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以作者查詢圖書館館藏 、以作者查詢臺灣博碩士 、以作者查詢全國書目 、勘誤回報 、線上人數：99 、訪客IP：18.119.103.132
姓名 王聖文(Sheng-Wen Wang) 查詢紙本館藏 畢業系所 光電科學與工程學系 論文名稱 非對稱散射式液晶波導元件及其應用
(Waveguide liquid crystal devices with asymmetrical light scattering property and their applications)相關論文 檔案 [Endnote RIS 格式]
[相關文章]
[文章引用]
[完整記錄]
[館藏目錄]
至系統瀏覽論文 (2026-7-1以後開放)
摘要(中) 本論文的研究主題為非對稱散射式液晶波導元件及其應用，主要探討側向光源入射以下三種元件後的非對稱散射光學特性，元件架構分別為(i)聚合物網絡液晶搭配低折射率氟化鎂(MgF2)薄膜、(ii)聚合物網絡液晶搭配膽固醇液晶聚合物以及(iii)混成扭轉型聚合物網絡液晶搭配線偏振片。
論文中將說明各項元件架構的原理及性能特性，以下分別簡述之。第一部分探討側向光源入射鍍有低折射率氟化鎂(MgF2)薄膜的聚合物網絡液晶盒，利用水平配向聚合物網絡型液晶盒，並在液晶盒其中一基板蒸鍍低折射率氟化鎂(MgF2)薄膜，其中主要透過液晶波導特性以及全反射的理論，當中利用側向入射光束於上(下)基板可達成的全反射條件次數不同，以完成在散射態保有
非對稱散射光學之特性。第二部分的研究是探討側向光源入射聚合物網絡
液晶搭配膽固醇液晶聚合物，利用水平配向聚合物網絡型液晶盒，並在液晶
盒一側架設膽固醇液晶聚合物用，藉由膽固醇液晶聚合物可反射特定波長
與特定旋性之入射光特性達成於特定波段內之側向入射光有顯著的非對稱
散射光學之特性，故此部分針對單一波長之入射光有較高的非對稱散射光
學之特性。第三部分則探討混成扭轉型聚合物網絡液晶對不同偏振態的散
射特性，由於該混成扭轉型聚合物網絡液晶上下基板的配向處理不同，兩側
基板的出射光偏振程度具有相當程度上的差異，故可利用於觀測側設置一
線偏振片用以提高自該液晶元件兩側觀測時的對比度差異，並實現非對稱
散射光學之特性。以上三種元件架構之配置皆可達成非對稱散射式液晶波
導元件，論文中亦提出於透明單向光源、具備隱私保護之液晶智慧玻璃、液
晶顯示元件之液晶波導的應用，目前仍有許多性能上的挑戰需進行最佳化。摘要(英) The main topic reported in this study is waveguide liquid crystal (LC)
devices with asymmetrical light scattering property and their applications. The
key points we discuss herein include the asymmetrical light scattering optical
characteristics when an edge light source is coupled into the proposed three
different LC devices applied with suitable electric fields, and then scattered out of
the LC devices. They are (i) polymer network LC (PNLC) cell coated with a low
refractive index thin film (MgF2), (ii) PNLC cell with cholesteric LC polymer
(CLCP) layers, and (iii) twisted hybrid aligned PNLC (TH-PNLC) cell with a
linear polarizer. We are going to explain the principle and the functional
characteristics of the structures of each LC device.
