| DC 欄位 |
值 |
語言 |
| DC.contributor | 化學學系 | zh_TW |
| DC.creator | 王詩瑩 | zh_TW |
| DC.creator | Shih-Ying Wang | en_US |
| dc.date.accessioned | 2014-7-21T07:39:07Z | |
| dc.date.available | 2014-7-21T07:39:07Z | |
| dc.date.issued | 2014 | |
| dc.identifier.uri | http://ir.lib.ncu.edu.tw:88/thesis/view_etd.asp?URN=101223002 | |
| dc.contributor.department | 化學學系 | zh_TW |
| DC.description | 國立中央大學 | zh_TW |
| DC.description | National Central University | en_US |
| dc.description.abstract | 染料敏化太陽能電池，具高光電轉換效率、低製造成本、透光性、可撓曲性等優點，是目前熱門的研究項目之一。參考我們實驗室先前所合成的染料CBTR，發現利用N-heterocyclic carbene配位基(簡稱NHC Ligand)取代傳統Bipyridine所合成出的染料具有不錯的光電轉換效率表現。因此在我的研究當中，是利用NHC-pyridine Ligand為基礎架構，加入噻吩來延伸染料的共軛系統並引入飽和長碳鏈增加元件穩定性，並接上不同的配位基進行探討，合成出染料CI123與CI124。同時我也合成Bipyridine-ligand-free 的染料DC106，利用兩片不同的NHC Ligand合成出Dicarbene的染料。 | zh_TW |
| dc.description.abstract | Dye-sensitized solar cells (DSSCs) have been considered as a significant source of electricity for their high power conversion efficiency with relatively low cost, and their designing flexibility. Here we report novel N-heterocyclic carbene (NHC)-pyridine ruthenium complexes CI123 and CI124, compared to previously reported CBTR. We have carried out structural modifications on previously reported strong electron donating N-heterocyclic carbene ancillary ligand by incorporating 2-thiophencarboxylic unit on the pyridine ring, thus making it as new carbene based anchoring ligands. Simultaneously, we also synthesized bipyridine-ligand-free dye in which two unsymmetrical NHC-pyridine ligands along with two NCS ligands were utilized to complex with ruthenium metal to form new DC106 sensitizer. | en_US |
| DC.subject | 染料敏化太陽能電池 | zh_TW |
| DC.title | 不同固著配位基對碳烯釕金屬光敏染料的影響 | zh_TW |
| dc.language.iso | zh-TW | zh-TW |
| DC.title | Effects of Various Anchoring Ligands on Carbene Based Sensitizers for Dye-Sensitized Solar Cell Applications | en_US |
| DC.type | 博碩士論文 | zh_TW |
| DC.type | thesis | en_US |
| DC.publisher | National Central University | en_US |