硫化銅-氧化鋅複合材料及其熱電特性研究

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姓名

楊凱丞(Kai-Cheng Yang) 查詢紙本館藏

畢業系所

電機工程學系

論文名稱

硫化銅-氧化鋅複合材料及其熱電特性研究
(Thermoelectric Properties of CuS-ZnO Composite)

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摘要(中)

熱電效應是利用熱電材料本身的特性，將熱能與電能相互轉換的現象，而廢熱存在於我們身邊許多裝置，回收這些廢熱在環保層面有著非常高的價值。熱電元件的應用非常廣泛，可以做為發電系統的廢熱回收，亦可做為致冷晶片使用，或是汽車的能源回收，甚至可做為隨身裝置晶片的能源。而熱電材料為固態設備，具有無汙染、體積小、重量輕、無噪音、無耗損、結構簡單等優點。目前科學家著重於奈米結構的改良與複合材料的開發，以期能夠增加ZT值，使熱電效應能夠達到商業化應用之標準。
本研究著重於探討硫化銅-氧化鋅合金與其他材料之熱電特性，找出合適的p-type材料應用於熱電模組的製作。量測範圍於室溫至523K，並探討其熱電模組的特性與未來應如何改善熱電模組的效能。

摘要(英)

The thermoelectric effect is a phenomenon of converting heat energy to electricity, and can be used in wide applications, including waste heat recycling, thermoelectric cooler, and portable power. It has the advantages of no pollution, small volume, light weight, no noise, and simple component structure, etc.
This study was focused on the development as well as the thermoelectric properties of CuS-ZnO alloy and the module made by this p-type material. Thermoelectric module was measured from room temperature to 523K, and the characteristic performance is analyzed and discussed.

關鍵字(中)

★ 硫化銅-氧化鋅
★ 熱電特性
★ 席貝克效應

關鍵字(英)

★ CuS-ZnO
★ Thermoelectric Properties
★ Seebeck Effect

論文目次

摘要 I
Abstract II
誌謝 III
目錄 IV
圖目錄 VII
表目錄 IX
第一章、緒論 1
1-1 前言 1
1-2 熱電效應 2
1-2-1 席貝克效應(Seebeck Effect) 2
1-2-2 帕爾帖效應(Peltier Effect) 3
1-2-3 湯姆森效應(Thomson Effect) 4
1-3 熱電優質(Figure of Merit) 4
1-4 研究動機 5
第二章、理論基礎與文獻回顧 6
2-1 熱電材料 6
2-2 p-type氧化物的摻雜 6
2-3 熱壓法 7
2-4 冷壓法 7
2-5 熱電模組 7
第三章、實驗流程與儀器設備 8
3-1 三氧化二銦、三氧化二鉻、氧化鎳摻雜 8
3-2 硫化銅合金 8
3-3 熱電模組製作 10
3-4 實驗儀器 12
3-4-1 四點探針 12
3-4-2 Seebeck量測 14
3-4-3 行星式球磨機 16
3-4-4 霍爾量測儀 17
3-4-5 熱導量測 17
3-4-6 熱擴散係數量測 18
3-4-7 密度 19
3-4-8 比熱量測 20
3-4-9 模組電性分析 21
第四章、實驗結果與討論 25
4-1 前言 25
4-2 三氧化二鉻、氧化鎳塊材量測分析 25
4-3 三氧化二銦塊材量測分析 26
4-4 硫化銅-氧化鋅合金量測分析 28
4-5 硫化銅-氧化鋅合金熱電特性 30
4-5-1 功率因子計算 30
4-5-2 穩定度測試 33
4-5-3 熱導率計算 34
4-5-4 硫化銅-氧化鋅合金之ZT 36
4-6 熱電模組分析 37
4-6-1 開路電壓 37
4-6-2 短路電流 37
4-6-3 功率輸出 37
4-6-4 模組(1)量測結果 38
4-6-5 模組(2)量測結果 40
4-6-6 模組理論值 43
4-7 結論與未來展望 44
參考文獻 45

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指導教授

辛正倫(Cheng-Lun Hsin)

審核日期

2018-7-25

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