金屬氧化物在尿素-氯化膽鹼深共熔溶液的溶解機制

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因敏綸(Min-Lun Yin) 查詢紙本館藏

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金屬氧化物在尿素-氯化膽鹼深共熔溶液的溶解機制

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摘要(中)

深共熔溶液(Deep Eutectic Solvent, DES)為近年廣泛研究的綠色溶液之一，將氯化膽鹼和尿素以莫耳比1:2的比例混合是典型的DES。雖然DES對多種金屬氧化物都有良好溶解度，但其溶解機制仍甚不清楚。本研究因此探討氯化膽鹼和尿素的組成成分，在溶解氧化亞銅(Cu2O)所扮演的角色。透過比較氧化亞銅溶解在DES、接近飽和的氯化膽鹼水溶液、尿素水溶液的溶解度和紫外光-可見光譜，發現尿素對溶解Cu2O的影響大。此外，比較銅氯化物、Cu2O和銅金屬溶解在DES和水溶液中的結果，可推論Cu2O溶於DES的機制，是由1價的銅離子與尿素形成錯合物而穩定溶解。最後，探討改變尿素在DES比例，發現增加尿素比例可提高DES對Cu2O的溶解能力，但須將溶液溫度保持在70 ℃才能有較好的操作條件。

摘要(英)

Recently, Deep Eutectic Solvent (DES) is known as one of the widely studied green solution with a typical molar mixing ratio of 1:2 between choline chloride and urea. Although many metal oxides have good solubility in DES, the mechanism of it is still lacking. This study consequently investigated the role of choline chloride and urea in dissolving copper (I) oxide (Cu2O). Urea was found to play a significant role in dissolving Cu2O from comparing the solubility and UV-vis absorption spectrogram of dissolved Cu2O in DES, near saturated choline chloride, and urea aqueous solutions. Moreover, the mechanism of dissolving Cu2O in DES was derived from the formation of a stable complex between copper (I) and urea by comparing copper (II) chloride, Cu2O, and metal copper dissolved in both DES and deionized water. Finally, the solubility of Cu2O in DES can be improved by varying urea fractions in DES and maintained temperature at 70 ℃ during operation.

關鍵字(中)

★ 深共熔溶液
★ 氯化膽鹼-尿素
★ 氧化亞銅
★ 溶解

關鍵字(英)

★ Deep eutectic solvent
★ Choline chloride-urea
★ Copper (I) oxide
★ Dissolution

論文目次

摘要 I
ABSTRACT II
致謝 III
目錄 IV
圖目錄 VI
表目錄 IX
第一章前言 1
1-1　研究緣起 1
1-2　研究目的 2
第二章文獻回顧 3
2-1　綠色溶液 3
2-1-1　綠色化學 3
2-1-2　綠色溶劑 5
2-2　深共熔溶液簡介 8
2-2-1　離子溶液 8
2-2-2　深共熔溶液 13
2-3　銅資源循環再利用 19
2-3-1　銅資源重要性 19
2-3-2　PCB產業產生之銅廢料 20
2-4　深共熔溶液溶解金屬氧化物的研究現況 24
第三章研究方法 28
3-1　研究架構 28
3-2　實驗材料與藥品 29
3-3　儀器設備 31
3-4　紫外光-可見光光譜儀分析原理 34
3-5　實驗方法 39
第四章結果與討論 44
4-1　尿素和氯化膽鹼在氧化亞銅溶解過程的角色 44
4-2　氧化亞銅在深共熔溶液中的溶解型態和途徑 51
4-2-1　CuCl2和CuCl化合物在深共熔溶液中的溶解 51
4-2-2　Cu金屬在深共熔溶液中的溶解 58
4-3　氧化亞銅在不同尿素比例DES中的溶解 65
第五章結論與建議 71
第六章參考文獻 73
附錄口試與外審意見答覆修正表 80

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指導教授

李崇德(Chung-Te Lee)

審核日期

2021-7-29

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