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    Please use this identifier to cite or link to this item: http://ir.lib.ncu.edu.tw/handle/987654321/26719


    Title: THE INFLUENCE OF THE CATALYST PREPARATION ON THE CATALYTIC PROPERTIES OF ZEOLITE-SUPPORTED CATALYSTS
    Authors: CHEN,YW;WANG,WJ
    Contributors: 化學工程與材料工程學系
    Keywords: CARBON-MONOXIDE HYDROGENATION;COBALT
    Date: 1993
    Issue Date: 2010-06-29 17:35:06 (UTC+8)
    Publisher: 中央大學
    Abstract: Two preparation techniques (incipient-wetness impregnation and ion exchange) have been used to prepare NaX and NaY zeolite-supported cobalt catalysts. These catalysts were characterized by X-ray diffraction, temperature-programmed reduction, and temperature-programmed desorption of hydrogen. The Fischer-Tropsch synthesis was examined at temperatures in the range of 220-300-degrees-C, a pressure of 1 atm, a CO/H-2 ratio of 1, and flow rate of GHSV=1200. The mobility of cobalt ions inside the zeolite cages in the ion-exchanged samples caused the difficulty in reduction and less active sites for the access of CO to the metals which are entraped in the sodalite cage. The ion-exchaned catalyst thus disclosed a low catalytic activity. The absence of hydroxyl group in the impregnated catalysts results in the stabilization of the metallic form of cobalt on the external surface of zeolite which cause catalytic activity in the FT reaction. The Co/X catalysts always exhibited higher activities than the Co/Y catalysts, no matter what preparation method was followed.
    Relation: STUDIES IN SURFACE SCIENCE AND CATALYSIS
    Appears in Collections:[化學工程與材料工程研究所] 期刊論文

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