We analyze the 6.4 keV line and continuum emission from the molecular cloud Sgr B2 and the source HESS J1745-303, which is supposed to be a complex of molecular gas. From the HESS results it follows that Sgr A* is a source of high energy protons, which penetrate into molecular clouds producing there a TeV gamma-ray flux. We present arguments that Sgr A* may also produce a flux of subrelativistic protons which generate the 6.4 keV line and bremsstrahlung continuum emission from the clouds.