HYDROGENATION ACTIVITY AND SELECTIVITY OF COBALT BORIDES

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題名:	HYDROGENATION ACTIVITY AND SELECTIVITY OF COBALT BORIDES
作者:	CHEN,YZ;WU,KJ
貢獻者:	化學工程與材料工程學系
關鍵詞:	GAS-PHASE HYDROGENATION;CATALYTIC-HYDROGENATION;NICKEL BORIDE;CARBON-MONOXIDE;SODIUM-BOROHYDRIDE;ORGANIC-SYNTHESIS;METAL-CATALYSTS;P-2 NICKEL;SILICA;METHANATION
日期:	1991
上傳時間:	2010-06-29 17:35:53 (UTC+8)
出版者:	中央大學
摘要:	Hydrogenation of monofunctional (olefinic and carbonyl) and bifunctional (alpha, beta-unsaturated aldehyde compounds have been studied over cobalt borides. The cobalt borides P-1Co and P-2WCo were prepared by reducing cobalt acetate with sodium borohydride in aqueous and 50% ethanolic media, respectively. P-1Co is more active than P-2WCo for hydrogenation of olefinic groups, whereas P-1Co is less active for carbonyl groups. Chromium and molybdenum effectively promote P-1Co and P-2WCo in carbonyl group reduction, but chromium depresses P-1Co and P-2WCo on olefinic group reduction. P-1Co and P-2WCo can selectively reduce benzene to cyclohexene and alpha,beta-unsaturated aldehyde to unsaturated alcohol, reactions that are difficult on other heterogeneous catalysts.
關聯:	APPLIED CATALYSIS
顯示於類別:	[化學工程與材料工程研究所] 期刊論文

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