金屬催化含氮炔類的合環反應之探討

Please use this identifier to cite or link to this item: http://ir.lib.ncu.edu.tw/handle/987654321/71379

Title:	金屬催化含氮炔類的合環反應之探討
Authors:	鍾民敬;Zhong,Min-Jing
Contributors:	化學學系
Keywords:	合環反應;金屬催化
Date:	2016-08-26
Issue Date:	2016-10-13 12:47:47 (UTC+8)
Publisher:	國立中央大學
Abstract:	我們以鈀金屬及金金屬化合物成功催化含氮炔類化合物( o-alkynyl sulfonamide )進行分子內合環形成環己烷取代吡咯衍生物( 3a,4,5,6,7,7a-hexahydro-indoles )，炔類上有不同的取代基團時皆可有不錯的產率。;The Pd(II) or Au(I)-catalyzed intramolecular cyclization reactions of aliphatic amino alkynes to nonaromatic nitrogen heterocycles( 3a,4,5,6,7,7a-hexahydro-indoles )were accomplished. We also found that both aryl and alkyl groups on the alkynes underwent the cyclization with moderate to good yields.
Appears in Collections:	[Graduate Institute of Chemistry] Electronic Thesis & Dissertation

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