Ligand substitution in cubic clusters: Surprising isolation of the cocrystallization products of Cu-8(mu(8)-Se)[S2P(OEt)(2)](6) and Cu-6[S2P(OEt)(2)](6)

Please use this identifier to cite or link to this item: http://ir.lib.ncu.edu.tw/handle/987654321/34539

Title:	Ligand substitution in cubic clusters: Surprising isolation of the cocrystallization products of Cu-8(mu(8)-Se)[S2P(OEt)(2)](6) and Cu-6[S2P(OEt)(2)](6)
Authors:	Liu,CW;Hung,CM;Santra,BK;Wang,JC;Kao,HM;Lin,ZY
Contributors:	化學研究所
Keywords:	X-RAY-STRUCTURE;STRUCTURAL CHARACTERIZATION;MOLECULAR-STRUCTURES;CRYSTAL-STRUCTURES;BONDING ANALYSIS;DISELENOPHOSPHATE LIGANDS;NICKEL-CLUSTERS;METAL-CLUSTERS;RARE EXAMPLE;PR-I
Date:	2003
Issue Date:	2010-07-07 12:06:59 (UTC+8)
Publisher:	中央大學
Abstract:	The cluster {Cu-8(mu(8)-Se)[S2P(OEt)(2)](6)}(0.54){Cu-6[S2P(OEt)(2)](6)}(0.46) (2) was prepared in 78% yield from the reaction of Cu-8(Se)[Se2P(OPr)(2)](6) (1) and NH4S2P(OEt)(2) in toluene. The central selenide ion in 2 was characterized by Se-77 NMR at
Relation:	INORGANIC CHEMISTRY
Appears in Collections:	[Graduate Institute of Chemistry] journal & Dissertation

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