First of all, we discuss the properties of a homogeneous aligned PNLC (HAPNLC) cell whose one substrate is coated with a thin film having low refractive
index. Such a low refractive index magnesium fluoride (MgF2) film is deposited
on the top of the indium-tin-oxide film of one of the substrates of the LC cell by
evaporation method. The main mechanisms adopted here are the properties of LC
waveguide and total internal reflection (TIR). Based on the different times of TIR
of the incident light source, occurred on the boundaries of different films, the
asymmetrical output light in its scattering state can be obtained. The second part
is the asymmetrical light scattering properties demonstrated by the proposed HAPNLC cell with a CLCP layer. Due to the limitation of the CLCP layer, the edge
light source selected herein is a He-Ne laser with its wavelength of 632.8 nm,
which is within the reflection band of the used CLCP layer. Briefly, the powers of
light scattered out of the LC device from the sides with and without the CLCP
layer are different, indicating that the asymmetrical light scattering property can
also be realized. The last part of the research about asymmetrical light scattering
property is based on the proposed TH-PNLC cell with a linear polarizer. The
surface treatments of the two substrates of the TH-PNLC cell are different, one is
iv
homogeneous alignment, and the other one is homeotropic alignment. Moreover,
the twisted and hybrid aligned PNLC structures provide light scattering with
different degrees of polarization from two sides of TH-PNLC cell applied with
suitable electric fields. Therefore, we can realize asymmetrical light scattering
property with one polarizer stuck on the side of the TH-PNLC cell treated with a
homeotropic alignment layer.
Finally, the three LC devices mentioned above can be applied to various
practical applications in daily life. In this thesis, the applications of the proposed
waveguide LC devices, including electrically switchable one-way transparent
light sources, switchable LC privacy smart windows, and LCDs with privacy
protection, have also been demonstrated. However, lots of challenges, such as
contrast, operation voltage, uniformity, etc., still need to be overcome關鍵字(中) ★ 液晶光電
★ 非對稱
★ 散射式
★ 智慧窗戶
★ 液晶波導
★ 隱私保護裝置關鍵字(英) ★ Waveguide
★ liquid crystal
★ asymmetrical light scattering
★ one-way shield論文目次 目錄
摘要........................................................................................................................................... ii
Abstract ....................................................................................................................................iii
誌謝.......................................................................................................................................... iv
目錄.......................................................................................................................................... vi
表目錄.................................................................................................................................... viii
圖目錄....................................................................................................................................... x
符號說明................................................................................................................................ xix
第一章 緒論............................................................................................................................. 1
§1-1 前言.............................................................................................................................. 1
§1-2 研究動機...................................................................................................................... 1
§1-3 文獻回顧...................................................................................................................... 2
§1-3-1 液晶波導顯示器[1]
................................................................................................ 2
§1-3-2 非對稱光學特性[2][3]
............................................................................................. 4
§1-4 論文架構...................................................................................................................... 7
第二章 液晶簡介..................................................................................................................... 9
§2-1 液晶定義[4]
................................................................................................................... 9
§2-2 液晶簡介[5]
................................................................................................................... 9
§2-3 液晶分類[6][8][11][12][13][15]
............................................................................................. 10
§2-3-1 向列型液晶(Nematics)[7][10][13]
........................................................................... 11
§2-3-2 層列型液晶(Smectics) ....................................................................................... 13
§2-3-3 膽固醇型液晶(Cholesterics，簡寫 N*)[7][8][9]
.................................................... 15
§2-4 液晶物理[8][12][15]
........................................................................................................ 21
§2-4-1 光學異向性(optical anisotropy)......................................................................... 21
