博碩士論文 110324063 詳細資訊




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姓名 賴奕銘(Yi-Ming Lai)  查詢紙本館藏   畢業系所 化學工程與材料工程學系
論文名稱 聚苯乙烯高分子-奈米粒子複合材料的黏度降低機制之研究
(Study on the Mechanism of Viscosity Reduction in Polystyrene Polymer-Nanoparticle Composites)
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檔案 [Endnote RIS 格式]    [Bibtex 格式]    [相關文章]   [文章引用]   [完整記錄]   [館藏目錄]   至系統瀏覽論文 (2028-8-31以後開放)
摘要(中) 將微米和奈米尺度的顆粒添加到高分子基質中通常會增加複合材料的黏度。不過,研究發現添加奈米顆粒於基質有可能反而造成複合物的黏度下降。對於造成黏度降低的機制目前尚未完全理解,為了解決這個問題,我們的研究旨在探究複合物黏度的降低可能來自於空間排列的變化。同時,我們還探索了複合物的宏觀性質變化,如熱性質和流變性質等,這些都是為了釐清黏度降低的機制。我們合成了不同尺寸的聚苯乙烯奈米顆粒,並將其分散在分子量低於或高於纏結臨界值的聚苯乙烯基質中。我們發現黏度下降的行為僅發生於纏結基質系統,並觀察到黏度降低約90 %。透過小角度和廣角度X射線散射實驗,我們認為奈米粒子的添加可能會影響分子鏈的結構排列。對於纏結分子鏈,粒子可能減弱糾纏的密度而增強鏈的流動性。透過結合微觀的分子排列行為與宏觀的黏度特性表現,我們希望建立這些性質之間的相關性,從而解釋黏度降低的機制。
摘要(英) The addition of micro- and nanoscopic particles to a polymer matrix typically increases the viscosity of the composite material. However, the studies have found that adding nanoparticles to the matrix may result in the viscosity reduction of the composite. The mechanism responsible for the viscosity reduction is not fully understood. To address this issue, our study aims to investigate how changes in spatial arrangement may contribute to the viscosity reduction. Also, we explore the macroscopic properties change of the composite, such as thermal and rheological properties, all in an effort to understand the mechanism behind the viscosity reduction. We synthesized the polystyrene nanoparticles with different sizes and dispersed them in the polystyrene matrix with the molecular weight below or above the entanglement threshold. We found that the viscosity reduction behavior only occurred in the entangled matrix system, and observed a viscosity decrease of approximately 90 %. Through the small-angle and wide-angle X-ray scattering experiments, we thought that the addition of nanoparticles may affect the structural arrangement of molecular chains. For the entangled molecular chains, the particles may weaken the density of entanglement and enhance the mobility of the chains. By combining the microscopic molecular arrangement behavior with the macroscopic viscosity characteristics, we hope to establish the correlation between these properties and thereby explain the mechanism of the viscosity reduction.
關鍵字(中) ★ 聚苯乙烯
★ 複合材料
★ 黏度降低
★ 高分子奈米複合材料
關鍵字(英) ★ polystyrene
★ composite
★ viscosity reduction
★ polymer nanocomposite
論文目次 目錄
摘要 i
Abstract ii
誌謝 iii
目錄 iv
圖目錄 vii
表目錄 xiv
一、緒論 1
1.1簡介 1
1.2研究目的及動機 2
二、文獻回顧 3
2.1複合材料 3
2.2奈米複合材料 4
2.3複合材料之流動特性 6
2.4異常黏度行為及可能機制 8
2.4.1自由體積理論 8
2.4.2基質纏結與解纏結效應 10
2.4.3奈米粒子空間限制性 14
2.4.4弛豫行為的約束釋放 16
2.4.5黏度下降機制整理與討論 18
2.5實驗製備 20
三、實驗製備與儀器測量 28
3.1實驗藥品 28
3.2樣品製備 30
3.2.1共聚高分子鏈合成 30
3.2.2奈米粒子交聯合成 33
3.2.3複合材料合成 35
3.2.4樣品資訊 38
3.2.4.1共聚高分子鏈 38
3.2.4.2奈米粒子 39
3.2.4.3高分子基質 40
3.2.4.4複合材料 40
3.3實驗儀器 41
3.4儀器原理介紹 43
3.4.1核磁共振光譜儀 43
3.4.2膠體滲透層析儀 46
3.4.3動態光散射儀 48
3.4.4掃描穿透式電子顯微鏡 51
3.4.5小角度及廣角度X光散射儀 54
3.4.6差示掃描量熱儀 59
3.4.7流變儀 62
四、結果與討論 68
4.1奈米粒子合成 68
4.1.1 NMR分析 68
4.1.2 GPC分析 73
4.2奈米粒子的性質分析 76
4.2.1 DLS分析 76
4.2.2 STEM分析 79
4.2.3 SAXS分析 82
4.3複合材料的型態分析 84
4.3.1 SAXS分析 84
4.3.2 WAXS分析 91
4.4複合材料的熱性質分析 101
4.5複合材料的流變分析 106
五、結論 117
參考文獻 118
附錄一、應變掃描測試 129
附錄二、平移因子方程式擬合 133
附錄三、複合物散射圖譜 137
附錄四、廣角度散射擬合 141
附錄五、樣品DSC熱流圖 145
附錄六、流變模量圖與黏度圖 150
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指導教授 陳儀帆(Yi-Fan Chen) 審核日期 2023-8-11
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