過渡金屬催化之碳氫鍵活化/芳香?化反應之研究與其應用在功能性有機光電材料之分子設計與合成;Investigation of Transition-Metal-Catalyzed Direct C-H Bond Activations/Arylations and Their Applications in the Molecular Design and Synthesis of Functional Organic Materials

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題名:	過渡金屬催化之碳氫鍵活化/芳香?化反應之研究與其應用在功能性有機光電材料之分子設計與合成;Investigation of Transition-Metal-Catalyzed Direct C-H Bond Activations/Arylations and Their Applications in the Molecular Design and Synthesis of Functional Organic Materials
作者:	劉青原
貢獻者:	國立中央大學化學工程與材料工程學系
關鍵詞:	化學;材料科技;光電工程
日期:	2013-12-01
上傳時間:	2014-03-17 11:31:28 (UTC+8)
出版者:	行政院國家科學委員會
摘要:	研究期間：10208~10307;Although plenty of -conjugated compounds (oligomers or polymers) have been widely applied in the field of organic optoelectronics, their synthetic strategies are generally based on traditional cross-coupling reactions. It is very common that the synthetic pathways are neither atom-economical nor efficient. On the other hand, there are lots of new synthetic procedures being developed every day but they never targeted on functional -conjugated materials. Hence, our research philosophy is to bridge the research area of fundamental organic synthetic methodologies with applied science of organic materials, in other word, we will proceed toward the research goal of target-oriented and atom-economical organic synthetic methodologies. Firstly, we will endeavor to investigate the transition-metal catalyzed direct C-H bond arylations using readily prepared orgaozincs, organozincates, organocuprates, organoaluminum, or organoindium species as new arylating reagents. In addition, less toxic and inexpensive transition-metal catalysts such as copper or iron complexes will be also examined in the direct C-H coupling reactions. As mid- and long-term objectives, we will apply the well-optimized synthetic methodology of C-H bond arylations in the efficient preparation of functional -conjugated molecules including: (1) donor-acceptor type organic dyes, and (2) polymers. Furthermore, device fabrication and efficiency measurement of organic solar cells will be achieved through on-campus collaborations.
關聯:	財團法人國家實驗研究院科技政策研究與資訊中心
顯示於類別:	[化學工程與材料工程學系 ] 研究計畫

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