English  |  正體中文  |  简体中文  |  Items with full text/Total items : 69561/69561 (100%)
Visitors : 23267291      Online Users : 550
RC Version 7.0 © Powered By DSPACE, MIT. Enhanced by NTU Library IR team.
Scope Tips:
  • please add "double quotation mark" for query phrases to get precise results
  • please goto advance search for comprehansive author search
  • Adv. Search
    HomeLoginUploadHelpAboutAdminister Goto mobile version


    Please use this identifier to cite or link to this item: http://ir.lib.ncu.edu.tw/handle/987654321/26420


    Title: Preparation of NiFeB Nanoalloy Catalysts and Their Applications in Liquid-Phase Hydrogenation of p-Chloronitrobenzene
    Authors: Chen,YW;Sasirekha,N
    Contributors: 化學工程與材料工程學系
    Keywords: SUPPORTED PLATINUM CATALYSTS;AMORPHOUS ALLOY CATALYST;SELECTIVE HYDROGENATION;O-CHLORONITROBENZENE;NI-B;SYNTHESIS PARAMETERS;ULTRAFINE MATERIALS;FE;CO;NANOPARTICLES
    Date: 2009
    Issue Date: 2010-06-29 17:27:39 (UTC+8)
    Publisher: 中央大學
    Abstract: A series of NiFeB nanoalloy catalysts were prepared by chemical reduction method using metal acetates as the starting materials, and NaBH4 as the reducing agent. The amorphous metal materials, combining the features of amorphous and nanometer materials, have more surface atoms and a higher concentration of coordinately highly unsaturated sites. Sodium borohydride in excess amount was added dropwise into the mixture to ensure full reduction of metal cations. The catalysts were characterized with X-ray diffraction, nitrogen sorption, transmission electron microscopy, and X-ray photoelectron spectroscopy. The hydrogenation of p-chloronitrobenzene was carried out in a batch reactor at 1.2 MPa H-2 pressure and 323-393 K. The Ni/Fe molar ratios in the starting materials affected the concentration of boron bounded to the nickel and iron metals, resulting in the difference in surface area, electronic structures of the metals, and the catalytic activities of the catalysts. The addition of iron in NiB catalyst could reduce the particle of the nickel metal, suppress the growth of crystalline structure of NiFeB, and help the NiFeB catalyst to maintain its amorphous state. Oil the basis of the electron transfer between elemental nickel and boron, Ni in NiFeB had more d-band electrons and higher electron density than in NiB; therefore, it also has higher activities of hydrogenation of the nitro group than does NiB.
    Relation: INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
    Appears in Collections:[化學工程與材料工程研究所] 期刊論文

    Files in This Item:

    File Description SizeFormat
    index.html0KbHTML395View/Open


    All items in NCUIR are protected by copyright, with all rights reserved.

    社群 sharing

    ::: Copyright National Central University. | 國立中央大學圖書館版權所有 | 收藏本站 | 設為首頁 | 最佳瀏覽畫面: 1024*768 | 建站日期:8-24-2009 :::
    DSpace Software Copyright © 2002-2004  MIT &  Hewlett-Packard  /   Enhanced by   NTU Library IR team Copyright ©   - Feedback  - 隱私權政策聲明