Isothermal vapor-liquid equilibria for binary mixtures of hexane, heptane, octane, nonane and cyclohexane at 333.15 K, 343.15 K and 353.15 K

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题名:	Isothermal vapor-liquid equilibria for binary mixtures of hexane, heptane, octane, nonane and cyclohexane at 333.15 K, 343.15 K and 353.15 K
作者:	Lee,KJ;Chen,WK;Ko,JW;Lee,LS;Chang,CMJ
贡献者:	化學工程與材料工程學系
关键词:	EXCESS GIBBS ENERGY;SYSTEMS;EXPRESSION;EQUATION;MODEL;NRTL;CO2
日期:	2009
上传时间:	2010-06-29 17:27:21 (UTC+8)
出版者:	中央大學
摘要:	Isothermal vapor-liquid equilibria at 333.15 K, 343.15 K and 353.15 K far four binary mixtures of hexane + heptane, heptane + octane, cyclohexane + octane and cyclohexane + nonane have been obtained at pressures ranged from 0 to 101.3 kPa. The NRTL, UNIQUAC and Wilson activity coefficient models have been employed to correlate experimental pressures and liquid mole fractions. The non-ideal behavior of the vapor phase has been considered by using the Soave-Redlich-Kwong equation of state in calculating the vapor mole fraction. Liquid and vapor densities were also measured by using two vibrating tube densitometers. Phase behaviors of the P-x-y diagrams indicate that three mixtures of hexane + heptane, heptane + octane, cyclohexane + octane were close to the ideal solution. However, the cyclohexane + nonane mixture presents a large positive deviation from the ideal solution. Only the cyclohexane + octane mixture is negative in the excess Gibbs energy indicates that it is an exothermic system. (C) 2009 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
關聯:	JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
显示于类别:	[化學工程與材料工程研究所] 期刊論文

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