§2-4-2 介電異向性(dielectric anisotropy)...................................................................... 26
§2-4-3 連續彈性體理論(Elastic Continuum Theory)..................................................... 28
第三章 實驗相關理論........................................................................................................... 30
§3-1 聚合物網絡型液晶.................................................................................................... 30
§3-1-1 水平配向聚合物網絡型液晶[22]
.........................................................................30
§3-1-2 90°扭轉向列型聚合物網絡液晶[16]
....................................................................36
§3-1-3 混成扭轉型聚合物網絡液晶[25]
.........................................................................40
§3-2 膽固醇液晶聚合物[26][27]
............................................................................................45
第四章 實驗方法與製程........................................................................................................49
§4-1 材料介紹 ....................................................................................................................49
§4-1-1 向列型液晶 E7[17]
................................................................................................49
§4-1-2 液晶聚合物 RM257[18]
........................................................................................50
§4-1-3 手性分子 CB15[20]
...............................................................................................51
§4-1-4 手性分子 S811[20]
................................................................................................51
§4-1-5 手性分子 S5011[23]
...............................................................................................52
§4-1-6 低折射率薄膜氟化鎂(MgF2)
[19]
..........................................................................52
§4-1-7 水平配向膜 PVA[24]
..............................................................................................53
§4-1-9 垂直配向膜 DMOAP[21]
.......................................................................................53
§4-2 實驗樣品製作 .............................................................................................................54
§4-2-1 材料配置..............................................................................................................54
§4-2-2 ITO 玻璃基板處理...............................................................................................54
§4-2-3 ITO 基板表面配向處理.......................................................................................55
§4-2-4 液晶空盒製作.....................................................................................................56
§4-2-5 液晶空盒厚度量測..............................................................................................57
§4-3 樣品觀測與實驗架設.................................................................................................59
§4-3-1 樣品觀測..............................................................................................................59
§4-3-2 側向光源及液晶盒夾具 .....................................................................................59
§4-3-3 聚合物網絡型液晶盒正向入射非偏振雷射光之光電特性量測......................60
§4-3-4 聚合物網絡型液晶盒側向入射非偏振雷射光之光電特性量測......................61
§4-3-5 聚合物網絡液晶盒側向入射白光 LED 之光電特性量測................................62
第五章 實驗結果與討論........................................................................................................64
§5-1 側向光源之水平配向聚合物網絡型液晶研究..........................................................64
§5-1-1 側向光源入射 HA-PNLCs 之穿透態與散射態................................................ 64
§5-1-2 低折射率氟化鎂(MgF2)薄膜對於側向光源的聚合物網絡液晶研究............. 66
§5-2 膽固醇液晶聚合物對於側向光源入射聚合物網絡液晶之影響............................ 70
§5-2-1 膽固醇液晶聚合物之光學特性討論................................................................. 71
§5-2-2 HA-PNLC 液晶盒搭配膽固醇液晶聚合物液晶盒的非對稱光散射現象討論 80
§5-3 90°扭轉向列型聚合物網絡液晶[2][3]
......................................................................... 87
§5-3-1 正向光源入射 90° TN-PNLC 散射態出射光與偏振相依性之討論 ............... 87
§5-3-2 光起始劑(DMPAP)濃度對 90° TN-PNLC 液晶盒之影響 ................................ 94
§5-3-3 配向液濃度對 90° TN-PNLC 液晶盒之影響 ................................................. 100
§5-3-4 透過 1D-DIMOS 模擬探討不同基板配向力對 90° TN-PNLC 液晶盒的影響110
§5-4 TH-PNLCs 液晶盒對於側向入射光源的穿透態與散射態.................................... 116
§5-4-1 側向入射 TH-PNLCs 液晶盒的穿透態與散射態 .......................................... 117
§5-4-2 TH-PNLCs 液晶盒之應用構想與設計 ............................................................ 123
§5-4-3 TH-PNLCs 液晶盒應用於透明光源之性能展示 ............................................ 126
§5-4-4 利用 TH-PNLCs 液晶結構顯示具備隱私保護圖案之構想與設計............... 130
§5-4-5 TH-PNLCs 液晶結構顯示具備隱私保護圖案之性能 展示 .......................... 132
第六章 結論與未來展望..................................................................................................... 139
§6-1 結論.......................................................................................................................... 139
§6-1-1 側向光源入射聚合物網絡液晶研究搭配低折射率氟化鎂(MgF2)薄膜 ...... 140
§6-1-2 側向光源入射聚合物網絡液晶研究搭配膽固醇液晶聚合物....................... 140
§6-1-3 不同配向之聚合物網絡型液晶盒之散射光與偏振態 研究......................... 141
§6-2 未來展望.................................................................................................................. 141
參考文獻............................................................................................................................... 144參考文獻 參考文獻
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