我們將研究由氧化鋁薄膜(Al2O3/NiAl(100))上的金與白金合金奈米粒子所催化之甲醇分解反應。樣品準備與合金奈米粒子的結構鑑定將在超高真空環境下使用各式表面探測儀器完成。催化反應的部分包含氣象與電化學的過程，探測此過程將使用同步輻射光發射能譜、溫度控制熱脫附以及循環電化量測(cyclic voltametry)。我們將探索反應隨著金與白的組成與結構的變化，以期找到最佳的組合及其原因。 We propose to study the catalyzed decomposition of methanol on Au-Pt nanoclusters supported on thin film Al2O3/NiAl(100). Sample preparation and structural characterization of the supported alloy clusters will be performed under ultrahigh vacuum (UHV) using a variety of surface probe techniques. The reactions, including gas-phase and electrocatalytic processes, will be probed by synchrotron radiation photoemission spectroscopy (PES), temperature-programmed desorption (TPD) and cyclic voltametry (CV). These reactions are studied as functions of Au-Pt compositions and structures with the goal of finding the optimal combination and the cause leading to such reactivity. 研究期間：9608 ~ 9707
