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    Please use this identifier to cite or link to this item: http://ir.lib.ncu.edu.tw/handle/987654321/6035


    Title: 雙(三唑)鄰苯二口井衍生物配位基之合成、鑑定及性質探討;Phthalazine derivatives synthesize
    Authors: 張文福;Wen-Fu Chang
    Contributors: 化學研究所
    Keywords: 雙(三唑)鄰苯二口井;phthalazine
    Date: 2004-06-25
    Issue Date: 2009-09-22 10:12:13 (UTC+8)
    Publisher: 國立中央大學圖書館
    Abstract: (聯胺)鄰苯二口井(1,4-dihydrazinophthalazine, 1)在藥物化學研究方面是很有貢獻的主架構,我們投入化合物1相關的衍生物研究時,發現在配位化學研究上,1也是很有趣的主架構。 ??化合物1與酮類14、15及16反應得到雙吡唑和吡唑加單三唑兩種不同的產物,其中以合成化合物12與13的反應尤其特別,我們僅僅在改變溫度及的酸鹼度的情況下,產物的選擇性會有極端的改變。 化合物1與醛類的反應,經過縮合及氧化合環的步驟,可得到雙三唑的化合物22、28與一個新的配位基配位基29,我們得到了29單晶構造解析的結果。這配位基可以與化合物31反應合成出含釕金屬化合物32。 我們也發現到,化合物32被UV光(325nm)照射,在很短的時間內,顏色就會由黃色改變為紅色,改放置在暗處顏色會變為黃色。 The heterocycles involving 1,4-dihydazinophthalazine (DHPH) as a building block have been paid considerable attention due to the significant biological applications. 1,4-dihydrazinophthalazine 1 reacted with 14、15 and 16. The ratio between 12 and 13, is dependent upon the pH of medium and temperature.1,4-dihydrazinophthalazine 1 reacted with aldehyde, followed by an oxidative cyclization to gave 22、28 and 29. When compound 29 was treated with 31 in ethanol under reflux for 12 h, it was also complex 32 .Upon irradiation with UV light, complex 32 changed color from yellow to red. The chemistry is yet to pursuit.
    Appears in Collections:[化學研究所] 博碩士論文

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