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姓名 盧興波(Shing-Bo Lu) 查詢紙本館藏 畢業系所 化學學系 論文名稱 設計與合成銥金屬錯合物藍光材料
(Design and Synthesis of Blue-Emitting Cyclometalated Iridium Complexes)相關論文 檔案 [Endnote RIS 格式] [Bibtex 格式] [相關文章] [文章引用] [完整記錄] [館藏目錄] 至系統瀏覽論文 ( 永不開放) 摘要(中) 摘要
環型的銥金屬錯合物是近年來具有突破性的磷光發光材料。它的元件性能是純有機分子所構成的螢光發光體所無法相比的。紅光及綠光的材料已經有令人滿意的發展,但藍光的進展卻困難重重。
本文主要在探討如何達成純藍光的銥金屬錯合物。我們有系統地設計雙芳香環的配位基,並利用鈀催化的偶合反應將它們合成出來。經由錯合物的結構分析及發光長的比較,我們成功的確定出達成銥金屬藍光錯合物的方向。摘要(英) Abstract
Phosphorescent cyclometalated iridium complexes has revolutionized the world of OLED (organic light-emitting diodes) materials. The much higher quantum efficiency of devices fabricated with this kind of materials was never achieved by simple organic emitters. Red light and also green light-emitting iridium complexes have made themselves candidates for real-world use, while blue light-emitter is still way behind mature.
The main goal of this thesis is to investigate how to achieve the pure blue light-emitting iridium complexes. Ligands were systematically designed and synthesized with the aid of palladium catalyzed cross-coupling reactions. Analysis of structures and emission spectra of the resulting complex makes it possible for us to design and to achieve the pure blue light-emitting iridium complexes in the days to come.關鍵字(中) ★ 銥金屬
★ 藍光
★ 有機發光二極體關鍵字(英) ★ blue-emitting
★ iridium complex
★ OLED論文目次 目 錄
壹‧序論
1.1 簡介…………………………………………………………………1
1.2 螢光與磷光…………………………………………………………3
1.3 有機發光二極體的基本構造………………………………………5
1.4 有機發光二極體材料………………………………………………7
1.5 銥金屬錯合物材料………………………………………………...12
1.6 銥金屬錯合物藍光材料的設計…………………………………...17
貳‧結果與討論
2.1 配位基的合成探討………………………………………………...23
2.2 錯何物的合成探討………………………………………………...31
2.3 錯合物的發光性質探討…………………………………………...33
叁‧實驗部分
3.1 化合物的合成流程…………………………………………………35
3.2 化合物的合成步驟…………………………………………………39
肆‧參考文獻………………………………………………………………..42參考文獻 參考文獻
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15. Simon P. H. Mee, Victor, Victor Lee, Jack E. Baldwin, Angew. Chem. Int.Ed, 2004, 43, 1132.指導教授 李文仁(Wen-Ren Li) 審核日期 2006-1-18 推文 facebook plurk twitter funp google live udn HD myshare reddit netvibes friend youpush delicious baidu 網路書籤 Google bookmarks del.icio.us hemidemi myshare