博碩士論文 108329602 詳細資訊




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姓名 阮書嫻(Nguyen Thi Thai Hien)  查詢紙本館藏   畢業系所 材料科學與工程研究所
論文名稱
(Development of periodic nanostructure substrates for the applications of SERS and water-splitting)
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摘要(中) 高熵陶瓷(HECs)是一類新發現的材料,除了與高熵合金(HEA)有部分特性相似之外,它們還有非常獨特的特性,因此吸引了各種研究的特征。HEC在許多領域都表現出色各種各樣的應用,具有無窮的可能性與發展潛力。在這項工作中,尖晶石(CoCrFeMnNi)3O4以多孔陽極氧化鋁(AAO)為光陽極,合成了一種新型光催化劑可見光光譜中的大量光吸收,帶隙為2.58 eV。這個研究了HECs AAO光陽極的光響應性能。結果表明,HECs具有顯著的光電化學和光催化性能活動這一發現證明了HECs在各種應用中的多功能性及其應用特別是光催化的前景。此外,石墨烯以前曾用於各種表面增強拉曼光譜散射(SERS)應用。這項研究描述了有序金的形成多孔陽極氧化鋁(AAO)襯底上的納米顆粒(AuNP)和石墨烯。這個AuNPs電磁增強活性與石墨烯獨特性能的結合AAO存在下的物理/化學性質增強了SERS性質並使微量分析調查。將對大量作品進行比較,以說明開發中的每個組件。此外,本研究旨在填補我們研究的空白了解SERS增強機制。
摘要(英) High entropy ceramics (HECs) are a new class of materials that have been discovered
recently. Apart from the similarities with high entropy alloys (HEAs), they have very unique
characteristics that have attracted various studies. HECs have exhibited great performance in a
variety of applications, and the possibilities are endless. In this work, spinel (CoCrFeMnNi)3O4
was synthesized on porous anodic aluminum oxide (AAO) as a photoanode and demonstrated
substantial light absorption in the visible light spectrum with a band gap of 2.58 eV. The
photoresponse performance of the HECs-AAO photoanode for water splitting was examined.
The results indicate that the HECs have remarkable photoelectrochemical and photocatalytic
activity. This discovery demonstrates HECs′ versatility in a variety of applications and their
prospects for photocatalysis in particular.
Furthermore, graphene has previously been used in a variety of surface-enhanced Raman
scattering (SERS) applications. This study describes the formation of ordered gold
nanoparticles (AuNPs) and graphene on a porous anodic aluminum oxide (AAO) substrate. The
combination of AuNPs electromagnetic enhancement activity and graphene′s unique
physical/chemical properties in the presence of AAO enhances SERS properties and enables
microanalysis investigations. Numerous works will be compared to illustrate the critical role of
each component in development. Additionally, this study aims to fill in the gaps in our
understanding of the SERS enhancement mechanism.
關鍵字(中) ★ 高熵陶瓷(HEC)
★ 陽極氧化鋁(AAO)
★ 光伏效應
★ 表面增强拉曼散射 (SERS)
★ 尖晶石結構電催化
關鍵字(英) ★ High entropy ceramics (HECs)
★ anodic aluminum oxide (AAO)
★ photoelectrochemical (PEC) and photocatalytic activity
★ surface-enhanced Raman scattering (SERS)
★ spinel (CoCrFeMnNi)3O4, AuNPs, graphene
論文目次 Table of contents
Chapter I Introduction ..1
Chapter II Literature Review...3
2-1. Anodic aluminum oxide (AAO).3
2-2. HECs on AAO for PEC & photocatalytic applications...3
2-2-1. The concept of HECs and their properties....3
2-2-2. Fundamental of photoelectrochemical (PEC) and photocatalytic activities for water
splitting.....8
2-3. Graphene and ordered gold nanoparticles deposited on AAO substrate for SERS.......11
2-3-1. The progress of plasmonic materials on SERS .12
2-3-2. Graphene on SERS .15
Chapter III Experimental Section...0
3-1. Preparation of AAO...20
3-2. Preparation of HECs on AAO .20
3-3. Preparation of Au/Graphene on AAO ..21
3-3-1. Au nanoparticles synthesis ..21
3-3-2. Graphene dispersion ..21
3-3-3. Defect graphene dispersion ..21
3-3-4. Deposited Au/Graphene on AAO...22
3-4. Characterizations.....22
3-4-1. Field emission scanning electron microscopy (FE-SEM)..22
3-4-2. Ultraviolet–visible spectroscopy (UV-Vis)..23
3-4-3. X-ray diffraction (XRD)..24
3-4-4. Raman scattering ...25
3-4-5. Electrochemical analyzer (CHI)..26
Chapter IV Results and Discussion ..28
4-1. HECs on AAO characteristics and PEC & photocatalytic performance 28
iv
4-1-1. Structural analysis...28
4-1-2. Photoresponse for PEC & photocatalytic activity in water-splitting.....32
4-2. Characteristics and SERS performance of graphene and ordered gold nanoparticles
placed on an AAO substrate .34
4-2-1. Structural analysis..34
4-2-2. SERS performance 36
Chapter V Conclusion .40
References 42
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指導教授 洪緯璿(Wei-Hsuan Hung) 審核日期 2022-1-25
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