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    Please use this identifier to cite or link to this item: http://ir.lib.ncu.edu.tw/handle/987654321/69877

    Title: 結合步驟經濟效益與低成本低毒性交叉耦合反應的新合成策略:功能性共軛分子環保合成法之研究;Combining Step-Economical Synthetic Strategy with Low-Cost and Low-Toxicity Green Cross-Couplings Leading to the Ecological Synthesis of Pi-Functional Molecules
    Authors: 劉青原
    Contributors: 化學工程與材料工程學系
    Keywords: 步驟經濟效益之合成策略;綠色環保交叉耦I合反應;功能性共輛分子;Step-Economical Synthetic Strategy / Green Cross-Couplings / 兀-Functional Molecules;化學工程
    Date: 2016-03-29
    Issue Date: 2016-03-29 18:32:57 (UTC+8)
    Publisher: 科技部
    Abstract: 過渡金屬催化的交叉耦合反應是目前被公認為在碳碳鍵生成反應中的絕佳合成工具之一。其中鈀催化 之碳氫鍵活化/官能基化反應更是在此相關領域中正快速崛起的明日之星,因為此類方法學可以避免 製備空氣敏感的Grignard試劑或是具高毒性的有機錫試劑,同時減少了副產物的產生。直接的碳氫鍵 官能基化反應更是一個省步驟、相對環保的重要合成策略,相信將會逐漸取代傳統耦合反應,因此, 目前不只有機化學家,高分子與材料化學家也相繼投入此領域的相關研究。 目前本實驗團隊已經成功發展出一套通用的鈀催化碳氫鍵直接芳香環化之合成方法學;Transition-metal-catalyzed cross-coupling reactions have been recognized as the most powerful synthetic tool for carbon-carbon bond formations. In particular, the palladium-catalyzed direct C-H functionalization has recently become the rising star in this;研究期間:10408~10507
    Relation: 財團法人國家實驗研究院科技政策研究與資訊中心
    Appears in Collections:[化學工程與材料工程學系 ] 研究計畫

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