2-丙烯醯胺基-2-甲基丙磺酸共聚之離子高分子之製備

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曹昀翔(CAO,YUN-XIANG) 查詢紙本館藏

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論文名稱

2-丙烯醯胺基-2-甲基丙磺酸共聚之離子高分子之製備

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至系統瀏覽論文 (2027-7-19以後開放)

摘要(中)

本論文提供一快速、低成本、高離子含量、高吸水性並可使用常用溶劑即可進行溶解之兩性離子聚合物之合成策略。首先使用2-丙烯醯胺基-2-甲基丙磺酸 (2-acrylamido-2-methylpropane sulfonic acid, AMPS ) 與1-乙烯基-3-己基咪唑溴鹽(1-hexyl-3-vinylimidazolium bromide, Vim6C) 為陰、陽離子單體，製備第一系列兩性離子聚合物-PAMPSIm。藉由調控陰、陽離子單體莫耳比，可開發出不同離子比例之離子高分子。目前PAMPSIm已成功分別合成出AMPS莫耳百分比為 30%、50%、70% 之比例。此系列高分子具有極高之離子交換容量最高可達4.49 meq/g，同時此新開發之離子高分子皆能溶於甲醇，成膜後展現極高之吸水膨潤比 (356%)。
另以2-丙烯醯胺基-2-甲基丙磺酸( AMPS )與丙烯酸羥乙酯( HEA )及乙氧基乙氧基乙基丙烯酸酯( Agisyn™ 2880 )開發第二系列共聚物PAMPSEO，目前鋰化後所得含鋰離子之PAMPSEOLi系列高分子，可作為鋰離子電池之固態電解質。此系列高分子已送往合作實驗室進行摻雜製備電池元件，等待後續電池效能檢測。

摘要(英)

This study provides a new strategy for the synthesis of a cost-effective, highly ionic, and highly water uptake ampholytic polymer that is soluble in common organic solvents. The first series of ampholytic polymer, PAMPSIm, was prepared by UV-initiated free-radical polymerization of anionic monomer, 2-acrylamido-2-methylpropane sulfonic acid (AMPS), and cationic monomer 1-hexyl-3-methyl imidazolium (Vim6C). Via modulation of the ratio of anion and cation monomers, PAMPSIm has been successfully synthesized with the molar ratios of 30%, 50% and 70% of AMPS monomers. The theoretical ion exchange capacity (IEC) has been calculated and reached up to 4.49 meq/g with a greater water uptake of 356%. All PAMPSIm series polymers are soluble and good film-forming in methanol
The second two series of copolymer, PAMPSEO and PAMPSEO3, were prepared by polymerization of AMPS with hydroxyl ethyl acrylate (HEA) and ethoxyethoxy ethyl acrylate (Agisyn™ 2880), respectively. Further, these copolymers were lithiated to obtain their corresponding lithium salts, PAMPSEOLi and PAMPSEO3Li, to serve as solid electrolytes for lithium ion batteries. Currently, the lithium ion battery performance testing of these lithiated copolymers are in progress.

關鍵字(中)

★ 離子聚合物
★ 聚合物電解質
★ 電解水產氫
★ 鋰電池固態電解質

關鍵字(英)

論文目次

目錄
摘要 i
Abstract ii
謝誌 iii
目錄 iv
表目錄 ix
圖目錄 x
Scheme xv
Equation xvi
附錄目錄 xviii
重要名詞縮寫對照表 xix
第一章緒論 1
1-1 前言--離子交換高分子化合物（Ion-exchange Polymer） 2
1-2 再生能源-氫能簡介 4
1-3 氫氣製造技術--水電解法 (Water Splitting by Electrolysis) 8
1-4 鋰離子電池運作原理 15
1-4-1 液態電解質 17
1-4-2 聚合物固態電解質 19
第二章文獻回顧 21
2-1 離子交換膜簡介 22
2-2 陰離子交換膜 23
2-3 陽離子交換膜 23
2-4 雙極離子交換膜 31
2-5 兩性離子交換膜 35
2-6 鋰離子電池固態電解質 38
第三章研究動機與目的 44
3-1 研究動機 44
3-2 陰離子交換基團的穩定性 47
3-3 陽離子交換基團的穩定性 54
3-4 實驗室聚合經驗彙整 56
3-5陰離子基團單體選擇 57
3-6陽離子基團單體選擇 62
第四章實驗與儀器 65
4-1 實驗藥品 66
4-1-1 實驗所使用之化學藥品 66
4-1-2 實驗所使用之溶劑 67
4-2 實驗儀器及技術原理 68
4-2-0 Brightek UV面光源機 68
4-2-1 核磁共振光譜儀 (Nuclear Magnetic Resonance)；Bruker AVANCE 300 / 500MHz 68
4-2-2 熱重分析儀 (Thermal Gravimetric Analysis, TGA)； Mettler Toledo TGA/SDTA 851 69
4-2-3 交流阻抗儀 (Alternating Current Impedance)；Autolab Pgstat 30 AUT system 71
4-2-4 吸水膨潤比 (Water Uptake) 與尺寸變化率 (Swelling Ratio) 72
4-2-5 離子交換容量 (Ion Exchange Capacity, IEC) 73
4-2-6 化學穩定性 (Chemical stability) 75
4-3 高分子合成後處理 75
4-3-1 高分子薄膜的製備 75
4-3-2 高分子薄膜的鹼化 75
4-3-3 高分子薄膜的酸化 76
4-4 合成步驟 76
4-4-1 1-hexyl-3-vinylimidazolium bromide (Vim6C) 的合成 76
4-4-2 PAMPS 的合成 78
4-4-3 PNIm 的合成 79
4-4-4 PAMPSNIm 30/70/50的合成 79
4-4-5 PAMPSEO 70/50 的合成 81
4-4-6 PAMPSEOLi 70/50 的合成 82
4-4-7 PAMPSEO3 70/50 的合成 83
4-4-8 PAMPSEO3Li 70/50的合成 84
4-4-9 PAMPSNImH 30/50/70的合成 85
第五章結果與討論 88
5-1 PAMPSNIm 系列之合成及討論 88
5-1-1 PAMPSNIm 30/70/50 的 1H 核磁共振光譜結構探討 93
5-1-2 PAMPSNIm 傅立葉變換紅外光譜（FTIR ）光譜探討 94
5-1-3 熱穩定性 (Thermal Stability) 95
5-1-4 離子交換容量 (Ion Exchange Capacity, IEC) 96
5-1-5 尺寸變化率 (S.R.) 與吸水膨潤比 (W.U.) 97
5-1-6 化學穩定性 (Chemical Stability) 98
5-1-7 離子導電度 (Ion Conductivity) 101
5-3 PAMPSEOLi 系列之合成及討論 101
5-3-1 PAMPSEO 的 1H 核磁共振光譜結構探討 104
5-3-2 熱穩定性 (Thermal Stability) 104
5-3-3 電池元件測試 105
第六章結論 106
補充資料 109
電解水產氫 109
其他電池 112
阻垢劑 115
參考文獻 116
附錄 123

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指導教授

陳銘洲(Ming-Chou Chen)

審核日期

2022-7-28

推文