以高非鏡像選擇性之吖環丙烷化反應進行C-KRN7000類似物的合成研究

Please use this identifier to cite or link to this item: http://ir.lib.ncu.edu.tw/handle/987654321/68223

Title:	以高非鏡像選擇性之吖環丙烷化反應進行C-KRN7000類似物的合成研究
Authors:	宣以辰;HSUAN,YI-CHEN
Contributors:	化學學系
Keywords:	C-KRN7000;吖環丙烷化;非鏡像選擇性
Date:	2015-08-25
Issue Date:	2015-09-23 10:55:18 (UTC+8)
Publisher:	國立中央大學
Abstract:	本篇研究最關鍵的步驟是以高非鏡像選擇性的吖環丙烷化(aziridination)反應將氮原子鍵結在碳鏈上。以交叉歧化(cross metathesis)反應將醣類部分和碳鏈部分進行連結。爾後，經由簡單的幾步反應即可得到目標產物。;The key step of the stratedy is using the stereoselective aziridination reaction to attach a nitrogen atom to the carbon chain. The following steps to incorporate perbenzylated galactose and aglycone via cross metathesis reaction produced the C-KRN7000 analogues.
Appears in Collections:	[Graduate Institute of Chemistry] Electronic Thesis & Dissertation

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