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    Please use this identifier to cite or link to this item: http://ir.lib.ncu.edu.tw/handle/987654321/26642


    Title: Methylation of aniline over SAPO-11
    Authors: Yang,SM;Pan,TW
    Contributors: 化學工程與材料工程學系
    Keywords: N/A
    Date: 1995
    Issue Date: 2010-06-29 17:33:07 (UTC+8)
    Publisher: 中央大學
    Abstract: Methylation of aniline over a mildly acidic siliconaluminium phosphate catalyst (SAPO-11) with medium pores is reported. The selectivity of N-methylates products is about 90%. By comparison with results obtained from SAPO-5 with large pores and with amorphous aluminium phosphate, molecular sieves with medium pores prevent the formation of bulky isomers and better resist formation of coke. The ortho isomer is most abundant among toluidine isomers. Some ortho isomers may result from the rearrangement of N-methylaniline.
    Relation: JOURNAL OF THE CHINESE CHEMICAL SOCIETY
    Appears in Collections:[National Central University Department of Chemical & Materials Engineering] journal & Dissertation

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