Dopant effects and conductivity studies on a new high voltage cathode material with inverse spinel structure

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题名:	Dopant effects and conductivity studies on a new high voltage cathode material with inverse spinel structure
作者:	Fey,GTK;Wu,CS
贡献者:	化學工程與材料工程學系
关键词:	LITHIUM
日期:	1997
上传时间:	2010-06-29 17:30:43 (UTC+8)
出版者:	中央大學
摘要:	The dopant effects of introducing rare earth atoms into the LiNiVO4 inverse spinel structure were studied by measuring electrical conductivity of LiNiVO4 as a function of temperature, type of dopants, and dopant mole ratio. The dopant mole ratios of LiNiVO4 to Ln (where Ln = La, Gd or Yb) used in the reactions of LiNiVO4 and Ln(2)O(3) ranged from 1 x 10(6) to 1 x 10(2). Using a d.c. polarization method, the best improvement in conductivity was achieved by the smallest Yb-doped samples at 25 degrees C, an increase from 10(-10) to 10(-7) S/cm at a mole ratio of LiNiVO4:Yb = 10(4). They maintained high conductivity of 10(-7) S/cm up to a mole ratio of 10(2). From 10 degrees C to 50 degrees C, the medium Gd-doped samples reached their highest conductivity, ranging from 6.21 x 10(-7) to 3.52 x 10(-7) S/cm when the mole ratio was 10(4), but beyond that conductivity declined sharply to 10(-10) S/cm. At 25 degrees C, the largest La-doped samples showed only a slight increase in conductivity from 10(-9) to 10(-8) S/cm at a mole ratio of 10(4), much lower than 2.21 x 10(-6) S/cm measured by a pseudo a.c. non-polarization method. During the doping process at lower dopant concentrations, activation energy decreased as concentration increased, but it remained virtually constant at higher dopant concentrations due to the reactions between LiNiVO4 and the dopants.
關聯:	PURE AND APPLIED CHEMISTRY
显示于类别:	[化學工程與材料工程研究所] 期刊論文

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