合成1,3-双[5-苯基-1,3,4-

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题名:	合成1,3-双[5-苯基-1,3,4-
作者:	徐啟鐘;Chi-Chung Hsu
贡献者:	化學工程與材料工程研究所
关键词:	5-硝基間苯二甲酸;間苯二甲酸;5-nitroisophthalic acid;isophthalic acid;oxadiazole
日期:	2005-07-12
上传时间:	2009-09-21 12:25:20 (UTC+8)
出版者:	國立中央大學圖書館
摘要:	本研究以間苯二甲酸及5-硝基間苯二甲酸為原料，製備双-1,3,4- This research is with isophthalic acid and 5-nitroisophthalic acid, as raw materials. Prepare bis-1,3,4-oxadiazole series chemical compounds. Can all win the purpose thing in accordance with the method step of papers. Among them every bis-1,3,4-oxadiazole series chemical compounds all shows the absorption peak of 1724 cm-1 on IR spectrum. Unknown it where characteristic of part absorb and how analyze for chemical compound. Every bis-1,3,4-oxadiazole series chemical compounds have nitro group all simple antithetical couplet when NH2NH2/Pd-C method is reduced for the amine group. This kind of amine group can also condensation reaction with the Cyanuric chloride. And become the water soluble chemical compounds. 5-nitroisophthalic acid can have azobenzene while reducing in the zinc powder-NaOH's aqueous solution, and the rate is 90%. This azobenzene has four formic acid. Can all esterify, Hydrazine hydrate and benzoyl chloride. Cyclodehydration is used in phosphorus oxychloride to be azobenzene with four pieces of 1,3,4-oxadiazole. The above-mentioned chemical compounds formate the purpose and increase its fluorescence intensity or the fluorescence of different wavelength emerges because of increase of 1,3,4-oxadiazole in the income result. Cause because of azobenzene（-N=N-） of the result. Fail to increase its fluorescence intensity and wavelength.
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