多元進料質子陶瓷燃料電池與質子交換膜燃料電池複合動力系統之熱力分析研究

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吳侑叡(Yu-Jui Wu) 查詢紙本館藏

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機械工程學系

論文名稱

多元進料質子陶瓷燃料電池與質子交換膜燃料電池複合動力系統之熱力分析研究
(Thermodynamic Analysis of Protonic Ceramic Fuel Cell-Proton Exchange Membrane Fuel Cell Hybrid Systems Fed by Hydrocarbon Fuels)

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至系統瀏覽論文 (2028-9-1以後開放)

摘要(中)

本研究建立以碳氫燃料為燃料之質子陶瓷燃料電池（Protonic ceramic fuel cell）與質子交換膜燃料電池（Protonic Exchange Membrane fuel cell）之複合動力系統（PCFC-PEMFC hybrid system）。根據電化學理論利用MATLAB計算PCFC及PEMFC之性能曲線，並將電化學模型鑲嵌於商用軟體Thermolib中進行系統模擬。其中PEMFC之性能曲線為根據本實驗室所製作之PEMFC百瓦電堆之實驗數據進行模型結果與實驗量測相互驗證。
在本研究中，建立了三種不同燃料電池複合系統，其中，系統一為燃料使用甲醇之燃料電池複合系統，系統二為燃料使用乙醇之燃料電池複合系統，系統三為燃料使用丙烷之燃料電池複合系統，各系統之系統配置有些需不同，透過在不同操作條件下進行比較，並從中分析系統之相關熱力特性對系統能耗與性能之影響。
研究結果表明，使用乙醇之燃料電池複合系統具有最佳之系統效率，其可用能效率亦為三系統中之最高。此外，從不同操作條件下之分析可得知，若是提升PCFC的燃料使用率，系統整體效率最高可以提高20%，若是，提升PEMFC的燃料使用率，系統整體效率最高可以提高5%。

摘要(英)

In this study, a hybrid power system consisting of a Protonic Ceramic Fuel Cell (PCFC) and a Proton Exchange Membrane Fuel Cell (PEMFC) was established, fueled by hydrocarbon fuels. The performance curves of the PCFC and PEMFC were calculated using electrochemical theory in MATLAB, and the electrochemical models were embedded in the commercial software Thermolib for system simulation. The performance curve of the PEMFC was validated by comparing the model results with experimental data obtained from our laboratory′s PEMFC stack.
Three different fuel cell hybrid systems were developed in this study. System 1 utilized methanol as the fuel, System 2 utilized ethanol, and System 3 utilized propane. Each system had different configurations, and comparisons were made under various operating conditions to analyze the influence of thermodynamic characteristics on system energy consumption and performance.
The results demonstrated that the ethanol-based fuel cell hybrid system achieved the highest system efficiency and exergy efficiency among the three systems. Furthermore, the analysis of different operating conditions revealed that increasing the fuel utilization rate of the PCFC could improve the overall system efficiency by up to 20%, while increasing the fuel utilization rate of the PEMFC could improve the overall system efficiency by up to 5%.

關鍵字(中)

★ 質子陶瓷燃料電池
★ 質子交換膜燃料電池
★ 碳氫燃料
★ 複合動力系統

關鍵字(英)

論文目次

中文摘要 VI
Abstract VII
致謝 VIII
目錄 IX
圖目錄 XII
表目錄 XV
符號表 XVI
一、緒論 1
1-1 前言 1
1-2 研究背景 4
1-2-1 固態氧化物燃料電池 4
1-2-2 質子交換膜燃料電池 6
1-2-3 極化現象 8
1-2-4 PCFC–PEMFC系統 11
1-2-5 熱回收系統 11
1-3 研究動機與目的 12
二、文獻回顧 14
2-1 SOFC模型 14
2-2 PEMFC模型 18
2-3 SOFC系統 20
2-4 PEMFC系統 23
三、理論分析 25
3-1 問題描述與假設 25
3-2 電池與系統模型 26
3-2-1 燃料電池電化學模型 26
3-2-2 質子陶瓷燃料電池（PCFC）電堆模型 32
3-2-3 質子交換膜燃料電池（Protonic Exchange Membrane fuel cell）電堆模型 32
3-2-4 熱交換器 33
3-2-5 後燃器 34
3-2-6 氣體泵浦 35
3-2-7 分離器 35
3-2-8 氫氣傳輸膜（Hydrogen transport membrane, HTM） 35
3-2-9 壓縮機 36
3-2-10 混合器 36
3-2-11 可用能（Exergy）定義 37
3-2-12 效率定義 38
3-2-13 質子陶瓷燃料電池（PCFC）參數條件 39
3-2-14 質子交換膜燃料電池（Protonic Exchange Membrane fuel cell）參數條件 40
3-3 數值方法與驗證 41
3-3-1 數值方法 41
3-3-2 程式驗證 45
四、結果與討論 47
4-1 質子陶瓷燃料電池（PCFC）性能曲線與模型驗證 47
4-2 質子交換膜燃料電池（PEMFC）性能曲線與模型驗證 50
4-2-1 燃料電池堆組裝與實驗結果 50
4-2-2 燃料電池堆性能曲線 53
4-3 燃料使用乙醇之燃料電池複合系統 60
4-3-1 乙醇燃料電池複合系統設計 60
4-3-2 燃料量及空氣量對乙醇燃料電池複合系統之影響 63
4-3-3 質子陶瓷燃料電池燃料使用率對系統之影響 68
4-3-4 質子交換膜燃料電池燃料使用率對系統之影響 70
4-3-5 乙醇燃料電池複合系統之可用能分析 72
4-4 燃料使用丙烷之燃料電池複合系統 74
4-4-1 丙烷燃料電池複合系統設計 74
4-4-2 燃料量及空氣量對丙烷燃料電池複合系統之影響 77
4-4-3 質子陶瓷燃料電池燃料使用率對系統之影響 82
4-4-4 質子交換膜燃料電池燃料使用率對系統之影響 84
4-4-5 丙烷燃料電池複合系統之可用能分析 86
4-5 燃料使用甲醇之燃料電池複合系統 88
4-5-1 甲醇燃料電池複合系統設計 88
4-5-2 燃料量及空氣量對甲醇燃料電池複合系統之影響 91
4-5-3 質子陶瓷燃料電池燃料使用率對系統之影響 96
4-5-4 質子交換膜燃料電池燃料使用率對系統之影響 98
4-5-5 甲醇燃料電池複合系統之可用能分析 100
4-6 綜合系統效率分析 102
4-6-1 燃料使用率之影響比較 102
4-6-2 系統效率分析與比較 106
五、結論 110
5-1 結論 110
5-2 未來建議 111
參考文獻 112

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指導教授

曾重仁

審核日期

2023-7-20

推文