通過機械力化學法合成類沸石-咪唑骨架材料-90（ZIF-90）及其應用探討

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姓名

林復慶(Phuc Khanh Lam) 查詢紙本館藏

畢業系所

化學學系

論文名稱

通過機械力化學法合成類沸石-咪唑骨架材料-90（ZIF-90）及其應用探討
(Study on the Application of Mechanochemistry for Zeolitic Imidazolate Framework-90 (ZIF-90))

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至系統瀏覽論文 (2025-1-31以後開放)

摘要(中)

本篇論文分成兩部分：
近年來奈米金屬粒子儼然成為材料領域最熱門的研究之一，主要是因為其表面積大的優勢在相催化，氣體儲存與表面增強拉曼散射的應用上相當好的表現。已有報導指出使用金屬有機骨架材料(Metal-organic Frameworks, MOFs) 包覆奈米金屬粒子，不僅可以減少昂貴催化劑損失防止金屬粒子聚集降低催化活性，同時也可以利用外在的孔洞性質去做選擇性催化。然而，目前主要合成Metal@MOF 材料方法大多需要有機溶劑，高溫，高壓或是長時間的反應過程，此類的反應條件相當耗能且不環保，所以開發一個更有效、對環境更友善的合成方法是亟需克服的問題，同時此法課已為後續工業應用方面帶來可觀的經濟效益。因此，本研究課題希望能在Metal@MOF材料的合成中，提供一個快速反應且使用溫和溶劑的合成環境。因此，本論文第一部份利用新穎特別且有效的機械力化學法(Mechanochemistry)球磨合成Metal@MOF，其中 Pd@ZIF-90 應用在表面增強拉曼散射光譜的散射效果最好，相較於 Au@ZIF-90 的21.2ppm，其可以偵測到甲苯蒸氣濃度為10.6 ppm。
本篇論文第二部分研究主題為透過機械力化學法，利用微量水輔助方式快速研磨合成類沸石-咪唑骨架材料-90 (Zeolitic Imidazolate Framework 90; ZIF-90) 包覆蛋白質。酵素與骨架材料的結合的複合材料在生物催化上相當具有潛力。本實驗室 2019 年成功透過機械力化學法的有機溶液輔助研磨反應快速合成金屬有機骨架材料包覆蛋白質。由於反應需要有機溶液輔助研磨，所以會讓蛋白質減少催化活性。因此，希望能在 Enzyme@MOF材料的合成中，提供一個快速反應且使用水輔助研磨反應，可以讓蛋白質減少損失催化活性。

摘要(英)

There are two parts in my dissertation as shown below
Part I: Green and Rapid Encapsulation of SERS-active Metal Nanoparticles in MOF matrices via Liquid-assisted Grinding
Noble metal nanoparticles have attracted wide attentions due to its great potential applications in heterogeneous atalysis, hydrogen storage, and Surface Enhanced Raman Spectroscopy (SERS) techniques. It is reported that the encapsulation of metal nanoparticles into Metal-organic Frameworks (MOFs) not only prevents the oxidation and agglomeration of nanoparticles but also enhances the selectivity of chemicals transferring through material apertures in catalyzing process. Most of the strategies reported on metal nanoparticles encapsulation was solvothermal methods that required bulk organic solvents, high temperature or pressure and considerable reaction time. Due to this fact, it is necessary to find an alternative method for embedding metal nanoparticles into MOFs that more effective, environmentally-friendly and energy reduction. Therefore, we successfully applied mechanochemical method in embedding metal nanoparticles such as gold and palladium into MOFs of Zeolitic Imidazolate Framework 90(ZIF-90) via mechanochemistry, ZIFs- a sub group of MOFs, and it is so called (Metal@ZIF-90). We further used Metal@MOFs composites as the SERS substrate for the detection of hazardous chemicals, i.e., toluene. The sample of Pd@ZIF-90 shows more sensitive to toluene vapor at 10.6 ppm comparing to Au@ZIF-90 at 21.2 ppm in the value of LOD (limit of detection).
Part II: Protein-Assisted Assembly of Zeolitic Imidazolate Framework 90 (ZIF-90) via Mechanochemitry
In order to enhance the durability and stability of biomacromolecules, normally the immobilization methods will be performed as well as the biological functions also maintained under a wide range of catalyzing conditions. Recently, our lab had successfully encapsulating enzymes in MOFs via mechanochemical strategy using trace amounts of organic solvents. However, the biological activity of enzymes significantly decreased with the presence of organic solvent. For this reason, the second part of my dissertation is about rapid encapsulation of enzymes into ZIF-90 by Mechanochemistry with water-assisted while maintaining the enzyme biological function. we aim to study a mechanochemical synthesis of encapsulated enzymes in MOFs assisting a trace amounts of water as solvent that can minimize the influence of solvent on the enzyme biological activity and also understand the mechanism by encapsulation of enzymes with different isoelectric points.

