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    Please use this identifier to cite or link to this item: http://ir.lib.ncu.edu.tw/handle/987654321/28265


    Title: Cs2K(UO)(2)Si4O12: A Mixed-Valence Uranium(IV,V) Silicate
    Authors: Lee,CS;Wang,SL;Lii,KH
    Contributors: 中央大學
    Keywords: CRYSTAL-STRUCTURE;HYDROTHERMAL SYNTHESIS;IANTHINITE;GERMANATE;OXIDATION;PHASE;FUEL;RB;CS
    Date: 2009
    Issue Date: 2010-06-29 19:45:08 (UTC+8)
    Publisher: 化學研究所
    Abstract: The first mixed-valence uranium(IV,V) silicate is synthesized under high-temperature, high-pressure hydrothermal conditions. The structure contains chains of corner-sharing (UO6)-O-IV,V octahedra which are interconnected by Si4O12 four-membered rings to form a 3-D framework. XPS and XANES spectra were measured to identify the valence state of uranium.
    Relation: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
    Appears in Collections:[化學研究所] 期刊論文

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