合成含有苯并咪唑之金屬錯合物並應用於染敏太陽能電池

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题名:	合成含有苯并咪唑之金屬錯合物並應用於染敏太陽能電池
作者:	孫雅君;Sun, Ya-Chun
贡献者:	化學學系
关键词:	染敏太陽能電池;苯并咪唑;DSSCs
日期:	2016-12-26
上传时间:	2017-01-23 16:06:27 (UTC+8)
出版者:	國立中央大學
摘要:	染敏太陽能電池為目前極具發展潛力之新型太陽能電池，其擁有、質輕、製造成本低、具有豐富色彩、可撓曲等優點，是現今熱門研究項目。而舊有研究中染料多為無機錯合物或純有機化合物，未有將兩者做結合之文獻。本論文參考先前實驗室所合成的含有有機無機混合之HSM系列染料，將其結構簡化設計出JDL系列。其結構簡易，在光物理性質及電化學性質皆有符合預期之表現，期望未來能作為良好之光敏劑。此外也希望其可順利接上金屬並鑑定其結構，用以比較染料在接上金屬前後的光電性質是否有改善，並期望可以為染敏太陽能電池研究領域提供一個新的方向。 ;Dye-sensitized solar cells (DSSCs), one of the potential type solar cells, has been more popular nowadays. It has advantages like low-cost, simple process, light-weight, flexibility and multi-color. In the previous studies, most of these dyes were inorganic complexes and pure organic compounds, but there was no literature combining them. In this paper, based on previous reports of organic-inorganic hybrid HSM series, we simplify the design of its structure JDL series. It has simple structure, and photophysical properties, electrochemical properties are with expectations of great performances. It can be expected to a good sensitizer in the future. In addition, we expected it can be successfully coordinated to the metal and identified its structure, compared to its photoelectric properties of the dye, before and after the metal coordinated. It is expected to provide a new direction for dye-sensitive solar cell studies.
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