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    题名: ENHANCED RAMAN-SCATTERING FROM CRYSTAL VIOLET AND BENZOIC-ACID MOLECULES ADSORBED ON SILVER NANOCRYSTALS
    作者: LEI,CL;WEI,CC;CHEN,MC;OU,SY;LI,WH;LEE,KC
    贡献者: 物理研究所
    关键词: OPTICAL-PROPERTIES;SMALL PARTICLES;SURFACE;RESONANCES;LAYERS
    日期: 1995
    上传时间: 2010-07-08 14:08:59 (UTC+8)
    出版者: 中央大學
    摘要: Enhanced Raman scattering by crystal violet molecules and benzoic acid molecules adsorbed on Ag nanocrystals was measured by employing the attenuated total reflection method. The Ag nanocrystals were deposited directly on a glass substrate by the gas condensation method. Scanning electron microscopy images show that they were evenly distributed over the surface of the substrate. Films composed of Ag nanocrystals were found to be good enhancers of Raman signals. No obvious frequency shift with respect to the ''normal'' Raman lines was observed in the enhanced Raman spectra, thus indicating that the enhancement effect is mainly electromagnetic in nature. The enhancement factor depends on the laser excitation line used. Under our experimental conditions the enhancement obtained from Ag nanocrystals of mean grain size about 15 nm is an order of magnitude greater than that obtained from a flat Ag thin film of mass thickness about 56 nm. The excitation profile obtained using benzoic acid molecules shows an intensity maximum at about 500 nm, which may be linked to an effect caused by the aggregation of Ag nanocrystals.
    關聯: MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY
    显示于类别:[物理研究所] 期刊論文

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