Silicon-induced ene-type reaction in the thermal conversion of enolates to beta-silyl enones with molecular dioxygen

Please use this identifier to cite or link to this item: http://ir.lib.ncu.edu.tw/handle/987654321/34005

Title:	Silicon-induced ene-type reaction in the thermal conversion of enolates to beta-silyl enones with molecular dioxygen
Authors:	Hwu,Jih Ru;Chen,Chien Hsien;Hsu,Chuan-I;Das,Asish R.;Li,Yen Cheng;Lin,Lung Ching
Contributors:	化學研究所
Keywords:	NORRISH TYPE-I;DIRECTED DECARBONYLATION;ORGANOSILICON COMPOUNDS;ELECTROCHEMICAL METHOD;UNSATURATED KETONES;CARBONYL-COMPOUNDS;ELECTRON-TRANSFER;ORGANIC-SYNTHESIS;SINGLET OXYGEN;OXIDATION
Date:	2008
Issue Date:	2010-07-07 11:55:31 (UTC+8)
Publisher:	中央大學
Abstract:	Reaction of alkyl, acetoxy, and silyl enol ethers of 3-(organosilyl)cyclohexanone with molecular dioxygen in toluene at 110 degrees C produced the corresponding conjugated enones in yields up to 88% yield. The reaction of the same type failed on replaceme
Relation:	ORGANIC LETTERS
Appears in Collections:	[Graduate Institute of Chemistry] journal & Dissertation

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