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    Please use this identifier to cite or link to this item: http://ir.lib.ncu.edu.tw/handle/987654321/83289


    Title: 有機催化4-嘧啶酮進行Aza-Michael加成反應
    Authors: 陳詠心;Chen, Yong-Sin
    Contributors: 化學學系
    Keywords: 4-嘧啶酮;Aza-Michael 加成反應
    Date: 2020-08-20
    Issue Date: 2020-09-02 15:19:13 (UTC+8)
    Publisher: 國立中央大學
    Abstract: 本篇以有機掌性催化劑來進行Michael addition 反應,以促進4-嘧啶酮與 α,β 不飽和的Michael acceptor 來進行不對稱1,4 加成反應,期望得到高產率與高選擇性之產物,其中又以辛可寧的方胺衍生物可得到最好的反應性,產率可達99 %,鏡像選擇性可達90 %。;an enantioselective organocatalytic aza-Michael addition reaction of heterocyclic compounds including 4 -hydroxypyrimidinone to α,β-unsaturated Michael acceptor.This is developed with the help of a bifunctional squaramide catalyst to give the corresponding adducts formed in good to excellent enantioselectivity(up to 90 % ee)
    Appears in Collections:[化學研究所] 博碩士論文

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