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    题名: Interplay between the Crystalline and Magnetic Structures in Lightly Cr-Doped Bi(0.37)Ca(0.63)Mn(0.96)Cr(0.04)O(2.99)
    作者: Yang,CC;Li,WH;Wu,CM;Li,CHC;Sun,JR;Lynn,JW
    贡献者: 物理學系
    关键词: NEUTRON-DIFFRACTION;THERMAL EXPANSION;PHASE-SEPARATION;DOUBLE EXCHANGE;PEROVSKITE;MANGANITES;CHARGE;MN;MAGNETORESISTANCE;FERROMAGNETISM
    日期: 2010
    上传时间: 2012-06-11 10:43:34 (UTC+8)
    出版者: 國立中央大學
    摘要: The interplay between the crystalline and magnetic structures of a 4% Cr-doped Bi(0.37)Ca(0.63)Mn(0.96)Cr(0.04)O(2.99) has been investigated by alternating current (ac) magnetic susceptibility, electrical resistivity, and neutron diffraction measurements. The compound crystallizes into a monoclinic P2(1)/m symmetry. A Jahn Teller distortion occurs at 280 K. The thermal behavior of charge transport may be described by a three-dimensional variable range hopping conduction. Strong interplay between the localized magnetic electrons and the itinerant electrons are clearly revealed as the localization length increases by 20% when the Mn spins become ordered below 85 K. Short range magnetic correlations persist up to 160 K. The collinear magnetic structure can be viewed as consisting of ferromagnetic spintrimers antiferromagnetically embedded in a ferromagnetic environment. Cr-doping reduces the charge ordering temperature and the magnetic ordering temperature. It nevertheless introduces long-range ferromagnetism.
    關聯: INORGANIC CHEMISTRY
    显示于类别:[物理學系] 期刊論文

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