An Exploration of the Efficacy of NiCo/NiCoOx Hydrogenation Treatment

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馬柏彥(FAHIM ABYAN MAKARIM) 查詢紙本館藏

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論文名稱

(An Exploration of the Efficacy of NiCo/NiCoOx Hydrogenation Treatment)

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至系統瀏覽論文 (2029-9-1以後開放)

摘要(中)

層狀雙氫氧化物 (LDH) 和/或氧化物催化劑是許多科學論文中最常研究的催化劑。然而，
隨著時間的推移，研究的新穎性和貢獻性要求已經將這些催化劑研究主題推向一些需
要“過於複雜”結構工程的“極端”角落。在這項研究中，提供了一種更“經典”和相對方便
的催化劑合成方法。將氫氣流入已經合成的氫氧化物和/或氧化物結構中，這種方法簡
稱為氫化。在這項研究中，發現空氣氣氛下的預熱處理效果是多餘的。這一點已由“空
氣煅燒”和“直接組”兩組樣本之間的微小差異證明，這兩組分別代表在空氣氣氛下有和
沒有預熱處理。研究發現，在氫析出反應（ HER）中，在相應電位值下，以 4 小時氫
化持續時間的空氣煅燒樣本和 4 小時氫化持續時間的直接氫化樣本的電流密度達到最
高電化學性能，記錄的電位分別為 -207 mV @ -100 mA.cm-2； -120 mV @ -10 mA.cm-2
和 -195 mV @ -100 mA.cm-2； -111 mV @ -10 mA.cm-2。對於氧析出反應（ OER），在相
應電位值下，以原始樣品的電流密度達到最高電化學性能，記錄的電位為 1628 mV @
100 mA.cm-2； 1516 mV @ 10 mA.cm-2。

摘要(英)

Layered double hydroxide (LDH) and or oxide catalysts are the two most commonly
studied catalysts in many scientific papers. As time progressed, however, the nature of newness
and contribution-seeking of the research have pushed these catalyst study topics into some
“extreme” corners which required the involvement of “overly complicated” structures
engineering. In this study, a more “classic” and relatively convenient catalyst synthesis method
is offered. Flowing hydrogen into an already synthesized hydroxide and or oxide structure is
the definition of the method discussed, called hydrogenation in short. In this study, the effect
of pre-heat treatment under an air atmosphere is found to be redundant. Proven by the
insignificant differences between the two groups specimens of “air calcined” and “direct group”,
which stand for with and without pre-heat treatment under an air atmosphere. It is found that
The highest electrochemical performances in terms of current density achieved at the respective
potential values for HER are achieved by 4 hours of hydrogenation durations for air-calcined
specimens and 4 hours of hydrogenation durations of a directly hydrogenated specimen with
the recorded potential of -207 mV @ -100 mA.cm-2; -120 mV @ -10 mA.cm-2 and -195 mV @
-100 mA.cm-2; -111 mV @ -10 mA.cm-2, in order. While for the OER, the highest
electrochemical performance was achieved by the pristine sample in terms of current density
per respective potential values, with the recorded potential of 1628 mV @ 100 mA.cm-2; 1516
mV @ 10 mA.cm-2

關鍵字(中)

★ 層狀雙氫氧化物 (LDH)
★ 氧化物催化劑
★ 氫化
★ 時間參數研究
★ 鎳-鈷基催化劑
★ 氫氣析出反應 (HER)

關鍵字(英)

★ Layered Double Hydroxide (LDH)
★ Oxide catalyst
★ Hydrogenation
★ Duration parameter study
★ nickel–cobalt-based catalyst
★ Hydrogen Evolution Reaction (HER)

