本篇論文討論 Sn@Ni 核殼結構奈米顆粒的磁性、超導研究與磁性 鬆弛行為，使用熱蒸鍍冷凝法的雙鍍源方式製作本樣品，經由 X 光繞 射譜圖、EDXS與 TEM判定 Sn核直徑為2.4 nm，Ni殼的厚度為 1.9 nm。 Sn@Ni 在外加磁場 Ha = 200 Oe 的阻擋溫度 TB = 43 K， ；Ha = 1 kOe ，TB = 6 K；Ha = 5 kOe，TB = 2.4 K。對其做磁化率隨著溫度變化的實 驗，可發現 Sn@Ni 具有弱自旋玻璃行為與超導臨界磁場 Hc0 = 2.9 kOe。 Sn@Ni 奈米顆粒磁性鬆弛研究具有磁化強度翻轉的行為，此行為 可得知與本樣品為核殼結構有關。磁化強度隨時間鬆弛的曲線，應有 兩個分量的貢獻，分別是殘留的磁化強度 Mr 曲線和感應的磁化強度 Mi曲線。弛豫現象與溫度、外加磁場、降場速率有關。 最後將 Sn@Ni 與本實驗室的 Au@Ni 做個比較，可得知 Sn@Ni 感 應的磁化強度百分比 Pi0比 Au@Ni 的來的強。;We report on the magnetic properties, superconductivity and magnetic relaxation behaviors in the nano-sized Sn@Ni core@shell particles. The Sn@Ni NPs were fabricated employing the gas-condensation method, using a chamber equipped with two decoupled evaporation sources for separate evaporation of Sn or Ni. We use X-ray diffraction pattern, energy-dispersive X-ray spectroscopy and transmission electron microscopy, resulting in a mean particle core diameter of 2.4 nm and shell thickness of 1.9 nm. In applied magnetic field Ha = 200 Oe, the blocking temperature TB of Sn@Ni is 43 K; Ha = 1 kOe, TB = 6 K; Ha = 5 kOe, TB = 2.4 K. Doing χ(T) experiment, Sn@Ni has weak spin glass behavior and the critical magnetic field Hc0 = 2.9 kOe. The study of magnetic relaxation behaviors of Sn@Ni NPs had inverse magnetization behavior. It related to core@shell structure and it depended on temperature, applied magnetic field, and turning the Ha off. M(t) should have two components: remanent magnetization Mr and Faraday inductive magnetization Mi. At last, we made a comparison between Sn@Ni and Au@Ni. The ratio of Faraday inductive magnetization Pi0 of Sn@Ni had much stronger than Au@Ni.
