金屬鹵化鈣鈦礦塊材之光致發光及光致變色特性研究

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黃子軒(TZU-HSUAN HUANG) 查詢紙本館藏

畢業系所

光電科學與工程學系

論文名稱

金屬鹵化鈣鈦礦塊材之光致發光及光致變色特性研究
(Photoluminescence and photochromic properties of metal halide perovskite bulk crystals)

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摘要(中)

本文主要針對混合鹵化物鈣鈦礦: CH3NH3PbBr3、CH3NH3PbBr2.25Cl0.75、CH3NH3PbBr2Cl1、CH3NH3PbBr1.5Cl1.5、CH3NH3PbCl3 上述材料做實驗的分析。第一部分的實驗是量測上述五種混合鹵化物鈣鈦礦的光致發光光譜，可以找出材料本身能階所在的位置以及利用曲線擬合分析出Br的缺陷能階所在的波長，接著利用加熱平台讓材料做升溫的處理，在升溫的過程中可以看到不同比例的鹵化物鈣鈦礦光致發光光譜有不同的變化，會發現在特定比例的鹵化物鈣鈦礦在升溫的過程中能量可以很穩定，後續也針對顏色做了分析，特定比例的鹵化物鈣鈦礦在升溫的過程中不會隨著升溫而有顏色的變化。
第二部分的實驗是量測升溫過程的鹵化物鈣鈦礦光致變色光譜，當Br主導的鹵化物鈣鈦礦，在600nm附近的吸收以及波谷的位置會隨溫度上升而增加，而Cl主導的鹵化物鈣鈦礦在升溫過程可以看到在550nm附近吸收及波谷的位置會隨溫度上升而降低。

摘要(英)

This research focuses on the metal halide perovskite: CH3NH3PbBr3、CH3NH3PbBr2.25Cl0.75、CH3NH3PbBr2Cl1、CH3NH3PbBr1.5Cl1.5、CH3NH3PbCl3 analysis of the above material for experimentation. The first part of the experiment is to measure the photoluminescence spectra of the above five metal halide perovskite, it is possible to find out the location of the energy level of material itself and use the curve fitting to analyze the wavelength of the defect energy level of Br, then use the heating platform to warm up the material, during the warming process, we can see different changes in the photoluminescence spectra of different proportions of metal halide perovskite,
it is found that the energy of a specific percentage of metal halide perovskite can be very stable during the heating process, meanwhile, further discussion on color changes of halide perovskite is made, specific percentage of metal halide perovskite does not change color as the temperature rises during the heating process.
The second part of the research, measurement of photochromic spectra of metal halide perovskite during warm-up temperature, When Br-dominated metal halide perovskite, the absorption near 600nm and the location of the dip will increase with temperature, The Cl-dominated metal halide perovskite can be seen to decrease in absorption and dip position near 550 nm as the temperature rises during the heating process.

關鍵字(中)

★ 變溫光譜
★ 光致發光光譜
★ 光致變色光譜
★ 有機無機鈣鈦礦

關鍵字(英)

★ warm-up temperature
★ photoluminescence spectrum
★ photochromic
★ metal halide perovskite

論文目次

致謝 ii
中文摘要 iv
ABSTRACT vi
目錄 ix
圖目錄 xiii
表目錄 xvii
Chapter1 緒論 1
1-1前言 1
1-2 鈣鈦礦的結構 4
1-3 研究動機 5
Chapter2 文獻回顧 6
2-1 光吸收 6
2-2螢光 7
2-3光致發光 9
2-4淺陷阱和深陷阱 10
2-5鈣鈦礦的相變溫度 11
2-6色度圖 13
Chapter3 實驗方法 16
3-1 單光儀 16
3-2 光致發光光譜 17
3-2-1 光致發光光譜的實驗架構 17
3-2-2 光致發光光譜的實驗流程 18
3-3 光致變色光譜 19
3-3-1 光致變色光譜的實驗架構 19
3-3-2 光致變色光譜的實驗流程 20
Chapter4 實驗結果與分析 21
4-1鈣鈦礦(Br、Cl)不同比例的光致發光光譜 21
4-1-1 MAPbBr3的光致發光光譜 21
4-1-2 MAPbBr2.25Cl0.75的光致發光光譜 22
4-1-3 MAPbBr2Cl1的光致發光光譜 23
4-1-4 MAPbBr1.5Cl1.5的光致發光光譜 24
4-1-5 MAPbCl3的光致發光光譜 25
4-2鈣鈦礦(Br、Cl)不同比例在不同溫度下的光致發光光譜 28
4-2-1 MAPbBr3在不同溫度下的光致發光光譜 28
4-2-2 MAPbBr2.25Cl0.75在不同溫度下的光致發光光譜 31
4-2-3 MAPbBr2Cl1在不同溫度下的光致發光光譜 35
4-2-4 MAPbBr1.5Cl1.5在不同溫度下的光致發光光譜 38
4-2-5 MAPbCl3在不同溫度下的光致發光光譜 41
4-3鈣鈦礦(Br、Cl)不同比例在不同溫度下的色度圖 45
4-3-1 MAPbBr3在不同溫度下的色度圖 45
4-3-2 MAPbBr2.25Cl0.75在不同溫度下的色度圖 46
4-3-3 MAPbBr2Cl1在不同溫度下的色度圖 47
4-3-4 MAPbBr1.5Cl1.5在不同溫度下的色度圖 49
4-3-5 MAPbCl3在不同溫度下的色度圖 50
4-4 鈣鈦礦(Br、Cl)不同比例在不同溫度下的光致變色光譜 52
4-4-1 MAPbBr2.25Cl0.75在不同溫度下的光致變色光譜 52
4-4-2 MAPbBr2Cl1在不同溫度下的光致變色光譜 54
4-4-3 MAPbBr1.5Cl1.5在不同溫度下的光致變色光譜 56
4-4-4 MAPbCl3在不同溫度下的光致變色光譜 58
Chapter5 結論 60
Reference 62

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指導教授

王智明(CHIH-MING WANG)

審核日期

2021-1-25

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