摘要(英) |
Volatile organic compounds (VOCs) are organic chemicals that have a high vapor pressure in normal condition; they cause numerous molecules to easily evaporate into the atmosphere. Most human-made chemical compounds include lots of VOCs that produce air pollution and dangerous to human health or cause harm to the environment.
In order to decrease VOCs produce air pollution and enhance spraying film quality, the research proposed solvent-free coating that UV-cured resin spraying into vacuum, we success have atomize viscosity 60cP resin by 14 kg/cm^2 pressure at 〖10〗^(-2) torr vacuum environment, moreover remove bubble in resin by degassing system then avoid pinhole pollution, and then cured by ultraviolet at atmospheric environment, finally success coating thickness 20 μm thin film on surface, the mist of polymer liquid spray on the substrate as a full-thickness liquid film that covers the entire substrate surface and its features. The resulting surface is glassy with virtually no defects or pinholes. Because of liquid film have excellent adhesion and quite efficient smoothing on rough substrates.
The process has several advantage include smooth like mirror, better adhesion on rough substrate, more quickly coating efficient, low temperature, amenable to virtually all types of deposition processes, especially this process avoid polymer directly contact human and VOCs can be exhaust by filter system, it’s friendly to environment. |
參考文獻 |
[1] 環保署/國科會(2007):空污防制科研合作計畫推動工作暨先驅策略規劃計畫。
[2] 經濟部工業局(1996):塗料工業及塗裝工程技術手冊。
[3] 經濟部工業局(1996):工業減廢技術手冊-塗料工業及塗裝工程。
[4] 化學工業出版社( 2012):塗料化學與塗裝技術基礎。
[5] 金屬中心(2005):前瞻奈米鍍膜技術與潛力市場探索。
[6] 魏宏樺(2005):微快速原型系統之霧化鋪層技術研究. 臺北科技大學製造科技研究所學位論文, 1-76.
[7] 李建昌,李宏宇,韓宇,巴德純(2012):真空噴射射流流場的 Fluent 模擬分析。東北大學學報(自然科學版),33(3),422-425。
[8] 孫越(2011)真空噴霧法的噴嘴內部空化流動及噴霧過程模擬研究 (Master′s thesis, 東北大學)。
[9] Affinito, J. D., Darab, J. G., & Gross, M. E. (1999). U.S. Patent No. 5,902,641. Washington, DC: U.S. Patent and Trademark Office. [10] Affinito, John D. "Hybridization of the polymer multi-layer (PML) deposition process." Surface and Coatings Technology 133 (2000): 528-534.)
[11] Affinito, J. D., Eufinger, S., Gross, M. E., Graff, G. L., & Martin, P. M. (1997). PML/oxide/PML barrier layer performance differences arising from use of UV or electron beam polymerization of the PML layers. Thin Solid Films, 308, 19-25.
[12] Affinito, J. (2002). A new method for vacuum deposition of polymer films. Thin Solid Films, 420, 1-7.
[13] Burrows, P. E., Graff, G. L., Gross, M. E., Martin, P. M., Hall, M., Mast, E., ... & Brown, J. J. (2001, February). Gas permeation and lifetime tests on polymer-based barrier coatings. In International Symposium on Optical Science and Technology (pp. 75-83). International Society for Optics and Photonics.
[14] Burrows, P. E., Graff, G. L., Gross, M. E., Martin, P. M., Shi, M. K., Hall, M., ... & Sullivan, M. B. (2001). Ultra barrier flexible substrates for flat panel displays. Displays, 22(2), 65-69..
[15] Lee, Y., Kim, H., & Roh, Y. (2001). Deposition of ZnO thin films by the ultrasonic spray pyrolysis technique. Japanese Journal of Applied Physics, 40(4R), 2423. |