Near-infrared spectroscopy of CH2 by frequency modulated diode laser absorption

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题名:	Near-infrared spectroscopy of CH2 by frequency modulated diode laser absorption
作者:	Marr,AJ;Sears,TJ;Chang,BC
贡献者:	中央大學
关键词:	ORBITAL ANGULAR-MOMENTUM;TRIATOMIC-MOLECULES;INTERNAL DYNAMICS;INDUCED FLUORESCENCE;SINGLET METHYLENE;RENNER-TELLER;SPECTRUM;STATE;TRANSITION;SPIN
日期:	1998
上传时间:	2010-06-29 19:47:38 (UTC+8)
出版者:	化學研究所
摘要:	A diode laser spectrometer incorporating a multi-pass Herriott type cell and frequency modulation detection was used to record a previously unaccessed region of the near-infrared singlet<--singlet absorption spectrum of methylene between 10 000 cm(-1) and 10 600 cm(-1). With this spectrometer, signal-to-noise ratios close to the quantum noise Limit have been attained. Identification of rovibronic transitions to five previously unobserved levels, K=1 (a) over tilde(0,9,0), K=2 (b) over tilde(0,1,0), K =2 (a) over tilde(1,6,0), K=3 (b) over tilde(0,1,0) and K=3 (a) over tilde(0,10,0), was made. Despite the fact that the present spectra access levels within approximately 1300 cm(-1) of the barrier to linearity, the spectrum is dense and perturbed, characteristics in common with spectra recorded in many previous studies at shorter wavelengths. Recent spectroscopic observations of halomethylenes [J. Mel. Spectrosc. 188, 68 (1998)] had suggested that the CH2 spectrum might become simpler at longer wavelengths, but this was not evident in the observed spectra. The mixed nature of the singlet states is evidenced by the assignment of rovibronic transitions to levels containing primarily (a) over tilde (1)A(1) state character. The new measurements provide a stringent test for modern theoretical models for CH2 and will enable refinement of the electronic potential surfaces. (C) 1998 American Institute of Physics.
關聯:	JOURNAL OF CHEMICAL PHYSICS
显示于类别:	[化學研究所] 期刊論文

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