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姓名 吳承翰(Cheng-Han Wu) 查詢紙本館藏 畢業系所 物理學系 論文名稱 Na-FeFe普魯士藍粒徑對二次鋰電池研究及應用 相關論文 檔案 [Endnote RIS 格式]
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摘要(中) 普魯士藍的晶體結構具有將電池內游離的離子進行儲存的功能，且中心孔洞較大，能放入大多數的鹼金屬離子。晶體的結構也較穩定，進行多次的氧化還原反應，結構不容易改變，也就是相當於可充放電循環次數較多。普魯士藍的製作方式簡單、成本低、環保及理論電容量較大，是二次電池裡具有潛力的負極材料。
本實驗是沉澱法製作出樣品。在不同製程溫度下Na-FeFe普魯士藍會有不同的粒徑，利用X光繞射儀掃描Na-FeFe普魯士藍樣品，掃出來的X光繞射譜圖再用General Structure Analysis System (GSAS)結構精算軟體，以進行粒徑大小及特性分析。
進行二次鋰離子電池製備後，放入充放電儀以進行定電流充放電實驗。充放電測試完後，將其數據進行電池微分曲線圖、電壓曲線圖、電容曲線圖及電壓流程圖，以得知Na-FeFe普魯士藍二次鋰電池在不同粒徑的條件下其充放電效率如何，在變電流的情況下，對電池的充放電影響，和若是將電池停止充放電一天後，充放電效率會變得如何。摘要(英) The crystal structure of Prussian blue has the function of storing free ions in the battery, and the central hole is large, which can accommodate most alkali metal ions. The structure of the crystal is also relatively stable, and the structure is not easily changed after repeated redox reactions, which is equivalent to a large number of charge-discharge cycles. Prussian blue has the advantages of simple production method, low cost, environmental protection and large theoretical electric capacity. It is a potential negative electrode material in secondary batteries.
In this experiment, the samples were prepared by the precipitation method. Na-FeFe Prussian blue will have different particle sizes at different process temperatures. The Na-FeFe Prussian blue sample is scanned with an X-ray diffractometer, and the scanned X-ray diffraction spectrum is then used to structure the General Structure Analysis System (GSAS) Actuarial software for particle size and characteristic analysis.
After the secondary lithium-ion battery was prepared, it was put into a charge-discharge apparatus to conduct a constant-current charge-discharge experiment. After the charge and discharge test is completed, the data is subjected to the battery differential curve, voltage curve, capacitance curve and voltage flow chart to know the charge and discharge efficiency of the Na-FeFe Prussian blue secondary lithium battery under the conditions of different particle sizes. How, in the case of variable current, the impact on the charging and discharging of the battery, and how the charging and discharging efficiency will become if the battery is stopped for one day after charging and discharging.關鍵字(中) ★ 普魯士藍
★ 鋰電池關鍵字(英) ★ Prussian blue
★ lithium battery論文目次 論文摘要 i
Abstract ii
致謝 iii
目錄 iv
圖目錄 vi
表目錄 xii
第一章 普魯士藍與儀器介紹 1
1-1 普魯士藍介紹 1
1-2 鋰電池介紹 3
1-3 X光繞射儀 6
1-4電池充放電測試儀 8
第二章 Na-FeFe普魯士藍製備與分析 10
2-1 Na-FeFe普魯士藍樣品製備 10
2-2 Na-FeFe普魯士藍化學成分、結構及粒徑分析 12
第三章 二次鋰電池製備 42
3-1 CR2032電池樣品結構 42
3-2 Na-FeFe陰極極片製作 45
3-3 CR2032電池樣品製作 47
3-4 單一極片普魯士藍含量計算 49
第四章 Na-FeFe二次鋰電池充放電分析 56
4-1 Na-FeFe二次鋰電池充放電循環的比較 56
4-2 Na-FeFe二次鋰電池充放電效率 60
4-3 Na-FeFe二次鋰電池充放電穩定度分析 68
第五章 充放電流程對Na-FeFe二次鋰電池影響 70
5-1 改變電流對普魯士藍鋰電池充放電影響 70
5-2 停止充放電循環對普魯士藍電池影響 82
第六章 結論 86
參考文獻 88參考文獻 [1] Lian Shen, Zhaoxiang Wang and Liquan Chen, Chem. Eur. J. 2014, 20,12559-12562
[2] Dezhi Yang, Jing Xu, Xiao-Zhen Liao, Yu-Shi He, Haimei Liu and Zi-Feng Ma, Chem. Commun., 2014,50, 13377-13380
[3] Jiahuan Luo, Shixiong Sun, Jian Peng, Bo Liu, Yangyang Huang, Kun Wang, Qin Zhang, Yuyu Li, Yu Jin, Yi Liu, Yuegang Qiu, Qing Li, Jiantao Han, and Yunhui Huang, ACS Appl. Mater. Interfaces 2017, 9, 30, 25317–25322
[4] Dean M. DeLongchamp and Paula T. Hammond, Adv. Funct. Mater., 2004, 14, 224
[5] Ya You, Xing-Long Wu, Ya-Xia Yin& Yu-Guo Guo. Energy Environ. Sci., 2014,7, 1643-1647
[6] Li-Ping Wang, Peng-Fei Wang, Tai-Shan Wang, Ya-Xia Yin, Yu-Guo Guo, Chun-Ru Wang, Journal of Power Sources, Vol 355, 1 July 2017, 18-22
[7] Wang, B., Han, Y., Wang, X., Bahlawane, N., Pan, H., Yan, M., Jiang, Y.,Prussian blue analogues for rechargeable batteries, ISCIENCE (2018),
[8] GSAS H. M. Rietveld, J. Appl. Cryst., 1969, 65-71
[9] Baoqi Wang, Yu Han, Xiao Wang, Naoufal Bahlawane, Hongge Pan, Mi Yan, Yinzhu Jiang, iScience, Vol 3, 25 May 2018, 110-133
[10] Dr. Lian Shen, Prof. Zhaoxiang Wang, Prof. Liquan Chen, Chemistry-A European Journal, Vol 20, 12559-12562, August 2014
[11] Lan Li, Ping Nie, Yubo Chenc and Jie Wang, J. Mater. Chem. A, 2019,7, 12134-12144
[12] Carissa H. Li,a Yusuke Nanba, Daisuke Asakura, Masashi Okubo and Daniel R. Talham, RSC Adv., 2014,4, 24955-24961
[13] Daisuke Asakura, Carissa H. Li, Yoshifumi Mizuno, Masashi Okubo, Haoshen Zhou, and Daniel R. Talham, J. Am. Chem. Soc. 2013, 135, 7, 2793–2799指導教授 李文献(Wen-Hsien Li) 審核日期 2022-7-11 推文 plurk
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