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    Please use this identifier to cite or link to this item: http://ir.lib.ncu.edu.tw/handle/987654321/26433


    Title: Studies on the Preparation and Properties of Sol-Gel Molecularly Imprinted Polymer Based on Tetramethoxysilane and Methyltrimethoxysilane for Recognized Sulfonamides
    Authors: Lee,SC;Peng,CL;Chen,H
    Contributors: 化學工程與材料工程學系
    Keywords: PLASTIC ANTIBODIES;PHASE EXTRACTION;SILICA-GEL;SULFAMETHAZINE;SELECTIVITY;CAFFEINE;PERFORMANCE;ADSORPTION;SEPARATION;DESIGN
    Date: 2009
    Issue Date: 2010-06-29 17:27:57 (UTC+8)
    Publisher: 中央大學
    Abstract: The synthesis of a molecularly imprinted polymer (MIP) composed of tetramethoxysilane (TMOS) and methyltrimethoxysilane (MTMOS) for recognized sulfonamides by sol-get process has been investigated. The MIP's preparation conditions, the H2O/Si molar ratios (R), pH value of competition solution, calcination temperature, and the TMOS and MTMOS molar fractions are discussed. Adsorption and selectivity in different pH solutions were determined by competition experiments between the MIP template (sulfamethazine, SMZ) and the analogue (sulfamethoxazole, SMO) using High-Performance Liquid Chromatography (HPLC). The results show that the selectivity of the MIP in competition solution with pH = 7.4 was higher than that with pH = 4.6. In addition, the second stage temperature of calcination. which was carried out at 375 degrees C, was obtained high selectivity. Moreover, the selectivity of the MIP (10.5) was approximately 3.5 times greater than the nonimprinted polymer (3.72) under the optimum preparation conditions.
    Relation: POLYMER JOURNAL
    Appears in Collections:[化學工程與材料工程研究所] 期刊論文

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