製備Fe金屬附載於碳化ZIF-67對抗生素與有機染料降解及六價鉻離子還原之催化反應

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姓名

張在焮(Tsai-Hsin Chang) 查詢紙本館藏

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化學學系

論文名稱

製備Fe金屬附載於碳化ZIF-67對抗生素與有機染料降解及六價鉻離子還原之催化反應

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至系統瀏覽論文 (2027-6-30以後開放)

摘要(中)

本論文研究為合成雙金屬有機金屬骨架材料，並將其碳化應用在催化反應上，使材料中金屬節點還原成金屬態並把有機配體碳化成氮參雜碳材以增加材料穩定度。以2-甲基咪唑與鐵和鈷的前驅物合成Fex-ZIF67，再以高溫鍛燒爐碳化成碳材Fex-CZ67，碳化後材料的穩定性得以提升，並且金屬還原後仍保有催化活性。
第一部分實驗中，針對抗生素—四環黴素與有機染料的Fenton降解反應，以調控鈷和鐵的含量達到最佳的降解效果，僅含鈷的CZ-67對四環黴素的降解需經過8.5分鐘才能反應完全，準一級反應速率常數k為42.78（min-1gcat-1）；而Fe0.1-CZ67和Fe0.2-CZ67的k值分別下降至18.98與14.92。但當鐵含量上升至40%時（Fe0.4-CZ67）降解速率為最快，3.5分鐘四環黴素降解率達到94.2%，且反應率速率常數k達到79.54，這個結果歸因於鐵和鈷的協同效應，而鈷可能為主要的催化金屬，所以Fe0.1-CZ67和 Fe0.2-CZ67的鈷含量降低且鐵的含量不足以在此反應產生協同效應。
第二部分的實驗為六價鉻還原反應，CZ-67對六價鉻還原需經過135分鐘，準一級反應速率常數k為2.16；而隨著鐵的含量上升至50%（Fe0.5-CZ67）時，7.5分鐘六價鉻還原率達到99.76%，反應速率常數k上升至79.29。此結果歸因於鐵和鈷的協同效應。

摘要(英)

This thesis is about to synthesize bimetallic metal-organic framework (MOF) materials and carbonized them to apply on catalytic reactions. Carbonization of MOF materials will makes metal nodes in MOF reduce to metallic states, and the organic linkers will also turn into N-doped carbon material to increase the stability of materials. Fex-ZIF67 was synthesized with 2-methylimidazole and precursors of iron and cobalt, and then carbonized into carbon material Fex-CZ67 in a high-temperature calcining furnace.
The first part of experiment is the Fenton degradation reaction of antibiotics-tetracycline and organic dyes. To adjust the content of cobalt and iron to achieve the best degradation effect, it takes 8.5min to degrade tetracycline completely by CZ-67, and the pseudo-first-order reaction rate constant k is 42.78 (min-1gcat-1); while the k values of Fe0.1-CZ67 and Fe0.2-CZ67 drop to 18.98 and 14.92, respectively. But when the iron content rises to 40 % (Fe0.4-CZ67) has the fastest degradation rate, the degradation rate of tetracycline reaches 94.2% in 3.5 minutes, and the reaction rate constant k reaches 79.54. This result is attributed to the synergistic effect of iron and cobalt, while cobalt probably the main catalytic metal, so Fe0.1-CZ67 and Fe0.2-CZ67 have reduced cobalt content and insufficient iron content to provide a synergistic effect in this reaction.
The second part of the experiment is the reduction reaction of hexavalent chromium. The reduction of hexavalent chromium by CZ-67 takes 135 minutes, and the pseudo-first-order reaction rate constant k is 2.16; when the iron content rises to 50 % (Fe0.5-CZ67) has the fastest reduction rate, the reduction rate of hexavalent chromium reached 99.76% in 7.5 minutes, and the reaction rate constant k increased to 79.29. This result is attributed to the synergistic effect of iron and cobalt.

