新孔洞化合物的誕生常會引起高度的注意，因為這些化合物可能具有許多有用的應用價值，像是催化、吸附或是離子交換反應等。為了擴展其他類型的孔洞固體，本計畫將置重點於中溫水熱/溶劑熱法合成含有機胺或有機配位基的金屬鍺酸鹽化合物，特別是具有嶄新結構和大孔洞的化合物。除了合成與結構鑑定外，也研究化合物的磁性、吸附、催化、離子交換及發光性質。 The synthesis of new microporous compounds has been a subject of intense research because of their potential applications in catalysis, absorption, and ion exchange. We propose to synthesize metal germanates containing organic amine linkers in their frameworks by hydro(solvo)thermal methods. Besides synthesis and crystal structure determination, we also study their magnetic, absorption, ion exchange, catalysis, and photoluminescence properties. 研究期間：9908 ~ 10007
