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    Please use this identifier to cite or link to this item: http://ir.lib.ncu.edu.tw/handle/987654321/28437


    Title: SOLVOLYSES OF MONOSUBSTITUTED BENZHYDRYL BROMIDES - NUCLEOPHILIC SOLVENT INTERVENTION AND DEPENDENCE OF SOLVATION ON THE EXTENT OF CHARGE DELOCALIZATION IN CATIONIC TRANSITION-STATES
    Authors: LIU,KT;CHIN,CP;LIN,YS;TSAO,ML
    Contributors: 中央大學
    Keywords: SCALE;REACTIVITIES;NITROBENZOATES;TOSYLATES
    Date: 1995
    Issue Date: 2010-06-29 19:48:52 (UTC+8)
    Publisher: 化學研究所
    Abstract: Solvolyses of monosubstituted benzhydryl bromides gave excellent linear correlations of logk with sigma + constants, and not with Y(BnBr) or Y(Br). Correlation analyses against corresponding logk of d-tert-butyl-(2-naphthyl)methyl bromide provided evidence for the importance of different extent of solvation in delocalized transition state and for nucleophilic solvent intervention in the solvolysis of benzhydryl systems.
    Relation: TETRAHEDRON LETTERS
    Appears in Collections:[化學研究所] 期刊論文

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