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    Please use this identifier to cite or link to this item: http://ir.lib.ncu.edu.tw/handle/987654321/6413


    Title: 環烯烴聚醚醚酮與聚醚醚酮酮質子傳導膜之開發;Crosslinkable sulfonated poly(ether ketone)s containing norbornene groups as proton exchange membrane
    Authors: 許閣倫;Ke-Lun Hsu
    Contributors: 化學研究所
    Keywords: 質子傳導膜;質子導電度;吸水膨潤度;尺寸穩定性;環烯烴;聚醚醚酮;聚醚醚酮酮;Norbornene;Proton conductivity;Water uptake;SPEEKK;Swelling ratio;SPEEK;Proton exchange membrane
    Date: 2008-07-08
    Issue Date: 2009-09-22 10:19:07 (UTC+8)
    Publisher: 國立中央大學圖書館
    Abstract: 本篇研究重心在於利用有機反應將環烯烴分子導入Sulfonated poly(ether ketone)s主鏈上,合成出一系列帶有環烯烴分子之NB-Ph SPEEK、NB-p-Ph SPEEK與NB-Np SPEEKK,之後再利用環烯烴分子內的雙鍵進行自由基聚合反應來達成交聯之目的,希望藉由這樣的調控能於質子導電度與膜膨潤情形之間取得平衡,得到適合應用於燃料電池之質子交換膜。此系列帶有環烯烴分子之聚合物同時擁有優異的熱穩定性與氧化穩定性,且於80oC 之熱水裡表現出很好的尺寸穩定性,其中NB-Np SPEEKK 於室溫下導電度更高達 7.52 x 10-2 S/cm,統整以上之結果可看出此類帶有環烯烴分子之膜材確實有潛力成為低成本質子交換膜的選擇之一。 A series of crosslinkable sulfonated poly(ether ketone)s containing norbornene groups were synthesized by aromatic nucleophilic substitution reaction . To decrease the swelling of fuel cell membranes , crosslinking of theses polymers by radical polymerization were be tested. These polymers had good thermal and oxidative stability , and good dimensional stability in hot water . The proton conductivity of NB-Np SPEEKK at room temperature is 7.52 x 10-2 S/cm. The results showed these materials containing norbornene groups are possible inexpensive candidate materials for proton exchange membranes in fuel cell applications.
    Appears in Collections:[Graduate Institute of Chemistry] Electronic Thesis & Dissertation

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