Rescaled mean spherical approximation for concentrated charge-stabilized colloids

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题名:	Rescaled mean spherical approximation for concentrated charge-stabilized colloids
作者:	Lai,SK;Wang,GF;Peng,WP;Wang,JL
贡献者:	物理研究所
关键词:	IONIC MICELLAR SOLUTIONS;LIQUID SOLUTIONS;PHASE-DIAGRAM
日期:	1999
上传时间:	2010-07-08 14:02:52 (UTC+8)
出版者:	中央大學
摘要:	The rescaled mean spherical approximation (MSA) [J.P. Hansen, J.B. Hayter, Mol. Phys. 46 (1982) 651] which was evaluated to be quite successful for studying the structures of charged colloidal dispersions at low volume fractions was revisited. Contrary to the common understanding in atomic liquids that the Ornstein-Zernike equation supplemented by the MSA closure becomes increasingly accurate at a high volume fraction (which implies the unnecessity of rescaling), it is found here that, even at high volume fractions, the calculated charged colloidal pair correlation function displays a negative value near the minimum contact distance. Both the numerical and analytical methods are applied to remedy this unphysical feature. We confirm that the analytical rescaling scheme proposed by Hansen and Hayter is equally applicable to a concentrated suspension of charge-stabilized colloids. (C) 1999 Elsevier Science B.V. All rights reserved.
關聯:	PHYSICA B-CONDENSED MATTER
显示于类别:	[物理研究所] 期刊論文

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