博碩士論文 107326026 詳細資訊




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姓名 白芸綺(Yun-Chi Pai)  查詢紙本館藏   畢業系所 環境工程研究所
論文名稱 靜電紡絲製備碳纖維電極應用於電容去離子系統
(Preparation of carbonaceous fiber for capacitive deionization by electrospinning)
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摘要(中) 電容去離子(CDI)是能處理不同鹽含量的微鹽水的先進水處理的技術。它有很多優點,在施加低電壓形成電極表面電雙層,離子進行電吸附,去除電壓後進行脫附,本研究利用靜電紡絲製備碳纖維(carbon fiber, CF)探討碳纖維電極的性能。靜電紡絲是一種用於生產微米直徑聚合物纖維的技術。當在進行後續用途時,電紡纖維的特性就很重要,而電紡的操作參數對纖維本身的性能影響很大,例如電紡施加電壓、前驅液濃度和進料速度等。聚丙烯腈(PAN)是眾所周知的聚合物,具有良好的穩定性和機械性能,已廣泛用於生產碳纖維。故本研究以PAN作為前驅物分別施加不同電紡電壓15、17和22 kV生產碳纖維,其為施加22kV時,碳纖維電極的電化學性能最佳,此外再以CF-22-1進行後續的改質。分別以氫氧化鉀作為活化藥劑以及在碳纖維上複合二氧化鈦,接著對NaCl水樣進行去離子實驗,結果表明,經過氫氧化鉀修飾後的電極(K-CF-22),具有最佳的吸附量。經SEM測定,電極表面的型態顯示,K-CF-22明顯增加表面的粗糙度,與BET結果一致,比表面積為643.01 m2/g增加至原來的2.5倍且總孔體積為0.061 cm3/g是全數樣品裡最高的。
摘要(英) Capacitive deionization (CDI) is an advanced water treatment technology that can process micro-saline water. The electrical double layer (EDL) is formed by applying low voltage. When the voltage is removed, the ions on the electrode are desorbed. In this study was used electrospinning to prepare carbon fiber (CF) to explore the performance of CF electrodes. Electrospinning can produce micron diameter polymer fibers. The operating parameters of electrospinning have a great influence on the performance of CF. In this study, PAN was used as the precursor to produce CFs with different electrospinning voltages of 15, 17 and 22 kV. When the electrospinning voltage was 22 kV (CF-22-1), the electrochemical performance of the CF electrode is the best. In addition, CF-22-1 is used for subsequent modification. KOH was used as the activating agent and TiO2 was deposited on CFs. The deionization efficiency showed that CF modified by KOH (K-CF-22) had the best adsorption capacity. The surface morphology of the K-CF-22 significantly increased the surface roughness. The specific surface area was 643.01 m2/g and the total pore volume was 0.061 cm3/g.
關鍵字(中) ★ 電容去離子
★ 靜電紡絲
★ 碳纖維改質
★ 氫氧化鉀
★ 二氧化鈦
關鍵字(英) ★ capacitive deionization
★ electrospinning
★ carbon fiber modification
★ KOH
★ TiO2
論文目次 摘要 II
ABSTRAC III
誌謝 IV
Content VI
List of Figures VIII
List of Tables X
CHAPTER Ⅰ. INTRODUCTION 1
1.1 Background 1
1.2 Objectives 4
CHAPTER Ⅱ. LITERATURE REVIEW 6
2.1 Capacitive deionization 6
2.1.1 Theory of capacitive deionization 7
2.1.2 Theory of electrical double layer 9
2.1.3 Semi-batch system 11
2.2 Electrospinning 14
2.2.1 Theory of electrospinning 14
2.2.2 Precursors for electrospinning 15
2.2.3 Processing parameters 15
2.3 Electrospun carbon fiber 19
2.3.1 Carbon fiber (CF) 19
2.3.2 Calcination of carbon fiber 21
2.3.2 Importance of temperature rising rate 24
2.5 Modification of carbon fiber 25
2.5.1 Preparation of activated carbon fiber with KOH 25
2.5.2 Fabrication of TiO2 carbon fiber 26
CHAPTER Ш. MATERIALS AND MTHODS 27
3.1 Preparation of Electrospun Fiber 27
3.1.1 Preparation of the precursor 27
3.1.2 Operating parameters of electrospinning 27
3.1.3 Stabilized-activated fiber 28
3.1.4 Preparation of activated fiber with KOH and composited fiber with TiO2 29
3.2 Characterization of carbon fiber 31
3.4 Analysis of NaCl 36
3.5 Data analysis 38
3.5.1 Diameter of CF 38
3.5.2 Adsorption amount 38
CHAPTER IV. RESULTS AND DISCUSSION 39
4.1 Physical characteristics 39
4.1.1 Morphology of different electrodes 39
4.1.2 Specific surface area and pore size distribution analysis 49
4.2 Chemical characteristics 57
4.2.1 FTIR 57
4.2.2 XRD analysis 58
4.3 Electrochemical characteristics 60
4.3.1 Analysis of the capacitance characteristics of the original CF 60
4.3.2 Carbon fiber activated by KOH 68
4.3.3 Different Ti wt.% on CF electrode 73
4.3.4 Electrochemical impedance spectroscopy 76
4.4 CDI performances 78
4.4.1 Optimal preparation conditions of CF electrode 78
4.4.2 Electrosorption performance of modified CF electrodes 82
CHAPTER V. CONCLUSION AND SUGGESTION 85
5.1 Conclusion 85
5.2 Suggestion 86
APPENDIX 87
REFERENCE 89
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指導教授 秦靜如 審核日期 2021-10-26
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