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    Please use this identifier to cite or link to this item: http://ir.lib.ncu.edu.tw/handle/987654321/60499


    Title: 雙極性磷光主體材料之合成與鑑定及其在有機發光二極體之應用;Synthesis and characterization of bipolar host material for phosphorescence – based organic light – emitting diodes.
    Authors: 林明遠;Lin,Ming-Yuan
    Contributors: 化學學系
    Keywords: 有機發光二極體;OLED
    Date: 2013-07-31
    Issue Date: 2013-08-22 11:39:02 (UTC+8)
    Publisher: 國立中央大學
    Abstract: 近年來,由於材料之設計與合成的進步,發現了許多雙極性的材料,其中有些甚至具有雙載子傳輸性質。因此,我們設計與合成一系列雙極性的分子,在分子結構上作細微的調整與修正,使其HOMO 或LUMO 能階能與陰陽極之功函數相仿,即可簡化OLED 元件結構而不影響元件之放光效率。本論文探討以Bis(3,5-di(9H-carbazol-9-yl) phenyl)amine (CzPA) 當作予體,此結構是由本實驗室陳錦地老師合成出3,5-Bis(9- carbazolyl)tetraphenylsilane (SimCP) 的衍伸物;分別以Oxadiazole (OXD)、Triazole (TAZ)、Benzimidazole (PBI)和Diphenyl phenanthro midazole (PPI) 當作受體,成功合成出予體-受體(D-A, Donor - Accepor)系統,這些新型材料皆具有良好的熱穩定性質。
    In this dissertation, We have developed a novel electron-transporting type host materials (bis(3,5-di(9H-carbazol-9-yl) phenyl)amine, CzPA), oxadiazole / triazole / benzimidazole / diphenyl phenanthro imidazole hybrid bipolar host materials (CzPAOXD, CzPATAZ, CzPAPBI, CzPAPPI). All these materials have good thermal stabilities.
    Appears in Collections:[Graduate Institute of Chemistry] Electronic Thesis & Dissertation

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