關鍵字(中)

★ 奈米金屬粒子
★ 金屬有機骨架材料
★ 機械力化學法
★ 類沸石-咪唑骨架材料-90
★ 酵素
★ 表面增強拉曼散射光譜

關鍵字(英)

★ Metal nanoparticles
★ Metal-organic Frameworks
★ Mechanochemical method
★ Zeolitic Imidazolate Framework 90
★ Enzyme
★ Surface Enhanced Raman Spectroscopy

論文目次

中文摘要 ··················································································· I
Abstract ··················································································· III
致謝詞 ···················································································· V
目錄 ······················································································ VI
圖目錄 ··················································································· XI
表目錄 ·················································································· XV
第1章緒論 ......................................................................................................... 1
1-1 金屬有機骨架材料 (Metal-organic frameworks) .................................... 1
1-2 類沸石-咪唑骨架材料(Zeolitic Imidazolate Frameworks) ...................... 5
1-3 類沸石-咪唑骨架材料-90/8 ...................................................................... 7
1-4 奈米金屬粒子 ............................................................................................ 8
1-4-1 物理方法 (Physical methods) ............................................................ 9
1-4-1-1 氣體蒸汽法 (Gas Evaporation Method) ..................................... 9
1-4-1-2 氣液固生長法 (Vapor Liquid Solid Growth) .............................. 9
1-4-1-3 機械球磨法 (Ball Milling) .......................................................... 9
1-4-1-4 雷射剝削法 (Laser Ablation Technique) .................................. 10
1-4-2 化學方法 (Chemical Methods) ........................................................ 10
1-4-2-1 氧化還原法 (Redox Method) .................................................... 11
1-4-2-2 光化學法 (Photochemical Method) .......................................... 11
1-4-2-3 聲波化學法 (Ultrasonic Irradidation Method) .......................... 11
1-4-2-4 溶膠凝膠法 (Sol Gel Method) .................................................. 12
1-4-2-5 微乳化法之逆微胞法 (Micro Emulsion Synthesis) ................. 12
1-4-2-6 電化學法 (Electrochemical Method) ........................................ 12
1-5 表面增強拉曼光譜（Surface-enhanced Raman spectroscopy） ........... 13
1-6 甲苯 (Toluene) ......................................................................................... 14
1-7 機械力化學法 (Mechanochemistry) ....................................................... 15
1-8 固定化酵素 (Immobilized Enzyme) ....................................................... 17
1-9 過氧化氫酶 (Catalase, Cat) .................................................................... 20
1-10 研究動機 (Experiment Motivation) ...................................................... 22
第2章實驗部分 ............................................................................................... 25
2-1 實驗藥品 .................................................................................................. 25
2-2 實驗儀器與設備 ...................................................................................... 26
2-2-1 實驗合成設備 ................................................................................... 26
2-2-2 實驗鑑定儀器 ................................................................................... 27
2-3 實驗儀器之原理 ...................................................................................... 27
2-3-1 中量快速球磨機 (Ball Mill Instrument).......................................... 27
2-3-2 X射線粉末繞射儀 (Powder X-ray Diffraction；PXRD) ............... 29
2-3-3 場發掃描式電子顯微鏡 (Field-emission Scanning Electron
Microscope；FE-SEM) ............................................................................... 30
2-3-4 穿透式電子顯微鏡 (Transmission Electron Microscope；TEM) .. 31
2-3-5 紫外線可見光吸收光譜儀 (UV-Visible Spectrophotometer) ......... 32
2-3-6 Zeta電位分析儀 (Zeta Potential Analyzer)...................................... 32
2-3-7 偵測蛋白質的濃度 (Bradford Assay) ............................................. 34
2-3-8 偵測過氧化氫水溶液之濃度 (Ferrous Oxidation in Xylenol orange
assay, FOX assay) ......................................................................................... 35
2-3-9 十二烷基硫酸鈉聚丙烯醯胺膠體電泳 (SDS-PAGE) .................... 36
2-4 實驗步驟 .................................................................................................. 40
2-4-1 金奈米粒子 Au (PVP) 的合成法 .................................................... 40
2-4-2 鈀奈米粒子 Pd (PVP) 的合成法 ..................................................... 41
2-4-3 機械球磨法合成 ZIF-90 ................................................................... 41
2-4-4 機械球磨法合成 Metal@ZIF-90 ...................................................... 42
2-4-5 機械球磨法合成 CAT@ZIF-90 ........................................................ 42
2-4-6 機械球磨法合成 Enzyme@ZIF-90 .................................................. 42
2-4-7 原位創新合成 CAT@ZIF-90 ............................................................ 43
2-4-8 原位創新合成 Lys@ZIF-90 ............................................................. 43
2-4-9 類沸石咪唑骨架-90包覆過氧化氫酶材料(CAT@ZIF-90)的活性測
試 .................................................................................................................. 44
2-4-10 添加蛋白酶(Proteinase K)的抑制測試 .......................................... 44
第3章結果與討論–機械力化學法合成 ZIF-90和Metal@ZIF-90 ............ 45
3-1 機械球磨合成 ZIF-90 .............................................................................. 45
3-2 機械球磨合成Au@ZIF-90 ..................................................................... 48
3-3 機械球磨合成 Pd@ZIF-90 ..................................................................... 55
3-4 Metal@ZIF-90於表面增強拉曼散射之探討 ......................................... 61
第4章結論–機械力化學法合成ZIF-90和 Metal@ZIF-90 ........................ 63
第5章結果與討論–機械力化學法合成 Enzyme@ZIF-90 ......................... 64
5-1 水輔助機械力化學法合成 CAT@ZIF-90結果之討論 ......................... 64
5-2 機械力化學法的水輔助研磨反應快速合成 Enzyme@ZIF-90結果之討論 .................................................................................................................. 66
5-3 機械力化學法的乙醇輔助研磨反應快速合成 Enzyme@ZIF-90結果之
討論 .................................................................................................................. 68
5-4 原位創新合成 Enzyme@ZIF-90結果之討論 ........................................ 69
5-5 機械力化學法的水輔助研磨反應快速合成 Enzyme@ZIF-90於界面電位之討論.......................................................................................................... 70
第6章結論–機械力化學法合成 Enzyme@ZIF-90 ..................................... 75
第7章參考文獻 ............................................................................................... 76

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指導教授

謝發坤(Fa-Kuen Shieh)

審核日期

2022-1-17

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