以染料HBC-23為主敏化劑並以共敏化劑或共吸附劑組裝太陽能電池元件之組裝優化之研究

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陳柏均(Po-Chun Chen) 查詢紙本館藏

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論文名稱

以染料HBC-23為主敏化劑並以共敏化劑或共吸附劑組裝太陽能電池元件之組裝優化之研究

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至系統瀏覽論文 (2025-9-25以後開放)

摘要(中)

本研究針對實驗室所開發之釕錯合物錯合物染料 HBC-23 進行元件組裝條件優化，並使用紫質染料 YD-2 或本實驗室合成之染料BTI-7/POEt/JIA-SQ-1/DUY-1 做為共敏化劑，以提高所組裝電池的效率及穩定性。本研究也使用共吸附劑 CDCA 或後吸附劑 PVA、OPA、TMEA-TMOS、TEOS 等方法來組裝元件。結果顯示只以HBC-23 為敏化劑所組裝之元件的最高效率為 8.29%，與 HBC-23 搭配最良好的共敏化劑為 YD-2，以 HBC-23 為主敏化劑 YD-2 為共敏化劑所組裝之電池最高效率為 7.95%。電池之 IPCE 光譜顯示當主敏化劑為 HBC-23，共敏化劑為 YD-2 之電池在 650 nm ~ 700 nm 處之IPCE 值最高上升了約 15%，且主敏化劑為 HBC-23 共敏化劑為 YD2 所組裝之電池長時間穩定性較只以 HBC-23 為敏化劑所組裝之元件好。電池組裝完在大氣中之黑暗環境下置放 500 個小時後，有使用
YD-2 之電池仍維持 7.57%的效率(跌幅約 5%)，而同樣條件下使用單一 HBC-23 染料組裝之電池效率則下降了 13%，其原因為當使用共敏化時，光電極上之總染料吸附量由 2.12 × 10-8 mole cm-2 µm-1上升至 2.94 × 10-8 mole cm-2 µm-1，使電解液內造成效率下降之離子IO3-較難吸附於覆蓋率較好的二氧化鈦表面上。

摘要(英)

In this study, we focused on optimizing the device assembly conditions for the ruthenium complex dye HBC-23, developed in our laboratory. We also employed the commercial porphyrins dye YD-2 or the dyes developed in our lab BTI-7/POEt/JIA-SQ-1 as co-sensitizers to improve the cell efficiency and stability of DSC. Futhermore, co-adsorbents CDCA or postadsorbents PVA, OPA, TMEA-TMOS, and TEOS were also tested. The highest efficiency of DSC based on only HBC-23 sensitizer is 8.29%.While the best-performing of HBC-23 co-sensitizer with YD-2 resulted in
a maximum cell efficiency of 7.95%. The IPCE spectra of the cells revealed that the IPCE value at 650-700 nm increased by approximately 15% when HBC-23 was used as the main sensitizer and YD-2 as the co-sensitizer. The long-term stability test of the cells showed that when HBC-23 is the main sensitizer and YD-2 is the co-sensitizer, the cell maintained an efficiency of 7.57% (decreased by 5%) after being placed in a dark environment in the atmosphere for 500 hours. However, the efficiency of the cell assembled with HBC-23 dye decreased by 13% under the same conditions.
The reason is that when using the co-sensitizer YD-2, the total dye adsorption on the photoelectrode increased from 2.12 × 10-8 mole cm-2 µm1 to 2.94 × 10-8 mole cm-2 µm-1
. The increase of dyes absorbed on TiO2 makes it more difficult for the IO3- molecules , which is in electrolyte and is harmful to the efficiency of the cell , to adsorb onto the better-covered titanium dioxide surface. As a result, the stability of the cell that use YD-2 as co-sensitizer is improved.

關鍵字(中)

★ 染料敏化太陽能電池

關鍵字(英)

