Lu, Z. B. Wang, Y. S. Yan, Fabrication of b-Oriented MFI Zeolite Films under Neutral Conditions without the Use of Hydrogen Fluoride. Angew. Chem. Int. Ed. 2015, 54, 5709-5712. 95 [19] C. Z.Wang, X. F.Liu, J.Lia, B. Q. Zhang, Microwave-assisted seeded growth of the submicrometer-thick and pure b-oriented MFI zeolite films using an ultra-dilute synthesis solution, Cryst. Eng. Comm. 2013, 15, 6301-6304. 第五章 參考文獻 [1] K. V. Agrawal , B. Topuz, T. C. T. Pham, T. H. Nguyen, N. Sauer, N. Rangnekar, H. Zhang, K. Narasimharao, S. N. Basahel, L. F. Francis, C. W. Macosko, S. Al-Thabaiti, M. Tsapatsis, K.B. Yoon, Adv. Mater. 2015, 27, 2243-2249. [2] M. Zhou, D. Korelskiy, P. C. Ye, M. Grahn, J. Hedlund, A uniformly oriented MFI membrane for improved CO2 separation, Angew. Chem. Int. Ed.2014,126, 3560-3563. [3]Y. Peng, X.F. Lu, Z. B. Wang, Y. S. Yan,Fabrication of b-oriented MFI zeolite films under neutral conditions without the use of hydrogen fluoride, Angew. Chem. Int. Ed.2015, 127 ,1-8. [4] B. T. Suo, X. Su, Ji. Wu, D. Chen, A. Wang, Z. H. Guo, Poly (vinyl alcohol) thin film filled with CdSe–ZnS quantum dots: Fabrication, characterization and optical properties,Mate. Chem. Phys.2010, 119 237 [5]R. Lai, Y. S. Yan, G. R. Gavalas, Growth of ZSM-5 films on alumina and other surfaces, Micropor. Mesopor. Mater. 2000, 37, 9-19. [6]I. Lee, J.L. Buday, H.K. Jeong, μ-Tiles and mortar approach: A simple technique for the facile fabrication of continuous b-oriented MFI silicalite-1 thin films, Microporous and Mesoporous Materials, 2009, 122, 288-293. [7] C. Z.Wang, X. F.Liu, J.Lia, B. Q. Zhang, Microwave-assisted seeded growth of the submicrometer-thick and pure b-oriented MFI zeolite films using an ultra-dilute synthesis solution, Cryst. Eng. Comm. 2013, 15, 6301-6304. [8] I. Lee, H. K. Jeong, Synthesis and gas permeation properties of highly b-oriented MFI silicalite-1 thin membranes with controlled microstructure, Micropor. Mesopor. Mater.2011, 141, 175–183. 118 [9] P. Nian, M. H. Su, T. Yu, Z. Wang, B. X. Zhang, X. L. Shao, X. Y. Jin, N. Z. Jiang, S. Li,Q. J.Ma, Fabrication of a highly b-oriented MFI-type zeolite film-modified electrode with molecular sieving properties by Langmuir-Blodgett method, J. Mater. Sci. 2016, 51, 3257-3270.
指導教授	蔣孝澈(Anthony Shiaw-Tseh Chiang)	審核日期	2016-8-23
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