關鍵字(中)

★ ZIF-67
★ Fenton
★ chromium reduction

關鍵字(英)

論文目次

中文摘要 i
Abstract ii
謝誌 iv
目錄 vi
圖目錄 ix
表目錄 xiii
第一章序論 1
1-1 前言 1
1-2 研究動機及目的 1
第二章材料與文獻回顧 5
2-1 有機金屬骨架材料 5
2-1-1 有機金屬骨架材料之介紹 5
2-1-2 類沸石咪唑骨架材料 8
2-1-3 類沸石咪唑骨架材料-67及衍生物 11
2-1-4 類沸石咪唑骨架衍生碳材-67及衍生物 13
第一部分類沸石咪唑骨架碳化材料之抗生素的降解 16
2-2類沸石咪唑骨架碳化材料之抗生素的降解 16
2-2-1 Fenton反應機制介紹 16
2-2-2 Fenton反應與降解抗生素應用之文獻回顧 17
第二部分類沸石咪唑骨架碳化材料之六價鉻還原 23
2-3 類沸石咪唑骨架碳化材料之六價鉻還原 23
2-3-1 金屬催化之六價鉻還原反應機制介紹 23
2-3-2 金屬催化之六價鉻還原反應文獻回顧 24
第三章實驗方法 30
3-1 實驗藥品 30
3-2 材料合成方法 32
3-2-1 類沸石咪唑骨架材料-67（ZIF-67） 32
3-2-2 含鐵雙金屬類沸石咪唑骨架材料（Fex –ZIF67） 32
3-2-3 類沸石咪唑骨架衍生碳材-67（CZ-67） 32
3-2-4 含鐵雙金屬類沸石咪唑骨架衍生碳材（Fex –CZ67） 32
3-3 材料應用 34
3-3-1 材料對抗生素進行Fenton降解反應與回收再使用實驗 34
3-3-2 材料對有機染料進行Fenton降解反應實驗 34
3-3-3 材料對抗生素進行Fenton降解反應回收效率實驗 34
3-3-4 材料對六價鉻進行還原反應實驗 35
3-3-5 材料對六價鉻進行還原反應回收效率實驗 35
3-4 實驗設備 36
3-4-1 實驗合成設備 36
3-4-2 實驗鑑定儀器 36
3-5 材料性質鑑定 38
3-5-1 氮氣吸脫附等溫曲線（N2-Adsorption-Desorption Isotherm, BET） 38
3-5-2 大角度X光繞射儀（Wide-Angle X-Ray Diffraction, WAXRD） 44
3-5-3 熱重量分析儀（Thermogravimetric Analysis） 45
3-5-4 掃描式電子顯微鏡（Scanning Electron Microscope，SEM） 46
3-5-5 穿透式電子顯微鏡（Transmission Electron Microscope，TEM） 47
3-5-6 X射線光電子能譜儀（X-ray photoelectron spectroscopy, XPS） 48
3-5-7 超導量子干涉磁化儀（Superconducting Quantum Interference Device，SQUID） 49
第四章結果與討論 50
4-1 Fex-ZIF67與Fex-CZ67基本性質鑑定 50
4-1-1 大角度X光繞射圖譜（WAXRD） 50
4-1-2 掃描式電子顯微鏡影像（SEM） 52
4-1-3 穿透式電子顯微鏡影像（TEM） 54
4-1-4 熱重量分析曲線（TGA） 62
4-1-5 氮氣吸脫附等溫曲線（N2-Adsorption-Desorption Isotherm） 65
4-1-6 超導量子干涉磁化圖譜（SQUID） 69
4-1-7 X射線光電子能譜圖（XPS） 70
第一部分雙金屬類沸石咪唑骨架碳化材料之抗生素的降解 72
4-2 Fex-CZ67催化抗生素與有機染料之Fenton降解反應 72
4-2-1 Fex-CZ67對抗生素之Fenton降解反應 73
4-2-2 Fex-CZ67對有機染料之Fenton降解反應 77
4-2-3 Fe0.4-CZ67對抗生素之Fenton降解反應回收效率 80
第二部分雙金屬類沸石咪唑骨架碳化材料之六價鉻還原 81
4-3 Fex-CZ67催化六價鉻還原反應 81
4-3-1 Fex-CZ67催化六價鉻還原 82
4-3-2 Fe0.5-CZ67催化六價鉻還原之回收效率 85
第五章結論 87
第六章參考資料 88

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指導教授

高憲明

審核日期

2022-7-27

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