非熱電漿結合觸媒技術為近年熱門研究議題之一,其可克服傳統非熱電漿技術能耗偏高與產物選擇性不佳之瓶頸,相關研究結果顯示觸媒型式對於效能具相當程度之影響,但目前對於如何選擇合適觸媒尚未有明確定論。本計畫配合核研所「電漿燃料轉化及污染防治技術之發展與應用」計畫之進行,藉由分析電漿觸媒轉化之化學機制與建立相關動力模式,探討電漿和觸媒各自所扮演之角色,彙整分析結果建議最適觸媒之選擇依據,提供核研所參酌。主要工作項目包括:1. 建立電漿整合觸媒進行轉化的化學機制。2. 建立電漿整合觸媒進行轉化的反應動力參數。3. 近年電漿觸媒轉化及合成之文獻回顧與評析。4. 評估適合電漿整合觸媒轉化之觸媒種類。5. 提出可行的電漿轉化或合成途徑。 Plasma catalysis technique, which can solve the major bottlenecks of conventional nonthermal plasma technologies such as the high energy consumption and the poor product’ selectivity, has become a popular research topic in recent years. Relevant studies indicate that type of catalyst might significantly affect the performance. To present time, how to select an appropriate catalyst is still unclear. The main purpose of this project is to assist the development of chemical synthesis with plasma catalysis technology undertaken by INER. The major items of this project include 1) establishment of the main reaction mechanisms, 2) building up the kinetic parameters, 3) critical literature review regarding plasma/catalysis in reforming/synthesis, 4) to evaluate the appropriate catalysts for chemical synthesis in plasma catalysis system, and 5) to propose the possible pathway and/or method for plasma reforming/synthesis. 研究期間:9601 ~ 9612