★ dye-sensitized solar cell

論文目次

中文摘要 I
Abstract II
圖摘要 III
謝誌 IV
目錄 V
圖目錄 XI
表目錄 XV
第一章、序論 1
1-1 前言 1
1-2 染料敏化太陽能電池工作原理 1
1-3 染料敏化太陽能電池構造 4
1-4 光電極(Photo electrode) 5
1-4-1 光電極中TiO2膜的作用 5
1-4-2染料(Dye) 5
1-4-3 共吸附劑(co- adsorbent) 13
1-4-4 後吸附劑(post- adsorbent) 14
1-5 對電極 17
1-6 電解質 18
1-6-1液態電解質中之氧化還原對 18
1-6-2電解質添加劑 19
1-7 研究動機 22
第二章、實驗方法 25
2-1 實驗藥品與儀器 25
2-2 染料敏化太陽能電池的組裝 28
2-2-1 光電極的製備 28
2-2-2 測量「染料吸附於二氧化鈦膜上吸收」之光電極製備 29
2-2-3 Pt 對電極的製備 29
2-2-4 染料溶液的配製 30
2-2-5 電解液的配製 30
2-2-6 太陽能電池組裝及效率量測 30
2-2-7 共吸附劑的使用方法 31
2-2-8 後吸附劑的使用方法 32
2-2-9 共敏化劑的使用方法 32
2-3 儀器分析與樣品製備 33
2-3-1 太陽光模擬器 (Solar Simulator, YSS-50A)及光電轉換效率測量 33
2-3-2太陽能電池外部量子效率量測(Incident Photon to Current Conversion Efficieny, IPCE, ENLI Technology Co. Ltd., EQE-R-3011) 34
2-3-3 交流阻抗分析儀(AC-Impedance analysis, Autolab PGSTAT30) 36
2-3-4光強度調制光電流/光電壓分析儀(Intensity modulated photocurrent spectroscopy (IMPS) / Intensity modulated photovoltage spectroscopy (IMVS))；Charge extraction, LD80226) 38
2-3-5 探針式輪廓儀 (Surface Profiler ; Veeco Dektak 150) 39
2-3-6紫外光/可見光/近紅外光吸收光譜(UV/VIS/NIR Spectrometer, Bio CARY300) 40
2-3-7 分子體積與表面積分析 42
第三章、結果與討論 43
3-1 以 HBC-23 為敏化劑的太陽能電池之電解質添加劑濃度優化 43
3-1-1 電解質添加劑BMII濃度調整 43
3-1-2 電解質添加劑LiI濃度調變 44
3-1-3 電解質添加劑tBP濃度調變 46
3-1-4 電解質I2濃度調變 47
3-2 以 HBC-23 為敏化劑的太陽能電池之對電極燒結溫度之優化 48
3-2-1 對電極燒結溫度調變 48
3-3 以 HBC-23 為敏化劑的太陽能電池之染料溶液濃度之優化 51
3-4 以HBC-23為敏化劑的太陽能電池之二氧化鈦膜之製作流程優化 53
3-4-1 二氧化鈦膜厚的調變 53
3-5 以染料HBC-23為敏化劑，並使用共吸附劑或後吸附劑所組裝之元件的光電表現與吸光性質 55
3-5-1 以CDCA、PVA、OPA為共吸附劑所組裝之元件效率 55
3-5-2 以PVA、OPA、TEOS、TMEA-TMOS為後吸附劑所組裝之元件效率 58
3-5-3 HBC-23使用不同後吸附劑吸附於二氧化鈦之光學性質量測 64
3-6 以染料HBC-23為主敏化劑，並使用BTI-7、YD-2、POEt、JIA-SQ1、DUY-1做為共敏化劑的太陽能電池之優化 65
3-6-1以染料HBC-23為主敏化劑，並使用BTI-7為共敏化劑的太陽能電池之優化 66
3-6-2以染料HBC-23為主敏化劑，並使用POEt為共敏化劑的太陽能電池之優化 75
3-6-3 以HBC-23為主敏化劑，並使用DUY-1為共敏化劑之太陽能電池之優化 80
3-6-4 以HBC-23為主敏化劑，並使用JIA-SQ1為共敏化劑之太陽能電池之優化 83
3-6-5以染料HBC-23為主敏化劑，並使用YD-2為共敏化劑的太陽能電池之優化 86
3-7 HBC-23、DUY-1、YD-2、BTI-7、POEt、JIA-SQ-1之吸光性質與在二氧化鈦上之吸附情形 102
3-7-1 HBC-23與其它染料之溶液UV-Vis圖比較 102
3-7-2 HBC-23與YD-2共敏化之光學性質與在二氧化鈦上之吸附量探討 103
3-8 以染料HBC-23為主敏化劑，並使用YD-2做為共敏化劑及以單一敏化劑HBC-23或YD-2所組裝之元件的光電表現 108
3-8-1 以染料HBC-23為主敏化劑，並使用YD-2做為共敏化劑及以單一敏化劑HBC-23所組裝之元件之內部電阻探討 108
3-8-2 以染料HBC-23為主敏化劑，並使用YD-2做為共敏化劑及以單一敏化劑HBC-23所組裝之元件的二氧化鈦膜上之電子生命期 110
3-8-3 以染料HBC-23為主敏化劑，並使用YD-2做為共敏化劑及以單一敏化劑HBC-23所組裝之元件之二氧化鈦膜上的擴散係數 112
3-8-4以染料HBC-23為主敏化劑，並使用YD-2做為共敏化劑及以單一敏化劑HBC-23或YD-2所組裝之元件長時間穩定性 114
3-8-5以染料HBC-23為主敏化劑，並使用YD-2做為共敏化劑及以單一敏化劑HBC-23所組裝之元件的元件效率的再現性 118
3-9 當使用共敏化劑時元件效率下降原因 121
第四章、結論 123
結論圖 124
參考文獻 125
附錄 131

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指導教授

吳春桂(Chun-Guey Wu)

審核日期

2023-12-7

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