The Effect of Pd and Cu Co-catalysts on the Activity of TiO2 Photocatalyst

NCU Institutional Repository > 工學院 > 化學工程與材料工程研究所 > 博碩士論文 > Item 987654321/85664

請使用永久網址來引用或連結此文件: http://ir.lib.ncu.edu.tw/handle/987654321/85664

題名:	The Effect of Pd and Cu Co-catalysts on the Activity of TiO2 Photocatalyst
作者:	許育瑄;Hsu, Yu-Hsuan
貢獻者:	化學工程與材料工程學系
關鍵詞:	光觸媒;二氧化鈦;鈀;銅;含浸法;光催化降解;Photocatalyst;Titanium dioxide;Pd-doping;Cu-doping;Impregnation method;Photocatalytic degradation
日期:	2021-07-02
上傳時間:	2021-12-07 11:12:49 (UTC+8)
出版者:	國立中央大學
摘要:	這項研究的目的是研究鈀和銅助催化劑對二氧化鈦光催化活性的影響。通過初濕含浸法製備了摻雜金屬的二氧化鈦。據推測，添加金屬可以減少電子-空穴複合的可能性並提高活性。 X射線衍射、比表面積和孔隙率分析儀、透射電子顯微鏡和高分辨率透射電子顯微鏡用於表徵催化劑的粒徑、比表面積、孔體積、孔徑大小、形態和金屬分佈。結果表明，二氧化鈦的粒徑和形態沒有發生顯著變化且金屬均勻分散在二氧化鈦的表面上。亞甲基藍可以用於測試在紫外線照射下的光降解活性。通過UV /可見光/ NIR分光光度計測定水中亞甲基藍的濃度。結果表明，合適的金屬含量和鍛燒溫度可以有效地提高二氧化鈦的光降解效率。鈀和銅均在?燒溫度為300℃及金屬含量為0.5 wt.％具有最高的光分解活性。TiO2的活性隨反應溫度的升高而增加。在0-50°C下，Pd /TiO2表現出相同的趨勢。但是當溫度高達70°C時，TiO2?的反應速率略為下降，而Pd/TiO2變得最差。與其他溫度相比，Cu/TiO2則在室溫下的活性更高。;The aim of this study was to investigate the effects of Pd and Cu co-catalyst on the photocatalytic activity of TiO2. The doped metal on the TiO2 was prepared by incipient-wetness impregnation method. It was hypothesized that adding metal can reduce the possibility of electron-hole recombination and improve activity. X-ray diffraction, specific surface and porosimetry analyzer, transmission electron microscopy, and high-resolution transmission electron microscopy were used to characterize the particle size, specific surface area, pore volume, pore size, morphology, and metal distribution of the catalysts. The results show that the particle size and morphology of TiO2 did not change significantly, as expected. The metal was uniformly dispersed on the surface of TiO2. Methylene blue was used to test the photodegradation activity under UV light irradiation. The concentration of methylene blue in water was determined by UV/Visible/NIR spectrophotometer. The results show that the suitable metal content and calcination temperature could effectively increase the photodegradation efficiency of TiO2. The calcining temperature of 300 ℃ and the palladium and copper metal content of 0.5 wt.% had the highest photodecomposition activity among all samples. At 0-50°C, the activity of TiO2 and Pd /TiO2 increases with the increase of reaction temperature. But when the temperature is as high as 70°C, the reaction rate of TiO2 drops slightly, and Pd/TiO2 becomes the worst. Cu/TiO2 is more active at room temperature than other temperatures.
顯示於類別:	[化學工程與材料工程研究所] 博碩士論文

文件中的檔案:

檔案	描述	大小	格式	瀏覽次數
index.html		0Kb	HTML	69	檢視/開啟

在NCUIR中所有的資料項目都受到原著作權保護.

社群 sharing

資料載入中.....