論文目次

摘要 ______________________________________________________________________ i
Abstract___________________________________________________________________ ii
Acknowledgment ___________________________________________________________iii
Table of Content ____________________________________________________________ v
List of Figures_____________________________________________________________viii
List of Tables ______________________________________________________________ x
List of symbols _____________________________________________________________xi
1 Introduction ____________________________________________________________ 1
1.1 Research background_________________________________________________ 1
1.2 Research purpose ____________________________________________________ 3
1.3 Research Topic _____________________________________________________ 3
1.4 Scope of the study (Disclaimer)_________________________________________ 3
2 Literature review ________________________________________________________ 4
2.1 Electrolysis_________________________________________________________ 4
2.2 Water electrolysis mechanism __________________________________________ 5
2.3 Main source references _______________________________________________ 6
2.3.1 NiCo/NiCoOx nanohybrid _________________________________________ 6
2.3.2 NiCo2S4________________________________________________________ 7
2.3.3 MoNi4 _________________________________________________________ 9
2.4 Electrocatalyst benchmarking _________________________________________ 11
2.5 Electrochemical and material characterization methods _____________________ 13
2.5.1 Linear sweep voltammetry (LSV) __________________________________ 13
2.5.2 Electrochemical impedance spectroscopy (EIS) _______________________ 14
2.5.3 Stability Test___________________________________________________ 16
2.5.4 Scanning electron microscopy (SEM) _______________________________ 18
2.5.5 Energy Dispersive X-ray Spectroscopy (EDS) ________________________ 20
2.5.6 X-ray diffraction (XRD)__________________________________________ 22
3 Experimental Procedure _________________________________________________ 23
3.1 Research flow chart _________________________________________________ 23
3.2 Variables of the study _______________________________________________ 24vi
3.3 Synthesis method scheme and materials _________________________________ 25
3.3.1 The hydrothermal method ________________________________________ 25
3.3.2 The Air calcination treatment and hydrogenation ______________________ 26
3.4 Equipment used ____________________________________________________ 28
4 Results and Discussion __________________________________________________ 30
4.1 LSV (Linear Sweep Voltammetry) _____________________________________ 30
4.1.1 HER of the “Air calcined group”___________________________________ 30
4.1.2 HER of the “Direct group”________________________________________ 32
4.1.3 OER of the “Air calcined group”___________________________________ 34
4.1.4 OER of the “Direct group”________________________________________ 36
4.2 Tafel slope ________________________________________________________ 38
4.2.1 HER – Tafel slope of the “Air calcined group” ________________________ 38
4.2.2 HER – Tafel slope of the “Direct group”_____________________________ 40
4.2.3 OER – Tafel slope of the “Air calcined group”________________________ 42
4.2.4 OER – Tafel slope of the “Direct group”_____________________________ 44
4.3 Repeatability test ___________________________________________________ 46
4.3.1 Repeatability test for HER – LSV of the “Air calcined group”____________ 46
4.3.2 Repeatability test for HER – LSV of the “Direct group” ________________ 48
4.3.3 Repeatability test for OER – LSV of the “Air calcined group”____________ 50
4.3.4 Repeatability test for OER – LSV of the “Direct group” ________________ 52
4.4 EIS (Electrochemical Impedance Spectroscopy) __________________________ 54
4.4.1 EIS of the “Air calcined group” at HER potential ______________________ 54
4.4.2 EIS of the “Direct group” at HER potential___________________________ 56
4.4.3 EIS of the “Air calcined group” at OER potential ______________________ 58
4.4.4 EIS of the “Direct group” at OER potential___________________________ 60
4.5 SEM (Scanning electron microscopy)___________________________________ 62
4.5.1 Pristine _______________________________________________________ 62
4.5.2 Air calcined – 2 hours ___________________________________________ 64
4.5.3 Air calcined – 4 hours ___________________________________________ 66
4.5.4 Air calcined – 6 hours ___________________________________________ 68
4.5.5 Air calcined – 8 hours ___________________________________________ 70
4.5.6 Direct – 2 hours ________________________________________________ 72
4.5.7 Direct – 4 hours ________________________________________________ 74
4.5.8 Direct – 6 hours ________________________________________________ 76
4.5.9 Direct – 8 hours ________________________________________________ 78vii
4.6 EDS (Energy Dispersive X-ray Spectroscopy) ____________________________ 80
4.6.1 Pristine _______________________________________________________ 80
4.6.2 Air calcined – 2 hours____________________________________________ 82
4.6.3 Air calcined – 4 hours____________________________________________ 84
4.6.4 Air calcined – 6 hours____________________________________________ 86
4.6.5 Air calcined – 8 hours____________________________________________ 88
4.6.6 Direct – 2 hours ________________________________________________ 90
4.6.7 Direct – 4 hours ________________________________________________ 92
4.6.8 Direct – 6 hours ________________________________________________ 94
4.6.9 Direct – 8 hours ________________________________________________ 96
4.7 X-ray diffraction (XRD) _____________________________________________ 98
4.7.1 X-ray diffraction (XRD) of the “Air calcined group” and “Direct group” ___ 98
4.8 Data connections __________________________________________________ 100
5 Conclusion and Suggestion ______________________________________________ 103
5.1 Conclusion _______________________________________________________ 103
5.2 Suggestion _______________________________________________________ 104
References ______________________________________________________________ 105

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指導教授

曾重仁(Tseng, Chung-jen)

審核日期

2024-7-31

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